Catalysts and methods for catalytic oxidation
    1.
    发明申请
    Catalysts and methods for catalytic oxidation 审中-公开
    催化剂和催化氧化方法

    公开(公告)号:US20070093379A1

    公开(公告)日:2007-04-26

    申请号:US11605531

    申请日:2006-11-28

    Abstract: Catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.

    Abstract translation: 在选择的大多环刚性配体,优选跨桥联的大多环配体络合的金属催化剂(优选含锰催化剂)存在下氧化材料的催化体系和方法。 包括在这些方法中使用这些金属催化剂:合成有机氧化反应,例如有机官能团,烃和杂原子的氧化,包括烯烃的对映体环氧化,烯烃,硫化物到砜等; 在诸如织物,餐具,台面,假牙等的表面上氧化可氧化化合物(例如污点); 溶液中可氧化化合物的氧化,织物洗涤中的染料转移抑制; 并进一步在纸浆和纸制品的漂白。

    Catalysts and methods for catalytic oxidation
    5.
    发明申请
    Catalysts and methods for catalytic oxidation 审中-公开
    催化剂和催化氧化方法

    公开(公告)号:US20050192195A1

    公开(公告)日:2005-09-01

    申请号:US11117103

    申请日:2005-04-28

    Abstract: Catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.

    Abstract translation: 在选择的大多环刚性配体,优选跨桥联的大多环配体络合的金属催化剂(优选含锰催化剂)存在下氧化材料的催化体系和方法。 包括在这些方法中使用这些金属催化剂:合成有机氧化反应,例如有机官能团,烃和杂原子的氧化,包括烯烃的对映体环氧化,烯烃,硫化物到砜等; 在诸如织物,餐具,台面,假牙等的表面上氧化可氧化化合物(例如污点); 溶液中可氧化化合物的氧化,织物洗涤中的染料转移抑制; 并进一步在纸浆和纸制品的漂白。

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