公开(公告)号：US20120083538A1

公开(公告)日：2012-04-05

申请号：US12897584

申请日：2010-10-04

申请人： Valerii Kukhar ,  Valeriy Bortyshevskyy ,  Nataliia Khimach ,  Viktor Burdeynyy ,  Rayisa Korzh ,  Svitlana Melnykova ,  Dmytro Kamens'kyh

发明人： Valerii Kukhar ,  Valeriy Bortyshevskyy ,  Nataliia Khimach ,  Viktor Burdeynyy ,  Rayisa Korzh ,  Svitlana Melnykova ,  Dmytro Kamens'kyh

IPC分类号： C07C27/00 ,  B01J19/08

CPC分类号： B01J8/0005 ,  B01J8/0045 ,  B01J8/20 ,  B01J8/26 ,  B01J8/382 ,  B01J8/386 ,  B01J8/42 ,  B01J2219/00006 ,  B01J2219/0004 ,  B01J2219/00103 ,  C10L1/02 ,  C10L9/086

摘要： A method and apparatus for the generation of synthetic motor fuels and additives to oil fuels, C1-C4 alcohols, hydrogen, methane, synthesized gas (H2+CO2) by hydrothermal treatment of carbonaceous compounds by providing a two-stage carbon gasification process operated under the supercritical conditions of H2O and CO2, including a first stage gasification reactor having a reaction zone for the conversion of carbonaceous compounds and a second stage reactor for the conversion of the products of the first stage reactor; feeding a aqueous suspension of carbonaceous compound in an amount of at least 30% by weight and an alkali metal or alkaline-earth metal catalyst or reactive OH— species from an electrolyzer through said first stage gasification reactor as a supercritical fluid at a volume velocity of 0.01-0.05 g of carbon per 1 cm3 per hour, at a carbon/catalyst mole ratio of between about 70/1 and 90/1, at a temperature of 390-450° C., and under a pressure of about 225 to 500 bars; feeding the reaction products from the first stage reactor to the second stage reactor over a copper-zinc catalyst at the temperature of 200-280° C. and under a pressure of at least about 100 bars so that any gases generated in the first stage are converted into C1-C4 alcohols with the weight ratio of C1-C2 to C3-C4 between about 0-35% to 100-65%.

摘要翻译： 一种通过提供在二氧化碳气化过程中运行的碳酸化合物的水热处理来生成合成汽油燃料和添加剂的方法和装置，用于生产油燃料，C 1 -C 4醇，氢气，甲烷，合成气（H 2 + CO 2） H 2 O和CO 2的超临界条件，包括具有用于转化碳质化合物的反应区的第一级气化反应器和用于转化第一级反应器产物的第二级反应器; 将至少30重量％的含碳化合物的水悬浮液和来自电解槽的碱金属或碱土金属催化剂或反应性OH-物质作为超临界流体通过所述第一级气化反应器以体积速度 0.01-0.05g碳/ 1cm 3 /小时，碳/催化剂摩尔比为约70/1至90/1之间，温度为390-450℃，压力为约225至500 酒吧 在200-280℃的温度和至少约100巴的压力下通过铜 - 锌催化剂将反应产物从第一阶段反应器进料到第二阶段反应器，使得在第一阶段中产生的任何气体为 转化为C 1 -C 4醇，其中C 1 -C 2至C 3 -C 4的重量比在约0-35％至100-65％之间。

公开(公告)号：US08536234B2

公开(公告)日：2013-09-17

申请号：US12897584

申请日：2010-10-04

申请人： Valerii Kukhar ,  Valeriy Bortyshevskyy ,  Nataliia Khimach ,  Viktor Burdeynyy ,  Rayisa Korzh ,  Svitlana Melnykova ,  Dmytro Kamens'kyh

发明人： Valerii Kukhar ,  Valeriy Bortyshevskyy ,  Nataliia Khimach ,  Viktor Burdeynyy ,  Rayisa Korzh ,  Svitlana Melnykova ,  Dmytro Kamens'kyh

IPC分类号： C07C27/00

CPC分类号： B01J8/0005 ,  B01J8/0045 ,  B01J8/20 ,  B01J8/26 ,  B01J8/382 ,  B01J8/386 ,  B01J8/42 ,  B01J2219/00006 ,  B01J2219/0004 ,  B01J2219/00103 ,  C10L1/02 ,  C10L9/086

摘要： A method and apparatus for the generation of synthetic motor fuels and additives to oil fuels, C1-C4 alcohols, hydrogen, methane, synthesized gas (H2+CO2) by hydrothermal treatment of carbonaceous compounds by providing a two-stage carbon gasification process operated under the supercritical conditions of H2O and CO2, including a first stage gasification reactor having a reaction zone for the conversion of carbonaceous compounds and a second stage reactor for the conversion of the products of the first stage reactor; feeding a aqueous suspension of carbonaceous compound in an amount of at least 30% by weight and an alkali metal or alkaline-earth metal catalyst or reactive OH-species from an electrolyzer through said first stage gasification reactor as a supercritical fluid at a volume velocity of 0.01-0.05 g of carbon per 1 cm3 per hour, at a carbon/catalyst mole ratio of between about 70/1 and 90/1, at a temperature of 390-450° C., and under a pressure of about 225 to 500 bars; feeding the reaction products from the first stage reactor to the second stage reactor over a copper-zinc catalyst at the temperature of 200-280° C. and under a pressure of at least about 100 bars so that any gases generated in the first stage are converted into C1-C4 alcohols with the weight ratio of C1-C2 to C3-C4 between about 0-35% to 100-65%.

摘要翻译： 一种通过提供在二氧化碳气化过程中运行的碳酸化合物的水热处理来生成合成汽油燃料和添加剂的方法和装置，用于生产油燃料，C 1 -C 4醇，氢气，甲烷，合成气体（H 2 + CO 2） H 2 O和CO 2的超临界条件，包括具有用于转化碳质化合物的反应区的第一级气化反应器和用于转化第一级反应器产物的第二级反应器; 将至少30重量％的含碳化合物的水悬浮液和来自电解槽的碱金属或碱土金属催化剂或反应性OH-物质作为超临界流体通过所述第一级气化反应器以体积速度 0.01-0.05g碳/ 1cm 3 /小时，碳/催化剂摩尔比为约70/1至90/1之间，温度为390-450℃，压力为约225至500 酒吧 在200-280℃的温度和至少约100巴的压力下通过铜 - 锌催化剂将反应产物从第一阶段反应器进料到第二阶段反应器，使得在第一阶段中产生的任何气体为 转化为C 1 -C 4醇，其中C 1 -C 2至C 3 -C 4的重量比在约0-35％至100-65％之间。