公开(公告)号：US07901742B2

公开(公告)日：2011-03-08

申请号：US12305521

申请日：2007-06-18

申请人： Katsuhiro Shirono ,  Takaki Mizuno ,  Tsuguo Koyanagi

发明人： Katsuhiro Shirono ,  Takaki Mizuno ,  Tsuguo Koyanagi

IPC分类号： B05D1/06

CPC分类号： C25D13/02

摘要： A method for forming a metal oxide fine particle layer, by which a metal oxide fine particle layer having uniformity and excellent in adhesion, abrasion resistance, strength, etc. can be formed easily compared with the conventional plating method, CVD method, liquid coating method, electrodeposition method or the like. The method comprises immersing a conductive substrate in a dispersion of metal oxide fine particles and fibrous fine particles and applying a direct-current voltage to the conductive substrate and the dispersion. The fibrous fine particles have a length (L) of 50 nm to 10 μm, a diameter (D) of 10 nm to 2 μm and an aspect ratio (L)/(D) of 5 to 1,000. The content of the fibrous fine particles in the dispersion is in the range of 0.1 to 20% by weight in terms of solids content, based on the metal oxide fine particles.

摘要翻译： 与传统的镀覆方法，CVD法，液体涂布法相比，可以容易地形成金属氧化物微粒层的形成方法，通过该方法可以形成均匀性和粘附性，耐磨性，强度等优异的金属氧化物微粒层 ，电沉积法等。 该方法包括将导电基底浸入金属氧化物细颗粒和纤维状细颗粒的分散体中，并向导电基材和分散体施加直流电压。 纤维状微粒的长度（L）为50nm〜10μm，直径（D）为10nm〜2μm，纵横比（L）/（D）为5〜1000。 基于金属氧化物微粒，分散体中的纤维状微粒的含量以固体成分计为0.1〜20重量％。

公开(公告)号：US06580026B1

公开(公告)日：2003-06-17

申请号：US09786093

申请日：2001-02-28

申请人： Tsuguo Koyanagi ,  Michio Komatsu

发明人： Tsuguo Koyanagi ,  Michio Komatsu

IPC分类号： H01M1400

CPC分类号： H01G9/2031 ,  H01G9/2009 ,  H01G9/2036 ,  Y02E10/542

摘要： A photovoltaic cell including a first substrate having on its surface a first electrode layer having on its surface a semiconductor film on which a photosensitizer is adsorbed, and a second substrate having on its surface a second electrode layer. The first and second substrates are arranged so that the first electrode layer overlaid with the semiconductor film and the second layer are opposite each other with an electrolyte layer disposed therebetween. The electrolyte layer includes an electrolyte and a liquid crystal and at least one of the electrode-layer-having substrates is transparent.

摘要翻译： 一种光伏电池，包括第一基板，其表面上具有在其表面上具有吸收光敏剂的半导体膜的第一电极层，以及在其表面上具有第二电极层的第二基板。 第一和第二基板被布置成使得与半导体膜和第二层重叠的第一电极层彼此相对，其间设置有电解质层。 电解质层包括电解质和液晶，并且至少一个具有电极层的衬底是透明的。

公开(公告)号：US5204177A

公开(公告)日：1993-04-20

申请号：US754208

申请日：1991-08-27

申请人： Goro Sato ,  Michio Komatsu ,  Tsuguo Koyanagi ,  Masayuki Matsuda ,  Hiroo Yoshidome ,  Akira Nakashima ,  Kazuaki Inoue

发明人： Goro Sato ,  Michio Komatsu ,  Tsuguo Koyanagi ,  Masayuki Matsuda ,  Hiroo Yoshidome ,  Akira Nakashima ,  Kazuaki Inoue

IPC分类号： C01G15/00 ,  C01G19/02 ,  C09C3/12 ,  C09D5/24 ,  H01B1/08 ,  H01B1/20

CPC分类号： C01G15/00 ,  C01G19/02 ,  C09C3/12 ,  C09D5/24 ,  H01B1/08 ,  H01B1/20 ,  C01P2002/52 ,  C01P2002/54 ,  Y10S428/918 ,  Y10T428/256

摘要： Transparent conductive coatings excellent in transparency are provided on substrates such as glass, plastics, etc. by the use of conductive coating materials obtained by maintaining aqueous solutions of hydrolyzable tin containing or indium containing compounds at pH of 8-12, and gradually hydrolyzing said compounds in the solutions to form sols containing colloidal particles, followed by drying and calcining.

摘要翻译： 通过使用通过维持pH为8-12的维持含有水解性锡或含铟化合物的水溶液获得的导电涂层材料，在诸如玻璃，塑料等的基材上提供透明度优异的透明导电涂层，并逐渐水解所述化合物 在形成含有胶体颗粒的溶胶的溶液中，然后干燥和煅烧。

公开(公告)号：US20090036299A1

公开(公告)日：2009-02-05

申请号：US12219823

申请日：2008-07-29

申请人： Takashi Kodama ,  Tsuguo Koyanagi

发明人： Takashi Kodama ,  Tsuguo Koyanagi

IPC分类号： B01J21/12

CPC分类号： B01J23/72 ,  B01J21/12 ,  B01J23/83 ,  B01J35/023 ,  B01J35/1019 ,  B01J37/0045 ,  C07C17/156 ,  C07C19/045

摘要： The present invention provides a catalytic composition for oxychlorination excellent in the fluidity, the capability of suppressing lowering of the fluidity, and the attrition resistance as well as in the selectivity for EDC and the capability of suppressing combustion of ethylene.The catalytic composition for oxychlorination contains silica alumina particles in the range from 5 to 40 wt % when expressed as an oxide thereof, copper in the range from 5 to 20 wt % when expressed as an oxide thereof (CuO), and alumina as a carrier in the range from 40 to 90 wt % when expressed as that of Al2O3. The silica alumina particles are prepared by coating silica particles with alumina, and have the average particle diameter in the range from 3 to 100 nm. A content of alumina in the silica alumina particles is in the range from 0.1 to 10 wt %.

摘要翻译： 本发明提供了流动性优异的流动性，抑制流动性降低的能力和耐磨耗性以及EDC的选择性和抑制乙烯燃烧的能力的氧氯化催化组合物。 用于氧氯化的催化组合物含有氧化硅氧化铝颗粒，当其氧化物表示为5至40重量％时，铜以氧化物（CuO）表示时为5至20重量％，氧化铝为载体 当表示为Al 2 O 3时，其范围为40至90重量％。 二氧化硅氧化铝颗粒通过用氧化铝涂覆二氧化硅颗粒制备，并且其平均粒径在3至100nm的范围内。 二氧化硅氧化铝颗粒中的氧化铝含量为0.1〜10重量％。

公开(公告)号：US20060286051A1

公开(公告)日：2006-12-21

申请号：US11117329

申请日：2005-04-29

申请人： Atsushi Tanaka ,  Tsuguo Koyanagi

发明人： Atsushi Tanaka ,  Tsuguo Koyanagi

IPC分类号： A61K8/29 ,  A61K8/28

CPC分类号： A61K8/28 ,  A61K8/25 ,  A61K8/29 ,  A61L9/01 ,  A61Q15/00

摘要： Present invention provides an antibacterial deodorant with antibacterial characteristics and high deodorizing capability. The antibacterial deodorant is inorganic oxide particles comprising a metal component and an inorganic oxide other than the metal component, the inorganic oxide includes titanium oxide and silica and/or zirconia, and the titanium oxide is crystalline titanium oxide. A content of the metal component in the inorganic oxide particles is in a range from 0.1 to 30% by weight as converted to an oxide thereof, and an average particle diameter of the inorganic oxide particle is in a range from 2 to 500 nm.

摘要翻译： 本发明提供具有抗菌特性和高除臭能力的抗菌除臭剂。 抗菌除臭剂是包含除金属成分以外的金属成分和无机氧化物的无机氧化物粒子，无机氧化物包括氧化钛和二氧化硅和/或氧化锆，氧化钛为结晶性氧化钛。 无机氧化物粒子中的金属成分的含量为0.1〜30重量％，其氧化物为无机氧化物粒子的平均粒径为2〜500nm的范围。

公开(公告)号：US20050031924A1

公开(公告)日：2005-02-10

申请号：US10495371

申请日：2002-11-08

申请人： Katsuhiro Shirono ,  Tsuguo Koyanagi ,  Michio Komatsu

发明人： Katsuhiro Shirono ,  Tsuguo Koyanagi ,  Michio Komatsu

IPC分类号： H01B1/08 ,  H01B1/12 ,  H01M8/10 ,  H01M8/12

CPC分类号： H01B1/122 ,  H01B1/08 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1039 ,  H01M8/1048 ,  Y02P70/56

摘要： The electrolyte membrane according to the present invention comprises inorganic oxide particles having proton conductivity, and an organic resin or an inorganic matrix component. The inorganic oxide particles having proton conductivity preferably comprise hydrated antimony oxide particles represented by the following formula (1) and have an average particle diameter of 5 to 50 nm, and the content of the hydrated antimony oxide particles is preferably in the range of 5 to 80% by weight in terms of an oxide (Sb2O5); Sb2O5.nH2O  (1)wherein n is 0.1 to 5. By the use of the electrolyte membrane of the present invention, a fuel cell exhibiting high cell performance even in a prolonged operation and/or an operation at high temperature can be obtained.

摘要翻译： 根据本发明的电解质膜包括具有质子传导性的无机氧化物颗粒和有机树脂或无机基质组分。 具有质子传导性的无机氧化物粒子优选含有下述式（1）所示的水合氧化锑粒子，其平均粒径为5〜50nm，水合氧化锑粒子的含量优选为5〜 80重量％的氧化物（Sb 2 O 5）; Sb 2 O 5·nH 2 O（1）其中n为0.1至5.通过使用本发明的电解质膜，可以获得即使在长时间运行和/或高温操作下也具有高电池性能的燃料电池。

公开(公告)号：US06586104B2

公开(公告)日：2003-07-01

申请号：US09011886

申请日：1998-02-23

申请人： Masayuki Matsuda ,  Nobuaki Yoshida ,  Tsuguo Koyanagi ,  Michio Komatsu

发明人： Masayuki Matsuda ,  Nobuaki Yoshida ,  Tsuguo Koyanagi ,  Michio Komatsu

IPC分类号： B32B900

CPC分类号： C09D183/04 ,  C08G77/58 ,  C09D183/14 ,  Y10T428/31663 ,  C08L2666/54

摘要： A coating liquid for forming a transparent coating comprising fine particles of an inorganic compound and a hydrolyzate of an organosilicon compound represented by the general formula (I): RnSi(OR′)4−n  (I) wherein R and R′ represent organic groups which may be identical to each other or different from each other, and n is an integer of 1 to 3. This coating liquid ensures excellent substrate wettability and compatibility with various organic solvents so that the printability and applicability thereof are desirable, with the result that a transparent coating film of high uniformity, for example, a flattening coating film, can be formed. The present invention comprises a substrate having a transparent coating film formed on the substrate surface from the above coating liquid.

摘要翻译： 一种用于形成透明涂层的涂布液，其包含无机化合物的细颗粒和由通式（I）表示的有机硅化合物的水解产物：其中R和R'表示可以彼此相同或不同于每个的有机基团 其它，n为1〜3的整数。这种涂布液确保了优异的基材润湿性和与各种有机溶剂的相容性，使得其可印刷性和适用性是期望的，结果是具有高均匀性的透明涂膜， 可以形成平坦化的涂膜。 本发明包括具有在上述涂布液体上形成在基板表面上的透明涂膜的基板。

公开(公告)号：US06359667B1

公开(公告)日：2002-03-19

申请号：US09601826

申请日：2000-08-08

申请人： Tsuguo Koyanagi ,  Michio Komatsu ,  Kazuhiro Nakayama

发明人： Tsuguo Koyanagi ,  Michio Komatsu ,  Kazuhiro Nakayama

IPC分类号： G02F11343

CPC分类号： C08G77/06 ,  C08G77/16 ,  G02F1/13392

摘要： An organopolysiloxane fine particle comprising as a principal component a polysiloxane having a hydrocarbon group (a) directly bonded to a silicon atom and having an OH group (b) directly bonded to a silicon atom, wherein: (i) carbons contained in the hydrocarbon group (a) constitute 5 to 35% of the weight of the organopolysiloxane fine particles, and (ii) the OH group (b) is in an amount of 1 to 8 meq per g of the organopolysiloxane fine particles, the organopolysiloxane fine particles having: (iii) a 10% compressive modulus of elasticity of 150 to 900 Kg/mm2, (iv) an average compressive deformation (Cr)m of 20 to 60%, (v) an average elastic recovery (Rr)m of 60 to 90%, and (vi) an average particle diameter of 0.5 to 50 &mgr;m. With respect to this organopolysiloxane fine particle, besides the requirements (i) to (vi), it is preferred that the statistical dispersion of the 10% compressive modulus of elasticity of the organopolysiloxane fine particle fall in the range ±20% based on an average of the 10% compressive modulus of elasticity. The produced organopolysiloxane fine particle exhibits a low aggregation ratio and an extremely sharp particle diameter distribution. The compressive modulus of elasticity, elastic recovery and compressive deformation thereof are high, and the statistical dispersion of compressive deformation is small. Moreover, the organopolysiloxane fine particle is excellent in the spreadabillty on a base. Therefore, the organopolysiloxane fine particles are suitable for use as a spacer fine particle to be incorporated in, for example, a liquid crystal cell.

摘要翻译： 1.一种有机聚硅氧烷微粒，其特征在于，含有与硅原子直接结合且具有与硅原子直接结合的OH基（b））的具有烃基（a）的聚硅氧烷作为主要成分，其中：（i）烃基中含有的碳 （a）占有机聚硅氧烷细颗粒重量的5〜35％，（ii）OH基（b）的量为1〜8meq / g有机聚硅氧烷细粒，有机聚硅氧烷微粒具有： （iii）10％压缩弹性模量为150至900kg / mm 2，（iv）平均压缩变形（Cr）m为20至60％，（v）平均弹性回复率（Rr）m为60至90 ％，和（vi）平均粒径为0.5〜50μm。对于该有机聚硅氧烷细粒子，除了要求（i）〜（vi）以外，优选10％的压缩弹性模量的统计分散 的有机聚硅氧烷细粒的平均值在±20％的范围内 10％的压缩弹性模量。所生产的有机聚硅氧烷细颗粒具有低聚集比和非常尖锐的粒径分布。 压缩弹性模量，弹性恢复和压缩变形均较高，压缩变形的统计分散性较小。 此外，有机聚硅氧烷细粒在基材上的扩展性优异。 因此，有机聚硅氧烷微粒适合用作例如液晶单元中的间隔物微粒。

公开(公告)号：US06294230B1

公开(公告)日：2001-09-25

申请号：US09380326

申请日：1999-08-27

申请人： Tsuguo Koyanagi ,  Kazuhiro Nakayama ,  Yutaka Mitsuo ,  Mitsuru Nakai ,  Michio Komatsu

发明人： Tsuguo Koyanagi ,  Kazuhiro Nakayama ,  Yutaka Mitsuo ,  Mitsuru Nakai ,  Michio Komatsu

IPC分类号： B23B702

CPC分类号： G02F1/13392 ,  Y10T428/1068 ,  Y10T428/2995

摘要： The present invention relates to spherical laminated particles each comprising a core particle and a laminate part disposed on a surface of the core particle, wherein the laminate part has a compressive modulus which is smaller than that of the core particle. These spherical laminated particles have a large compressive strength and is excellent in the recovery from a deformation by an arbitrary load, when the load is removed afterwward, as compared with conventional elastic particles composed of a single substance. Therefore, the use of these spherical laminated particles as spacers minimizes the difference in extent of displacement of spacer particles attributed to the difference in load on individual spacer particles caused by, for example, the waviness of a substrate for liquid crystal display cell during the manufacturing of the liquid crystal display cell, so that the cell gap uniformity can be ensured.

摘要翻译： 本发明涉及一种球形层叠体，其中，所述球形层叠体各自具有核心粒子和设置在所述核心粒子表面的层叠部，其中，所述层叠部的压缩弹性模量小于所述核心粒子的压缩弹性模量。 这些球形层压颗粒具有较大的抗压强度，与常规的由单一物质组成的弹性颗粒相比，当与负载相反地消除负载后的变形恢复性优异。 因此，使用这些球形层叠颗粒作为隔离物，由于在制造过程中由于例如液晶显示单元的基板的波纹引起的各个间隔物颗粒上的负荷差引起的间隔物颗粒的位移程度的差异最小化 的液晶显示单元，从而可以确保单元间隙的均匀性。

公开(公告)号：US20090226627A1

公开(公告)日：2009-09-10

申请号：US12305521

申请日：2007-06-18

申请人： Katsuhiro Shirono ,  Takaki Mizuno ,  Tsuguo Koyanagi

发明人： Katsuhiro Shirono ,  Takaki Mizuno ,  Tsuguo Koyanagi

IPC分类号： B01J19/08

CPC分类号： C25D13/02

摘要： A method for forming a metal oxide fine particle layer, by which a metal oxide fine particle layer having uniformity and excellent in adhesion, abrasion resistance, strength, etc. can be formed easily compared with the conventional plating method, CVD method, liquid coating method, electrodeposition method or the like. The method comprises immersing a conductive substrate in a dispersion of metal oxide fine particles and fibrous fine particles and applying a direct-current voltage to the conductive substrate and the dispersion. The fibrous fine particles have a length (L) of 50 nm to 10 μm, a diameter (D) of 10 nm to 2 μm and an aspect ratio (L)/(D) of 5 to 1,000. The content of the fibrous fine particles in the dispersion is in the range of 0.1 to 20% by weight in terms of solids content, based on the metal oxide fine particles.

摘要翻译： 与传统的镀覆方法，CVD法，液体涂布法相比，可以容易地形成金属氧化物微粒层的形成方法，通过该方法可以形成均匀性和粘附性，耐磨性，强度等优异的金属氧化物微粒层 ，电沉积法等。 该方法包括将导电基底浸入金属氧化物细颗粒和纤维状细颗粒的分散体中，并向导电基材和分散体施加直流电压。 纤维状微粒的长度（L）为50nm〜10μm，直径（D）为10nm〜2μm，纵横比（L）/（D）为5〜1000。 基于金属氧化物微粒，分散体中的纤维状微粒的含量以固体成分计为0.1〜20重量％。