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公开(公告)号：US5558771A
公开(公告)日：1996-09-24
申请号：US566554
申请日：1995-12-04
CPC分类号： B01J20/28028 , B01D15/00 , B01D53/64 , B01J20/103 , B01J20/28059 , B01J20/3234 , Y10S210/914
摘要： Composite articles are useful for separating mercury from fluids. The composite articles can be porous supports comprising an inert substrate having immobilized thereon finely divided gold optionally in combination with a tin salt coating. The porous support can be a particulate or porous fibrous webs. Alternatively, the composite articles can comprise a porous fibrous membrane having enmeshed therein the aforementioned porous supports which can be in particulate or fibrous forms. The method for separating elemental, ionic, or organic mercury in fluids comprises the step of contacting and passing a fluid containing mercury through a support comprising a porous, high surface area, inert substrate on which is immobilized finely divided elemental gold at a controlled rate for a time sufficient for the mercury to sorb to the elemental gold and to provide an immobilized gold-mercury amalgam on the support. If a tin salt also is immobilized on the inert substrate, mercury-tin salt can also be formed. In a further, and optional, step, elemental mercury can be removed from the support and optionally can be quantified.
摘要翻译： 复合制品可用于从流体中分离汞。 复合制品可以是多孔载体，其包括其上固定有细碎金的惰性基材，任选与锡盐涂层组合。 多孔载体可以是颗粒或多孔纤维网。 或者，复合制品可以包括多孔纤维膜，其中包含可以是颗粒或纤维形式的上述多孔载体。 用于分离流体中的元素，离子或有机汞的方法包括使包含汞的流体通过包含多孔，高表面积的惰性基质的载体接触和通过的步骤，在其上以受控的速率将细分的元素金固定在其上 足以使汞吸附到元素金上并在载体上提供固定的金汞汞合金。 如果锡盐也固定在惰性基材上，也可以形成汞锡盐。 在另外的和任选的步骤中，元素汞可以从支持物中除去并且可任选地被定量。
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公开(公告)号：US5492627A
公开(公告)日：1996-02-20
申请号：US268286
申请日：1994-06-29
CPC分类号： B01J20/28028 , B01D15/00 , B01D53/64 , B01J20/103 , B01J20/28059 , B01J20/3234 , Y10S210/914
摘要： Composite articles are useful for separating mercury from fluids. The composite articles can be porous supports comprising an inert substrate having immobilized thereon finely divided gold optionally in combination with a tin salt coating. The porous support can be a particulate or porous fibrous webs. Alternatively, the composite articles can comprise a porous fibrous membrane having enmeshed therein the aforementioned porous supports which can be in particulate or fibrous forms. The method for separating elemental, ionic, or organic mercury in fluids comprises the step of contacting and passing a fluid containing mercury through a support comprising a porous, high surface area, inert substrate on which is immobilized finely divided elemental gold at a controlled rate for a time sufficient for the mercury to sorb to the elemental gold and to provide an immobilized gold-mercury amalgam on the support. If a tin salt also is immobilized on the inert substrate, mercury-tin salt can also be formed. In a further, and optional, step, elemental mercury can be removed from the support and optionally can be quantified.
摘要翻译： 复合制品可用于从流体中分离汞。 复合制品可以是多孔载体，其包括其上固定有细碎金的惰性基材，任选与锡盐涂层组合。 多孔载体可以是颗粒或多孔纤维网。 或者，复合制品可以包括多孔纤维膜，其中包含可以是颗粒或纤维形式的上述多孔载体。 用于分离流体中的元素，离子或有机汞的方法包括使包含汞的流体通过包含多孔，高表面积的惰性基质的载体接触和通过的步骤，在其上以受控的速率将细分的元素金固定在其上 足以使汞吸附到元素金上并在载体上提供固定的金汞汞合金。 如果锡盐也固定在惰性基材上，也可以形成汞锡盐。 在另外的和任选的步骤中，元素汞可以从支持物中除去并且可任选地被定量。
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