Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
    2.
    发明授权
    Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same 失效
    基于多官能羰基化合物的低聚受阻胺光稳定剂及其制备方法

    公开(公告)号:US06545156B1

    公开(公告)日:2003-04-08

    申请号:US09704872

    申请日:2000-11-03

    IPC分类号: C07D22120

    CPC分类号: C07D211/46

    摘要: Oligomeric compounds and methods of making the compounds having the formula: T&Parenopenst;M—F&Parenclosest;i&Parenopenst;M—F′&Parenclosest;jM  (III) wherein i and j are integers from about 0 to 300 and the sum of i and j is greater than 2, wherein the units F, F′ and T are derived from one or more multi-functional carbonyl compounds of general structure DO—CO—CRaRb—(—CRcRd—)n—NH—(Y)m—CO—OD  (IV) wherein n is an integer from 1 to 15, m is either 0 or 1; Ra, Rb, Rc, and Rd, are each a hydrogen or a hydrocarbyl group; Y is CO—(CReRf)p, wherein Re and Rf are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C6H4—, D is a hydrocarbyl group, and M is a moiety derived from one or more diamino or dihydroxy compounds that contain a 4-aminopiperidine radical.

    摘要翻译: 低聚化合物和制备具有下式的化合物的方法:其中i和j为约0至300的整数,i和j的和大于2,其中单元F,F'和T衍生自一个或多个 一般结构的多官能羰基化合物,其中n为1至15的整数,m为0或1; Ra,Rb,Rc和Rd各自为氢或烃基; Y是CO-(CReRf)p,其中Re和Rf各自为氢或烃基,p为0或1至20的整数或CO-C 6 H 4 - ,D为烃基,M为衍生自 一种或多种含有4-氨基哌啶基团的二氨基或二羟基化合物。

    Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
    3.
    发明授权
    Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same 失效
    基于多官能羰基化合物的低聚受阻胺光稳定剂及其制备方法

    公开(公告)号:US06414155B1

    公开(公告)日:2002-07-02

    申请号:US09704527

    申请日:2000-11-03

    IPC分类号: C07D40114

    摘要: Oligomeric compounds and methods of making the compound having the formula: wherein i, j, k, and l are integers from about 0 to 300 and the sum of i, j, k, and l is greater than 2, wherein the units F, F′ and T are derived from one or more multi-functional carbonyl compounds of general structure DO—CO—CRaRb—(—CRcCRd—)n—NH—(Y)m—CO—OD  (IV) wherein n is an integer from 1 to 15, m is either 0 or 1; Ra, Rb, Rc, and Rd, are each a hydrogen or a hydrocarbyl group; Y is CO—(CReRf)p, wherein Re and Rf are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C6H4—, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern, and one or more of the hydrogens of the phenylene group may be substituted by a hydrocarbyl group or a functional group; and D is a hydrocarbyl group and the units E, E′ and S are derived from one or more 1-substituted piperidin-4-ol or 4-aminopiperidines of general structure wherein Z is OH or NHG, wherein G is H or C1-C12 alkyl, R1 is —(CH2)s—OH or —(CH2)s—NH2, wherein s is an integer from 1 to 10; R2 represents hydrogen, C1-C8 alkyl, or benzyl; R3, R4, R5, and R6 are each a hydrogen, C1-C8 alkyl, benzyl or phenethyl, or two geminal R moieties, which together with the carbon to which they are attached form a C5-C10 cycloalkyl. The compounds are useful for stabilizing polymer compositions against photo- and thermal degradation.

    摘要翻译: 低聚化合物和制备具有下式的化合物的方法:其中i,j,k和l为约0至300的整数,i,j,k和l的和大于2,其中单元F, F'和T衍生自一种或多种通式结构的多官能羰基化合物,其中n为1至15的整数,m为0或1; Ra,Rb,Rc和Rd各自为氢或烃基; Y是CO-(CReRf)p,其中Re和Rf各自为氢或烃基,p为0或1至20的整数或CO-C 6 H 4 - ,其中亚苯基上的取代模式为邻位,间位 或对位取代模式,并且亚苯基的一个或多个氢可以被烃基或官能团取代; 并且D是烃基,并且单元E,E'和S衍生自一种或多种一般结构的1-取代的哌啶-4-醇或4-氨基哌啶,其中Z是OH或NHG,其中G是H或C1-C12 烷基,R 1是 - (CH 2)s -OH或 - (CH 2)s -NH 2,其中s是1至10的整数; R 2表示氢,C 1 -C 8烷基或苄基; R 3,R 4,R 5和R 6各自是氢,C 1 -C 8烷基,苄基或苯乙基,或两个偕R部分,它们与它们所连接的碳一起形成C5-C10环烷基。 该化合物可用于稳定聚合物组合物以抵抗光和热降解。