公开(公告)号：US07589228B2

公开(公告)日：2009-09-15

申请号：US10908849

申请日：2005-05-27

Applicant: Ai Nishichi ,  Yoshinobu Asako ,  Kazushi Omote ,  Shimpei Sato ,  Toshiya Iida ,  Satoshi Ishida

Inventor： Ai Nishichi ,  Yoshinobu Asako ,  Kazushi Omote ,  Shimpei Sato ,  Toshiya Iida ,  Satoshi Ishida

IPC: C07C69/76

CPC classification number: C08K5/315 ,  C07C69/76 ,  C07C255/54 ,  C08L67/00

Abstract: The present invention has an object to provide a fluorine-containing compound which can be used for applications such as additives making a transparent resin material low in a water absorbing ratio and high in water repellency without deteriorating of various properties such as transparency which the transparent resin material has, a fluorine-containing ester compound which is superior in properties such as heat resistance and low moisture(water) absorption property and can be suitably used in various fields such as a material for electronic information, a material for precision instruments and an optical material, a fluorine-containing aryl ester polymer, methods of producing the same. The present invention provides a fluorine-containing compound represented by the following formula (1): in the formula, X represents an oxygen atom or a sulfur atom; Rf represents a fluorine-containing alkyl group having 4 or more carbon atoms; r represents the number of Rf—X— groups bonded to an aromatic ring and is an integer of 1 or more; s represents the number of fluorine atoms bonded to an aromatic ring and is an integer of 1 or more; and r+s is an integer of 2 to 5.

Abstract translation: 本发明的目的是提供一种含氟化合物，其可以用于制造透明树脂材料，吸水率低，拒水性高的添加剂，而不会导致透明性等各种性能的劣化 材料具有耐热性，低水分（水）吸收性等优异的含氟酯化合物，可以适用于电子信息材料，精密仪器用材料和光学材料等各种领域 材料，含氟芳基酯聚合物，其制备方法。 本发明提供由下式（1）表示的含氟化合物：式中X表示氧原子或硫原子; Rf表示碳原子数为4以上的含氟烷基， r表示与芳环键合的Rf-X基的数目，为1以上的整数， s表示与芳环键合的氟原子数，为1以上的整数， r + s为2〜5的整数。

公开(公告)号：US20050265686A1

公开(公告)日：2005-12-01

申请号：US10908849

申请日：2005-05-27

Applicant: Ai Nishichi ,  Yoshinobu Asako ,  Kazushi Omote ,  Shimpei Sato ,  Toshiya Iida ,  Satoshi Ishida

Inventor： Ai Nishichi ,  Yoshinobu Asako ,  Kazushi Omote ,  Shimpei Sato ,  Toshiya Iida ,  Satoshi Ishida

IPC: C07C69/76 ,  C07C255/54 ,  C08K5/00 ,  C08K5/315 ,  G02B6/00

CPC classification number: C08K5/315 ,  C07C69/76 ,  C07C255/54 ,  C08L67/00

Abstract: The present invention has an object to provide a fluorine-containing compound which can be used for applications such as additives making a transparent resin material low in a water absorbing ratio and high in water repellency without deteriorating of various properties such as transparency which the transparent resin material has, a fluorine-containing ester compound which is superior in properties such as heat resistance and low moisture(water) absorption property and can be suitably used in various fields such as a material for electronic information, a material for precision instruments and an optical material, a fluorine-containing aryl ester polymer, methods of producing the same. The present invention provides a fluorine-containing compound represented by the following formula (1): in the formula, X represents an oxygen atom or a sulfur atom; Rf represents a fluorine-containing alkyl group having 4 or more carbon atoms; r represents the number of Rf-X— groups bonded to an aromatic ring and is an integer of 1 or more; s represents the number of fluorine atoms bonded to an aromatic ring and is an integer of 1 or more; and r+s is an integer of 2 to 5.

Abstract translation: 本发明的目的是提供一种含氟化合物，其可以用于制造透明树脂材料，吸水率低，拒水性高的添加剂，而不会导致透明性等各种性能的劣化 材料具有耐热性，低水分（水）吸收性等优异的含氟酯化合物，可以适用于电子信息材料，精密仪器用材料和光学材料等各种领域 材料，含氟芳基酯聚合物，其制备方法。 本发明提供由下式（1）表示的含氟化合物：式中X表示氧原子或硫原子; Rf表示碳原子数为4以上的含氟烷基， r表示与芳环键合的Rf-X基的数目，为1以上的整数， s表示与芳环键合的氟原子数，为1以上的整数， r + s为2〜5的整数。

公开(公告)号：US06465668B2

公开(公告)日：2002-10-15

申请号：US09993892

申请日：2001-11-27

Applicant: Ikuyo Ikeno ,  Hitoshi Mitsui ,  Toshiya Iida ,  Toshimitsu Moriguchi

Inventor： Ikuyo Ikeno ,  Hitoshi Mitsui ,  Toshiya Iida ,  Toshimitsu Moriguchi

IPC: C07F722

CPC classification number: C07F7/2208

Abstract: A method for easily and inexpensively producing and purifying a fluoroaryl metal compound such as bis(pentafluorophenyl)dialkyltin which is less colored and has no impurities is provided. Hydrocarbon magnesium halide is reacted with fluoroaryl halide in a solvent including an ether solvent so as to obtain fluoroaryl magnesium halide, which is then reacted with an organic metal compound so as to produce a fluoroaryl metal compound. Tin is more preferable as a metal atom included in the organic metal compound. As for the ether solvent, chain ether solvents are preferable, more specifically, diisopropyl ether, dibutyl ether, and t-butylmethyl ether are more preferable. Besides, it is preferable that magnesium halide, which is a by-product of the fluoroaryl metal compound, is precipitated and removed, or treated with an acid.

Abstract translation: 提供了一种容易且廉价地生产和纯化氟代芳基金属化合物如双（五氟苯基）二烷基锡的方法，所述二（五氟苯基）二烷基锡颜色较少，没有杂质。 碳氢化镁卤化物与氟芳基卤化物在包括醚溶剂的溶剂中反应，得到氟化芳基卤化镁，然后与有机金属化合物反应，生成氟芳基金属化合物。 作为有机金属化合物中的金属原子，更优选锡。 对于醚类溶剂，优选链状醚溶剂，更优选二异丙基醚，二丁基醚和叔丁基甲基醚。 此外，优选将作为氟代芳基金属化合物的副产物的卤化镁沉淀除去，或用酸处理。

公开(公告)号：US06235222B1

公开(公告)日：2001-05-22

申请号：US09425385

申请日：1999-10-22

Applicant: Hitoshi Mitsui ,  Toshiya Iida ,  Ikuyo Ikeno ,  Naoko Hirano ,  Yukiko Ariyoshi

Inventor： Hitoshi Mitsui ,  Toshiya Iida ,  Ikuyo Ikeno ,  Naoko Hirano ,  Yukiko Ariyoshi

IPC: C07F302

CPC classification number: C07F3/02 ,  C07F5/027

Abstract: In order to provide a method of safely, efficiently, and industrially manufacturing fluoroaryl magnesium halide containing no impurities, such as coloring components, by a relatively gradual reaction compared with the conventional reactions, and a method of readily and efficiently manufacturing a highly-pure fluoroaryl borane derivative, fluoroaryl magnesium halide expressed by General Formula (1): where each of R1-R5 independently represents H, F, a hydrocarbon group, or an alkoxy group, provided that at least three of R1-R5 are fluorine atoms, and Xa represents Cl, Br, or I; is manufactured by reacting, in a solvent containing a chain ether solvent, hydrocarbon magnesium halide expressed by General Formula (2): R6MgXa  (2) where R6 represents a hydrocarbon group, and Xa represents Cl, Br, or I; with fluoroaryl halide expressed by General Formula (3): where each of R1-R5 independently represents H, F, a hydrocarbon group, or an alkoxy group, provided that at least three of R1-R5 are fluorine atoms and Xb represents Br or I.

Abstract translation: 为了提供与常规反应相比，通过相对逐渐的反应，安全，有效和工业上制造不含杂质的诸如着色组分的氟化芳基卤化镁的方法，以及容易且有效地制备高纯度氟化芳基 硼烷衍生物，由通式（1）表示的氟化芳基卤化镁：其中R 1 -R 5各自独立地表示H，F，烃基或烷氧基，条件是R 1 -R 5中至少有3个为氟原子，Xa 通过使通式（2）表示的烃卤化镁在含有链醚溶剂的溶剂中反应制备：其中R6表示烃基，Xa表示Cl，Br或I; 与通式（3）表示的氟化芳基卤：其中R 1 -R 5各自独立地表示H，F，烃基或烷氧基，条件是R 1 -R 5中的至少三个为氟原子， Xb表示Br或I.

公开(公告)号：US07887920B2

公开(公告)日：2011-02-15

申请号：US11795320

申请日：2006-01-30

Applicant: Akio Ito ,  Satoshi Ishida ,  Toshiya Iida ,  Takako Ishii ,  Nobuhiro Kobayashi

Inventor： Akio Ito ,  Satoshi Ishida ,  Toshiya Iida ,  Takako Ishii ,  Nobuhiro Kobayashi

IPC: B32B33/00 ,  G02B5/22 ,  C08K5/55 ,  C07F5/02

CPC classification number: C07F5/027 ,  Y10S428/913 ,  Y10T428/31

Abstract: A borate for a near-infrared ray absorption material, having an anion represented by the formula (1): [BR1mR24-m]− (wherein R1 represents an aryl group having an electron withdrawing group; R2 represents an organic group, a halogen group or a hydroxyl group; and m is an integer in the range of 1 to 4) is provided. The borate of the present invention enables to improve durability, in particular, heat resistance and moisture resistance of a near-infrared ray absorbing dye.

Abstract translation: 一种具有由式（1）表示的阴离子的近红外线吸收材料的硼酸盐：[BR1mR24-m] - （其中R1表示具有吸电子基团的芳基; R2表示有机基团，卤素基团 或羟基; m为1〜4的整数）。 本发明的硼酸盐能够提高近红外线吸收染料的耐久性，特别是耐热性和耐湿性。

公开(公告)号：US07678881B2

公开(公告)日：2010-03-16

申请号：US10908843

申请日：2005-05-27

Applicant: Ai Nishichi ,  Yoshinobu Asako ,  Kazushi Omote ,  Shimpei Sato ,  Toshiya Iida ,  Satoshi Ishida

Inventor： Ai Nishichi ,  Yoshinobu Asako ,  Kazushi Omote ,  Shimpei Sato ,  Toshiya Iida ,  Satoshi Ishida

IPC: C08G73/24 ,  C08G73/00 ,  G02B1/00

CPC classification number: G02B1/04 ,  C08G65/4025

Abstract: The present invention has an object to provide a transparent resin material having a low water absorption ratio without deteriorating various properties such as transparency which transparent resin has and also having a controllable refractive index. The present invention provides a transparent resin material containing a polymer capable of forming a formed product having transparency, wherein the transparent resin material comprises a fluorine atom-containing polymer and/or compound and contains 0.3 to 35% by weight of a fluorine atom in 100% by weight of the formed product.

Abstract translation: 本发明的目的是提供一种透明树脂材料，其具有低的吸水率，而不会使诸如透明树脂具有的透明性和折射率可控的各种性能恶化。 本发明提供一种透明树脂材料，其含有能够形成具有透明性的成型体的聚合物，其中，所述透明树脂材料含有含氟原子的聚合物和/或化合物，并且含有0.3〜35重量％的氟原子100 重量％的成型产品。

公开(公告)号：US20080102279A1

公开(公告)日：2008-05-01

申请号：US11795320

申请日：2006-01-30

Applicant: Akio Ito ,  Satoshi Ishida ,  Toshiya Iida ,  Takako Ishii ,  Nobuhiro Nobayashi

Inventor： Akio Ito ,  Satoshi Ishida ,  Toshiya Iida ,  Takako Ishii ,  Nobuhiro Nobayashi

IPC: G02B5/23 ,  C08K5/55 ,  C07F5/02 ,  B32B33/00

CPC classification number: C07F5/027 ,  Y10S428/913 ,  Y10T428/31

Abstract: A borate for a near-infrared ray absorption material, having an anion represented by the formula (1): [BR1mR24−m]− (wherein R1 represents an aryl group having an electron withdrawing group; R2 represents an organic group, a halogen group or a hydroxyl group; and m is an integer in the range of 1 to 4) is provided. The borate of the present invention enables to improve durability, in particular, heat resistance and moisture resistance of a near-infrared ray absorbing dye.

Abstract translation: 一种具有由式（1）表示的阴离子的近红外线吸收材料的硼酸盐：[BR] 1

公开(公告)号：US07254419B2

公开(公告)日：2007-08-07

申请号：US10443562

申请日：2003-05-22

Applicant: Toshiya Iida

Inventor： Toshiya Iida

IPC: H04M1/00

CPC classification number: H04M19/04 ,  H04M1/7253

Abstract: A plurality of operators provided on a communication terminal, such as a portable phone, are assigned in advance to functions for generating tones, and a tone generation starting signal is generated in response to depressing operation, by a user, of any one of the operators. The communication terminal transmits, to a tone generator module, performance content data having added thereto operation time information representative of a time when the user's depressing operation has taken place. Upon receipt of the performance content data from the communication terminal, the tone generator module carries out a process based on the tone generation starting signal on the basis of the operation time information added to the performance content data.

Abstract translation: 提供在诸如便携式电话的通信终端上的多个运营商被预先分配用于产生音调的功能，并且响应于用户对于任何一个运营商的按下操作而生成音调生成开始信号 。 通信终端向乐音发生器模块发送表示添加了表示用户按下操作的时间的操作时间信息的演奏内容数据。 在从通信终端接收到演奏内容数据的情况下，乐音发生器模块基于添加到表演内容数据的操作时间信息，基于乐音产生开始信号进行处理。

公开(公告)号：US07205441B2

公开(公告)日：2007-04-17

申请号：US10431613

申请日：2003-05-08

Applicant: Ikuyo Ikeno ,  Toshimitsu Moriguchi ,  Hitoshi Mitsui ,  Toshiya Iida

Inventor： Ikuyo Ikeno ,  Toshimitsu Moriguchi ,  Hitoshi Mitsui ,  Toshiya Iida

IPC: C07F5/02

CPC classification number: C07F5/027

Abstract: Fluoroaryl magnesium halide is reacted with a boron compound so that a molar ratio of the fluoroaryl magnesium halide to the boron compound is not less than 3.0 and not more than 3.7, so as to produce a tetrakis (fluoroaryl) borate.magnesium compound. With this method, there occurs no hydrogen fluoride which corrodes a producing apparatus and requires troublesome waste water treatment.

Abstract translation: 氟芳基卤化镁与硼化合物反应，使得氟化芳基卤化镁与硼化合物的摩尔比不小于3.0且不大于3.7，以产生四（氟化芳基）硼酸镁化合物。 通过这种方法，不会发生腐蚀生产装置的氟化氢，并且需要麻烦的废水处理。

公开(公告)号：US06281389B1

公开(公告)日：2001-08-28

申请号：US09391585

申请日：1999-09-07

Applicant: Hitoshi Mitsui ,  Toshiya Iida ,  Ikuyo Ikeno ,  Naoko Hirano ,  Yukiko Ariyoshi

Inventor： Hitoshi Mitsui ,  Toshiya Iida ,  Ikuyo Ikeno ,  Naoko Hirano ,  Yukiko Ariyoshi

IPC: C07F502

CPC classification number: C07F5/027

Abstract: A solution containing an organic solvent and a compound including impurities, represented by, for example, general formula (1) (wherein R1 to R10 independently represent H, F, a hydrocarbon group or an alkoxy group, at least one of R1 to R5 is F, at least one of R6 to R10 is F, M is H, alkali metal, alkaline earth metal or alkaline earth metal halide, n is 3 or 4, and m is 2 when M is an alkaline earth metal, or m is 1 when M is the other) is mixed with water. The purified compound is reacted with a compound which forms a monovalent cation seed to prepare a derivative. Thus, a purifying method capable of efficiently and easily separating and removing colored components contained in tetrakis(fluoroaryl)borate compounds can be provided. Moreover, it is possible to provide a method capable of preparing a highly-pure tetrakis(fluoroaryl)borate derivative efficiently and at low costs.

Abstract translation: 由通式（1）表示的含有有机溶剂和包含杂质的化合物的溶液（其中R 1至R 10独立地表示H，F，烃基或烷氧基，R 1至R 5中的至少一个为 F中，R 6〜R 10中的至少一个为F，M为H，碱金属，碱土金属或碱土金属卤化物，n为3或4，M为碱土金属时m为2，m为1 当M是另一个）与水混合时。 将纯化的化合物与形成一价阳离子种子的化合物反应以制备衍生物。 因此，可以提供能够有效且容易地分离和除去四（氟化芳基）硼酸盐化合物中所含有色成分的纯化方法。 此外，可以提供一种能够以低成本有效地制备高纯度四（氟化芳基）硼酸盐衍生物的方法。