摘要:
An inner wall 11 of a reactor 10 has a two-layer structure: an anticorrosive layer 11a comprising an alloy material having high anticorrosiveness is provided on the inner side of the reactor contacting a corrosive process gas, and a heat conductive layer 11b for efficiently conducting the heat within the reactor 10 from an inner wall surface to a coolant flow passage 13 is provided on the outer side of the reactor (outer-wall side). The anticorrosive layer 11a comprises an alloy material having a composition for which a value R, defined by R=[Cr]+[Ni]−1.5 [Si], is not less than 40% wherein [Cr] is a mass content (% by mass) of chromium (Cr), [Ni] is a mass content (% by mass) of nickel (Ni), and [Si] is a mass content (% by mass) of silicon (Si).
摘要:
A hydrogenation reaction vessel makes STC-containing substance react with hydrogen to convert the substance into TCS. A low boils removal column separates a chlorosilane distillate discharged from a hydrogenation reaction vessel into TCS and a mixture distillate containing hyper-hydrogenated chlorosilane, and circulates the mixture distillate containing hyper-hydrogenated chlorosilane to the hydrogenation reaction vessel. The mixture distillate containing the hyper-hydrogenated chlorosilane separated in the low boils removal column is circulatingly supplied to the hydrogenation reaction vessel. Accordingly, low boils by-product conventionally wasted is circulated and recycled in the process, which results in enhancing a yield of TCS production.
摘要:
A silacyclohexane compound of the formulas (I) ##STR1## wherein R represents an organic residue, ##STR2## represents an unsubstituted or substituted silicon-containing cyclohexylene group or a 1,4-cyclohexylene group, ##STR3## represents an unsubstituted or substituted phenylene, an unsubstituted or substituted silicon-containing cyclohexylene group or trans-4-sila-1,4-cyclohexylene group, or a 1,4-cyclohexylene group provided that at least one of these residues represents a silicon-containing cyclohexylene group, j, k and l are, respectively, 0 or 1, L.sub.1 and L.sub.2, respectively, represent H or F, m and n are, respectively, 0, 1 or 2 provided that m+n=2, 3 or 4, and X represents H, F or Cl. A liquid crystal composition comprising the silacyclohexane compound of the above formula is also described, along with a liquid crystal device comprising the composition.
摘要翻译:式(I)的硅环己烷化合物,其中R表示有机残基,表示未取代或取代的含硅亚环己基或1,4-亚环己基,表示未取代或取代的亚苯基,未取代或取代的含硅亚环己基 基团或反式-4-硅烷-1,4-亚环己基或1,4-亚环己基,条件是这些残基中的至少一个表示含硅的亚环己基,j,k和l分别为0或 1,L1和L2分别表示H或F,m和n分别为0,1或2,条件是m + n = 2,3或4,X表示H,F或Cl。 还描述了包含上式的硅环己烷化合物的液晶组合物以及包含该组合物的液晶装置。
摘要:
A silacyclohexane compound represented by the following general formula (I). ##STR1## In this formula, R denotes a linear-chain alkyl group with 1-10 carbon atoms, a branched-chain alkyl group with 3-8 carbon atoms, a mono- or di-fluoroalkyl group with 1-10 carbon atoms, an alkoxyalkyl group with 2-7 carbon atoms, or an alkenyl group with 2-8 carbon atoms. ##STR2## is trans-1-silacyclohexylene or trans-4-silacyclohexylene group whose silicon at position 1 or position 4 has a substitutional group(s) of H, F, Cl or CH.sub.3. X denotes a R, OR, CN, F, Cl, CF.sub.3, CF.sub.2 Cl, CHFCl, OCF.sub.3, OCHF.sub.2, OCF.sub.2 Cl, OCHFCl, --(O).sub.m --CY.sub.1 .dbd.CX.sub.1 X.sub.2 (m denotes 0 or 1, Y.sub.1 and X.sub.1 respectively denote H, F or Cl, and X.sub.2 denotes F or Cl) or --O--C.sub.r F.sub.s H.sub.2r+1-s is (r denotes an integral of 2 to 4 and s denotes an integral of 1 to 7) group. Y denotes H or F. Z denotes H or F.
摘要:
Described is a guest host liquid crystal composition comprising as a host liquid crystal a liquid crystal composition containing some of the compounds represented by the formulas (I) to (V) which will be described below; and at least four dichromatic dye compounds. ##STR1##
摘要:
A silacyclohexane compound of the following formula (I) ##STR1## wherein R is an unsubstituted or substituted organic residue, W is H, F, Cl or methyl, X is CN, F, Cl or an unsubstituted or substituted organic residue, and Y and Z independently represent H, F or Cl. The silacyclohexane compounds are useful in liquid crystal compositions and also in liquid crystal devices.
摘要:
A silacyclohexane compound of the following formula (I) ##STR1## wherein R represents an organic residue; at least one of ##STR2## represents a substituted or unsubstituted trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group and the other represents a trans-1,4-cyclohexylene group, L.sub.1 and L.sub.2 independently represent H, F, Cl or CH.sub.3 ; X represents an organic residue or CN, F, Cl; and m and n are, respectively, 0 or 1 provided that m+n=1. Silacyclohexane compounds are useful in liquid crystal compositions and also in liquid crystal devices.
摘要翻译:下式(I)的硅环己烷化合物其中R表示有机残基; “IMAGE”中的至少一个表示取代或未取代的反式-1-硅烷-1,4-亚环己基或反式-4-硅烷-1,4-亚环己基,另一个表示反式-1,4-亚环己基 ,L1和L2独立地表示H,F,Cl或CH3; X表示有机残基或CN,F,Cl; 如果m + n = 1,则m和n分别为0或1。 硅环己烷化合物可用于液晶组合物和液晶装置中。
摘要:
A silacyclohexane compound of formula (I): ##STR1## wherein R denotes a linear-chain alkyl group, a mono- or di-fluoroalkyl group, a branched-chain alkyl group, an alkoxyalkyl group, or an alkenyl group: at least one of ##STR2## denotes a 1-sila-1,4-cyclohexylene or a 4-sila-1,4-cyclohexylene group whose silicon at position 1 or 4 is H, F, Cl or CH.sub.3, and the other denotes a 1,4-cyclohexylene group, a 1-sila-1,4-cyclohexylene or a 4-sila-1,4-cyclohexylene group whose silicon at position 1 or 4 is H F, Cl or CH.sub.3 ; X denotes a substitutional group at an equatorial position, specifically CN, an alkyl group with its end group replaced by a trifluoromethyl group, an alkoxy group, an alkanoyloxy group, an alkoxycarbonyl group, a linear-chain alkyl group, or an alkoxyalkyl group; Y denotes a group at an axial position, specifically H or CN when Y is connected to a carbon atom in said (B) group or H, F, Cl or CH.sub.3 when Y is connected to a silicon atom in said (B) group.
摘要:
A process for preparing a silacyclohexane compound of the general formula ##STR1## wherein R and Q are, respectively, defined substituents, which process comprising the steps of converting a compound of the following formula ##STR2## to a halosilacyclohexane of the following formula ##STR3## wherein X is a halogen, reacting the halosilacyclohexane with an alcohol to obtain an alkoxysilacyclohexane of the formula which is equilibrated in steric configuration, and ##STR4## reducing the equilibrated alkoxysilacyclohexane whereby a trans form silacyclohexane compound is predominantly produced.
摘要翻译:制备通式为“IMAGE”的硅环己烷化合物的方法,其中R和Q分别为限定的取代基,该方法包括以下步骤:将下式的化合物转化为下式的卤代环己烷:IMA IMA >其中X是卤素,使卤代二环己烷与醇反应,得到在空间结构中平衡的式的烷氧基硅烷环己烷,并且还原平衡的烷氧基硅烷环己烷,由此主要生产反式形式的硅环己烷化合物。
摘要:
A silacyclohexane compound represented by the following general formula (I). ##STR1## In this formula, R denotes a linear-chain alkyl group with a carbon number of 1-10, a mono- or di-fluoroalkyl group with a carbon number of 1-10, a branched-chain alkyl group with a carbon number of 3-8, an alkoxyalkyl group with a carbon number of 2-7, or an alkenyl group with a carbon number of 2-8. ##STR2## denotes a trans-1-silacyclohexylene or trans-4-silacyclohexylene group whose silicon at position 1 or position 4 has a substitutional group(s) of H, F, Cl or CH.sub.3. X denotes a CN, F, Cl, CF.sub.3, CF.sub.2 Cl, CHFCl, OCF.sub.3, OCHF.sub.2, OCF.sub.2 Cl, OCHFCl, R or OR group. Y denotes H or F. Z denotes H or F.