公开(公告)号：US4454329A

公开(公告)日：1984-06-12

申请号：US279650

申请日：1981-07-02

申请人： Yoshiaki Takagi ,  Yoshinori Kai

发明人： Yoshiaki Takagi ,  Yoshinori Kai

IPC分类号： C07D311/72

CPC分类号： C07D311/72

摘要： A tocopherol concentrate having a high tocopherol concentration can be obtained in a high yield by subjecting a deodorized distillate formed as a by-product at the step of deodorizing oils and fats to esterification of free fatty acids by addition of an alcohol or removal of free fatty acids by distillation and then to hydrogenation. A tocopherol concentrate can also be obtained by subjecting a deodorized distillate to esterification by addition of a polyhydric alcohol and then to distillation. Concentrates having a high concentration and a high quality can be obtained in a high yield with a good operation efficiency.

摘要翻译： 通过在除油和脂肪除臭步骤中形成的副产物脱臭馏出物通过加入醇或除去游离脂肪来酯化游离脂肪酸，可以高收率地获得具有高生育酚浓度的生育酚浓缩物 酸通过蒸馏然后氢化。 还可以通过加入多元醇使除臭的馏出物进行酯化，然后进行蒸馏来获得生育酚浓缩物。 可以以高产率以良好的操作效率获得高浓度和高质量的浓缩物。

公开(公告)号：US4321210A

公开(公告)日：1982-03-23

申请号：US263823

申请日：1981-05-15

申请人： Yoshinori Kai ,  Everett H. Pryde

发明人： Yoshinori Kai ,  Everett H. Pryde

IPC分类号： C07C69/602 ,  B01J23/00 ,  C07B31/00 ,  C07B37/08 ,  C07C51/00 ,  C07C51/353 ,  C07C57/03 ,  C07C67/00 ,  C09F7/00 ,  C11C3/12 ,  C11C3/14

CPC分类号： C11C3/14 ,  C11C3/126

摘要： Cyclopropenoid compounds such as malvalic and sterculic fatty acids found in sterculia oil are rearranged substantially quantitatively to conjugated dienes when heated in the presence of a rhodium catalyst. The dienes can thereafter be reduced to the corresponding branched chain derivatives by means of hydrogenation with the same catalyst. Both the diene and branched derivatives have application in the production of plastics, coatings, lubricants, soaps, cosmetics, and other commercial products.

摘要翻译： 当在铑催化剂存在下加热时，在甾醇油中发现的环丙烷类化合物如马来酸和甾醇脂肪酸基本上定量地重组成共轭二烯。 之后，二烯可以通过用相同的催化剂氢化而还原成相应的支链衍生物。 二烯和支链衍生物都可用于生产塑料，涂料，润滑剂，肥皂，化妆品和其他商业产品。