公开(公告)号：US09840529B2

公开(公告)日：2017-12-12

申请号：US15037824

申请日：2014-10-14

申请人： Yoshiaki Nishibayashi ,  Masahiro Yuki ,  Haruyuki Nakanishi

发明人： Yoshiaki Nishibayashi ,  Masahiro Yuki ,  Haruyuki Nakanishi

IPC分类号： C07F15/00 ,  C07F17/02 ,  B01J31/22 ,  C07C309/06 ,  H01M4/90 ,  H01M8/18 ,  H01M8/20 ,  H01M4/86

CPC分类号： C07F17/02 ,  B01J31/22 ,  C07C309/06 ,  H01M4/9008 ,  H01M8/1007 ,  H01M8/188 ,  H01M8/20 ,  H01M2004/8684

摘要： The present invention is to provide a hydrogen oxidation catalyst that does not contain platinum. Disclosed is a hydrogen oxidation catalyst that is a dinuclear transition metal complex having a chemical structure represented by the following general formula (1) or (2): wherein, in the general formulae (1) and (2), M1 and M2 are each independently Fe or Ru; Ar1 and Ar2 are each independently a cyclopentadienyl group or a pentamethylcyclopentadienyl group; Ar3 and Ar4 are each independently a divalent aromatic hydrocarbon group having 6 to 12 carbon atoms; and Ar5 is a monovalent aromatic hydrocarbon group having 6 to 12 carbon atoms, and in the general formula (2), R1 and R2 are each independently a hydrogen atom or a monovalent aliphatic hydrocarbon group having 1 to 3 carbon atoms.

公开(公告)号：US20160289254A1

公开(公告)日：2016-10-06

申请号：US15037824

申请日：2014-10-14

申请人： Yoshiaki NISHIBAYASHI ,  Masahiro YUKI ,  Haruyuki NAKANISHI

发明人： Yoshiaki NISHIBAYASHI ,  Masahiro YUKI ,  Haruyuki NAKANISHI

IPC分类号： C07F17/02 ,  H01M8/20 ,  H01M8/18 ,  H01M4/90 ,  C07C309/06

CPC分类号： C07F17/02 ,  B01J31/22 ,  C07C309/06 ,  H01M4/9008 ,  H01M8/1007 ,  H01M8/188 ,  H01M8/20 ,  H01M2004/8684

摘要： The present invention is to provide a hydrogen oxidation catalyst that does not contain platinum. Disclosed is a hydrogen oxidation catalyst that is a dinuclear transition metal complex having a chemical structure represented by the following general formula (1) or (2): wherein, in the general formulae (1) and (2), M1 and M2 are each independently Fe or Ru; Ar1 and Ar2 are each independently a cyclopentadienyl group or a pentamethylcyclopentadienyl group; Ar3 and Ar4 are each independently a divalent aromatic hydrocarbon group having 6 to 12 carbon atoms; and Ar5 is a monovalent aromatic hydrocarbon group having 6 to 12 carbon atoms, and in the general formula (2), R1 and R2 are each independently a hydrogen atom or a monovalent aliphatic hydrocarbon group having 1 to 3 carbon atoms.

摘要翻译： 其中，在通式（1）和（2）中，M1和M2各自独立地为Fe或Ru; Ar 1和Ar 2各自独立地为环戊二烯基或五甲基环戊二烯基; Ar 3和Ar 4各自独立地为具有6至12个碳原子的二价芳族烃基; Ar 5为碳原子数6〜12的一价芳香族烃基，通式（2）中，R 1和R 2各自独立地为氢原子或碳原子数为1〜3的一价脂肪族烃基。