公开(公告)号：US07674508B2

公开(公告)日：2010-03-09

申请号：US11980599

申请日：2007-10-31

申请人： Yasuhiro Kubo

发明人： Yasuhiro Kubo

IPC分类号： C09K19/30 ,  C09K19/12

CPC分类号： C09K19/44 ,  C09K19/12 ,  C09K2019/0444 ,  C09K2019/123 ,  C09K2019/3016 ,  C09K2019/3019 ,  Y10T428/10

摘要： A liquid crystal composition having a nematic phase that includes two components, wherein the first component is at least one compound selected from the group of compounds represented by formulas (1-1) and (1-2), and the second component is at least one compound selected from the group of compounds having a group represented by formulas (2-1) and (2-2): wherein R1 is alkyl having 1 to 12 carbons; Z1 and Z2 are each independently a single bond or ethylene; X1 is independently fluorine, chlorine, OCF3 or OCF2H; Y1 is independently hydrogen or fluorine; and n is independently 1 or 2.

摘要翻译： 一种液晶组合物，其具有向列相，其包含两种成分，其中所述第一成分为选自式（1-1）和（1-2）所示的化合物的族群中的至少一种化合物，第二成分为至少 一种选自具有由式（2-1）和（2-2）表示的基团的化合物的化合物：其中R1是具有1至12个碳原子的烷基; Z 1和Z 2各自独立地为单键或亚乙基; X1独立地为氟，氯，OCF 3或OCF 2 H; Y1独立地是氢或氟; 且n独立地为1或2。

公开(公告)号：US07452576B2

公开(公告)日：2008-11-18

申请号：US11642650

申请日：2006-12-21

申请人： Yasuhiro Kubo

发明人： Yasuhiro Kubo

IPC分类号： C09K19/34 ,  C09K19/30 ,  C09K19/20

CPC分类号： C09K19/46 ,  C09K19/3402 ,  C09K2019/0466 ,  C09K2019/3422 ,  Y10T428/10

摘要： A liquid crystal composition, and a liquid crystal display containing the same, having a nematic phase including three components, wherein the first component is at least one compound selected from the group of compounds represented by formula (1), the second component is at least one compound selected from the group of compounds represented by formula (2), and the third component is at least one compound selected from the group of compounds represented by formula (3): wherein R1 and R2 are each independently alkyl having approximately 1 to approximately 12 carbons or alkenyl having approximately 2 to approximately 12 carbons; R3 is alkyl having approximately 1 to approximately 12 carbons or alkoxy having approximately 1 to approximately 12 carbons; R4 and R5 are each independently alkyl having approximately 1 to approximately 12 carbons; X1 is fluorine, chlorine, —OCF2H, —CF3 or —OCF3; Y1 is hydrogen or fluorine; and m and n are each independently 0 or 1.

摘要翻译： 一种液晶组合物和含有该液晶组合物的液晶显示器，其具有包含三个组分的向列相，其中第一组分是选自式（1）表示的化合物组中的至少一种化合物，第二组分至少为 一种选自由式（2）表示的化合物的化合物，第三组分是选自式（3）表示的化合物中的至少一种化合物：其中R 1和R 2， 各自独立地为具有约1至约12个碳的烷基或具有约2至约12个碳的烯基; R 3是具有约1至约12个碳的烷基或具有约1至约12个碳的烷氧基; R 4和R 5各自独立地为具有约1至约12个碳的烷基; X 1是氟，氯，-OCF 2 H，-CF 3或-OCF 3 3; Y 1是氢或氟; m和n各自独立地为0或1。

公开(公告)号：US20070145331A1

公开(公告)日：2007-06-28

申请号：US11642650

申请日：2006-12-21

申请人： Yasuhiro Kubo

发明人： Yasuhiro Kubo

IPC分类号： C09K19/34 ,  C09K19/30 ,  C09K19/20

CPC分类号： C09K19/46 ,  C09K19/3402 ,  C09K2019/0466 ,  C09K2019/3422 ,  Y10T428/10

摘要： A liquid crystal composition, and a liquid crystal display containing the same, having a nematic phase including three components, wherein the first component is at least one compound selected from the group of compounds represented by formula (1), the second component is at least one compound selected from the group of compounds represented by formula (2), and the third component is at least one compound selected from the group of compounds represented by formula (3): wherein R1 and R2 are each independently alkyl having approximately 1 to approximately 12 carbons or alkenyl having approximately 2 to approximately 12 carbons; R3 is alkyl having approximately 1 to approximately 12 carbons or alkoxy having approximately 1 to approximately 12 carbons; R4 and R5 are each independently alkyl having approximately 1 to approximately 12 carbons; X1 is fluorine, chlorine, —OCF2H, —CF3 or —OCF3; Y1 is hydrogen or fluorine; and m and n are each independently 0 or 1.

摘要翻译： 一种液晶组合物和含有该液晶组合物的液晶显示器，其具有包含三个组分的向列相，其中第一组分是选自式（1）表示的化合物组中的至少一种化合物，第二组分至少为 一种选自由式（2）表示的化合物的化合物，第三组分是选自式（3）表示的化合物中的至少一种化合物：其中R 1和R 2， 各自独立地为具有约1至约12个碳的烷基或具有约2至约12个碳的烯基; R 3是具有约1至约12个碳的烷基或具有约1至约12个碳的烷氧基; R 4和R 5各自独立地为具有约1至约12个碳的烷基; X 1是氟，氯，-OCF 2 H，-CF 3或-OCF 3 3; Y 1是氢或氟; m和n各自独立地为0或1。

公开(公告)号：US07081279B2

公开(公告)日：2006-07-25

申请号：US10650765

申请日：2003-08-29

申请人： Takashi Kato ,  Tomoyuki Kondo ,  Henry Bernhardt ,  Shuichi Matsui ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Fusayuki Takeshita ,  Etsuo Nakagawa

发明人： Takashi Kato ,  Tomoyuki Kondo ,  Henry Bernhardt ,  Shuichi Matsui ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Fusayuki Takeshita ,  Etsuo Nakagawa

IPC分类号： C09K19/34 ,  C09K19/30 ,  C09K19/32 ,  C09K19/12 ,  C07C43/225

CPC分类号： C09K19/3491 ,  C07C17/2635 ,  C07C25/18 ,  C07C25/24 ,  C07C45/515 ,  C07C45/60 ,  C07F7/0896 ,  C09K19/0403 ,  C09K19/12 ,  C09K19/3001 ,  C09K19/3003 ,  C09K19/3402 ,  C09K19/3444 ,  C09K19/3458 ,  C09K19/406 ,  C09K19/42 ,  C09K2019/0407 ,  C09K2019/0444 ,  C09K2019/3027 ,  C09K2019/3422 ,  Y10T428/10 ,  C07C49/753 ,  C07C47/277

摘要： Liquid crystalline compounds having a large negative Δε low viscosity, a large K33/K11 value, a small Δε/Δ⊥ and mutually excellent solubility even at low temperature, compositions containing at least one of the compounds and liquid crystal display devices containing such a liquid crystal compositions are disclosed.

摘要翻译： 具有较大的负值Deltaepsilon低粘度，较大的K 33 / K 11值的小晶体化合物，即使在低温下也具有相当优异的溶解度，组成 含有至少一种化合物和含有这种液晶组合物的液晶显示装置。

公开(公告)号：US06759102B2

公开(公告)日：2004-07-06

申请号：US10132854

申请日：2002-04-26

申请人： Katsuyuki Murashiro ,  Yasuhiro Kubo

发明人： Katsuyuki Murashiro ,  Yasuhiro Kubo

IPC分类号： C09K1930

CPC分类号： C09K19/46 ,  C09K19/42 ,  C09K19/44 ,  Y10T428/10 ,  Y10T428/1036

摘要： Liquid crystal compositions which comprise as a first component at least one compound selected from the group of compounds represented by the formula (I) and as a second component at least one compound selected from the group of compounds represented by the formula (II), the content of the first component being not less than 30% by weight based on the total weight of the composition wherein R1 and R3 are independently an alkyl of 1 to 10 carbon atoms and any —CH2— in the alkyl may be replaced by —O— or —CH═CH—; R2 is an alkyl of 1 to 10 carbon atoms, —F or —Cl; X1, X2, X3, X4, X5, X6, X7, X8 and X10 are independently —F or —H; X9 is —F, —Cl, —CF3, —OCF3 or —OCF2H; A1 and A2 are independently 1,4-cyclohexylene, pyrimidine-2,5-diyl or 1,4-phenylene in which any —H may be replaced by —F; Z1 and Z3 are independently a single bond, —(CH2)2— or —(CH2)4—; Z2 is a single bond or —CF2O—; and Z4 is a single bond, —COO— or —CF2O—. These compositions have reduced response time and low threshold voltage, and are used in a liquid crystal display device, especially that of an OCB mode.

摘要翻译： 作为第一成分含有选自式（I）所示化合物的化合物和作为第二成分的至少一种选自式（II）所示的化合物的化合物的化合物的第一成分的液晶组合物， 基于组合物的总重量，第一组分的含量不小于30重量％，其中R 1和R 3独立地是1至10个碳原子的烷基，并且烷基中的任何-CH 2 - 可以是 被-O - 或-CH = CH-取代; R 2是1-10个碳原子的烷基，-F或-Cl; X 1，X 2，X 3，X 4，X 5，X 6，X 7，X 8和X 10独立地为-F或 - H; X 9是-F，-Cl，-CF 3，-OCF 3或-OCF 2 H; A 1和A 2独立地是1,4-亚环己基，嘧啶-2,5-二基或1,4-亚苯基，其中任何-H可被-F代替; Z 1和Z 3独立地是单键， - （CH 2）2 - 或 - （CH 2）4 - ; Z 2是单键或-CF 2 O-; 且Z 4为单键-COO-或-CF 2 O-。 这些组合物具有降低的响应时间和低阈值电压，并且用于液晶显示装置，特别是OCB模式的液晶显示装置中。

公开(公告)号：US06703083B2

公开(公告)日：2004-03-09

申请号：US10084854

申请日：2002-02-28

申请人： Takashi Kato ,  Yasuyuki Koizumi ,  Yasuhiro Kubo ,  Kanetsugu Terashima

发明人： Takashi Kato ,  Yasuyuki Koizumi ,  Yasuhiro Kubo ,  Kanetsugu Terashima

IPC分类号： C09K1934

CPC分类号： C07F7/0896 ,  C09K19/406 ,  Y10T428/10

摘要： Silicon compounds having a low viscosity and a low threshold voltage and improved mutual solubility, a liquid crystal composition comprising the same and a liquid crystal display using the liquid crystal composition. The silicon compound is represented by formula (1): wherein Y1 is, for example, alkylene having 1 to 10 carbon atoms, Y2 is, for example, hydrogen, halogen, —CN, —C≡C—CN, or alkyl having 1 to 10 carbon atoms; A1, A2, A3, and A4 each are, for example, independently 1,4-cyclohexylene, 1,4-cyclohexenylene, 1,4-phenylene, or 1,4-phenylene; Z1, Z2 and Z3 each are independently a single bond, —(CH2)2—, —OCH2—, —CH2O—, —CH═CH—, —C≡C—, —(CH2)4—, —O(CH2)3—, —(CH2)3O—, —COO—, —OCO—, —OCF2—, or —CF2O—; and p and q each are independently 0 or 1.

摘要翻译： 具有低粘度和低阈值电压和改善的互溶性的硅化合物，包含该硅化合物的液晶组合物和使用该液晶组合物的液晶显示器。 硅化合物由式（1）表示：其中Y 1为例如具有1至10个碳原子的亚烷基，Y 2为例如氢，卤素，-CN，-C = C- CN或具有1至10个碳原子的烷基; A 1，A 2，A 3和A 4各自独立地为1,4-亚环己基，1,4-亚环己烯基，1,4-亚苯基或1,4-亚环己基， 亚苯基; Z 1，Z 2和Z 3各自独立地为单键， - （CH 2）2 - ， - OCH 2 - ， - CH 2 O - ， - CH = CH - ， - C = CH2）4-，-O（CH2）3 - ， - （CH2）3O-，-COO-，-OCO-，-OCF2-或-CF2O-; p和q各自独立地为0或1。

公开(公告)号：US06692657B1

公开(公告)日：2004-02-17

申请号：US09323820

申请日：1999-06-02

申请人： Takashi Kato ,  Tomoyuki Kondo ,  Henry Bernhardt ,  Shuichi Matsui ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Fusayuki Takeshita ,  Etsuo Nakagawa

发明人： Takashi Kato ,  Tomoyuki Kondo ,  Henry Bernhardt ,  Shuichi Matsui ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Fusayuki Takeshita ,  Etsuo Nakagawa

IPC分类号： C09K1934

CPC分类号： C09K19/3491 ,  C07C17/2635 ,  C07C25/18 ,  C07C25/24 ,  C07C45/515 ,  C07C45/60 ,  C07F7/0896 ,  C09K19/0403 ,  C09K19/12 ,  C09K19/3001 ,  C09K19/3003 ,  C09K19/3402 ,  C09K19/3444 ,  C09K19/3458 ,  C09K19/406 ,  C09K19/42 ,  C09K2019/0407 ,  C09K2019/0444 ,  C09K2019/3027 ,  C09K2019/3422 ,  Y10T428/10 ,  C07C49/753 ,  C07C47/277

摘要： Liquid crystalline compounds having a large negative &Dgr;∈ low viscosity, a large K33/K11 value, a small &Dgr;∈/&Dgr;⊥ and mutually excellent solubility even at low temperature, compositions containing at least one of the compounds and liquid crystal display devices containing such a liquid crystal compositions are disclosed.

摘要翻译： 具有大的负ΔΔε低粘度，大的K33 / K11值，小的Δε/Δ⊥和即使在低温也相互优异的溶解性的液晶化合物，含有至少一种化合物和含有这些化合物的液晶显示装置 公开了一种液晶组合物。

公开(公告)号：US06596349B2

公开(公告)日：2003-07-22

申请号：US09836315

申请日：2001-04-18

申请人： Tomoyuki Kondou ,  Shuichi Matsui ,  Kazutoshi Miyazawa ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Fusayuki Takeshita ,  Etsuo Nakagawa

发明人： Tomoyuki Kondou ,  Shuichi Matsui ,  Kazutoshi Miyazawa ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Fusayuki Takeshita ,  Etsuo Nakagawa

IPC分类号： C09K1912

CPC分类号： C07C25/18 ,  C07C43/225 ,  C09K19/12 ,  Y10T428/10

摘要： The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties with temperature change, high &Dgr;n, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices made using these liquid crystal compositions. The liquid crystalline compounds are terphenyl derivatives represented by general formula (1): wherein R represents a straight or branched alkyl group of 1-20 carbon atoms, and any methylene groups (—CH2—) not adjacent each other in each alkyl group may be replaced by oxygen atoms; X is a halogen atom, —OCF3, —OCF2H, —CF3, —CF2H or —CFH2; Y1, Y2, Y3, Y4, Y5 and Y6 independently represents H or F, but at least two of Y1, Y2, Y3 and Y4 represent F; and any atom constituting these compounds may be substituted by its isotope.

摘要翻译： 本发明提供具有高电压保持率和低阈值电压的液晶化合物，这些性质与温度变化的变化小，DELTAn高，与其他液晶材料的相容性特别好，在低温下; 含有这些结晶化合物的液晶组合物; 以及使用这些液晶组合物制成的液晶显示装置。 液晶化合物是由通式（1）表示的三联苯衍生物：其中R表示1-20个碳原子的直链或支链烷基，每个烷基中不相邻的任何亚甲基（-CH 2 - ）可以是 被氧原子取代; X是卤素原子，-OCF 3，-OCF 2 H，-CF 3，-CF 2 H或-CFH 2; Y1，Y2，Y3，Y4，Y5和Y6独立地表示H或F，但Y1，Y2，Y3和Y4中的至少两个表示F; 并且构成这些化合物的任何原子可以被其同位素取代。

公开(公告)号：US06572938B2

公开(公告)日：2003-06-03

申请号：US09773536

申请日：2001-02-02

申请人： Motoki Yanai ,  Yasuhiro Kubo ,  Etsuo Nakagawa

发明人： Motoki Yanai ,  Yasuhiro Kubo ,  Etsuo Nakagawa

IPC分类号： C09K1930

CPC分类号： C09K19/42 ,  C09K19/3001 ,  Y10T428/10

摘要： The present invention is to provide a liquid crystal composition which has particularly a high upper limit temperature of a nematic phase, a low lower limit temperature of the nematic phase and a small birefringence while satisfying general characteristics required for the liquid crystal composition for an AM-LCD. Liquid crystal compositions are disclosed which comprise a component I comprising at least one compound selected from the group of compounds represented by Formula (I-1) or (I-2) as described in the specification, a component II comprising at least one compound selected from the group of compounds represented by Formulas (II-1) to (II-8) as described in the specification and a component III comprising at least one compound selected from the group of compounds represented by Formulas (III-1) to (III-5) as described in the specification.

公开(公告)号：US06544604B2

公开(公告)日：2003-04-08

申请号：US09925484

申请日：2001-08-10

申请人： Shuichi Matsui ,  Yasuyuki Sasada ,  Kazutoshi Miyazawa ,  Hiroyuki Takeuchi ,  Katsuyuki Kawano ,  Yasuhiro Kubo ,  Etsuo Nakagawa ,  Mayumi Furuya

发明人： Shuichi Matsui ,  Yasuyuki Sasada ,  Kazutoshi Miyazawa ,  Hiroyuki Takeuchi ,  Katsuyuki Kawano ,  Yasuhiro Kubo ,  Etsuo Nakagawa ,  Mayumi Furuya

IPC分类号： C09K1934

CPC分类号： C09K19/46 ,  C09K19/20 ,  C09K19/3001 ,  C09K19/3066 ,  C09K19/42 ,  C09K19/44 ,  C09K2019/0448 ,  C09K2019/0451 ,  C09K2019/3027 ,  Y10T428/10

摘要： The present invention provides a liquid crystalline compound having a difluoropropyleneoxy group as a bonding group, which is represented by Formula (1): wherein R1 and R2 each independently represent hydrogen, halogen, a cyano group or an alkyl group having 1 to 20 carbon atoms; rings A1 to A5 each independently represent a 1,4-cyclohexylene group, a 1,4-cyclohexenylene group or a 1,4-phenylene group; Z1 to Z4 each independently represent a single bond, —CH2CH2—, —CH2O—, —OCH2—, —COO—, —OCO—, —CH═CH—, —C≡C—, —CF2O— or —OCF2—; Y1, Y2, Y3 and Y4 each independently represent hydrogen or fluorine; and k, l, m and n each independently represent 0 or 1. This liquid crystalline compound has a large absolute value (|&Dgr;&egr;|) of a dielectric anisotropy and shows a relatively small refractive anisotropy. The present invention further provides a liquid crystal composition comprising this compound which makes it possible to drive display elements of various modes at a low voltage, and a liquid crystal display element containing this liquid crystal composition.

摘要翻译： 本发明提供具有二氟亚丙氧基作为键合基团的液晶化合物，其由式（1）表示：其中R 1和R 2各自独立地表示氢，卤素，氰基或具有1至20个碳原子的烷基 ; 环A1至A5各自独立地表示1,4-亚环己基，1,4-亚环己基或1,4-亚苯基; Z 1至Z 4各自独立地表示单键，-CH 2 CH 2 - ， - CH 2 O - ， - OCH 2 - ， - COO - ， - OCO-， - CH = CH-，-C = C - ， - CF 2 O-或-OCF 2 - Y 1，Y 2，Y 3和Y 4各自独立地表示氢或氟; 并且k，l，m和n各自独立地表示0或1.该液晶化合物的介电各向异性的绝对值（| DELTAepsi |）大，折射率各向异性相对较小。 本发明还提供一种包含该化合物的液晶组合物，其可以驱动低电压的各种模式的显示元件，以及含有该液晶组合物的液晶显示元件。