Process for preparing (meth)acrylates of C17-alcohol mixtures
    3.
    发明授权
    Process for preparing (meth)acrylates of C17-alcohol mixtures 有权
    制备C17-醇混合物的(甲基)丙烯酸酯的方法

    公开(公告)号:US08664415B2

    公开(公告)日:2014-03-04

    申请号:US12952732

    申请日:2010-11-23

    IPC分类号: C09F7/00

    摘要: A process for preparing (meth)acrylates of C17-alcohol mixtures by reacting (meth)acrylic acid with a C17-alcohol mixture in the presence of at least one acidic catalyst and of at least one polymerization inhibitor and in the presence of a solvent which, with water, forms an azeotrope in which the esterification is performed in a reactor with a circulation evaporator, the azeotrope is distilled off and condensed, and the condensate splits into an aqueous phase and an organic phase, wherein the C17-alcohol mixture has a mean degree of branching (iso index) of 2.8 to 3.7.

    摘要翻译: 一种通过使(甲基)丙烯酸与C17-醇混合物在至少一种酸性催化剂和至少一种聚合抑制剂存在下和在溶剂存在下使C17-醇混合物反应制备(甲基)丙烯酸酯的方法, 与水形成共沸物,其中在具有循环蒸发器的反应器中进行酯化,将共沸物蒸馏并冷凝,并将冷凝物分成水相和有机相,其中C17-醇混合物具有 平均分枝度(iso指数)为2.8〜3.7。

    Integrated process for the preparation of fatty acid methyl ester (biodiesel)
    6.
    发明授权
    Integrated process for the preparation of fatty acid methyl ester (biodiesel) 失效
    用于制备脂肪酸甲酯(生物柴油)的综合方法

    公开(公告)号:US08481768B2

    公开(公告)日:2013-07-09

    申请号:US12058446

    申请日:2008-03-28

    IPC分类号: C11B1/00 C09F7/00

    摘要: The disclosure provides methods and systems for the production of biodiesel from biological feedstocks such as vegetable oils or animal fats. In particular, the disclosure is directed to the product of biodiesel from seeds such as non-edible oil seeds. Methods for maximizing oil recovery from the feedstocks are provided, as well as methods to convert free fatty acids in the feedstocks into glycerides amenable to transesterification. Thus the methods and systems provide for efficient biodiesel production.

    摘要翻译: 本公开提供了用于从生物原料如植物油或动物脂肪生产生物柴油的方法和系统。 特别地,本公开涉及来自种子的生物柴油的产物,例如非食用油籽。 提供了从原料中最大化油回收率的方法,以及将原料中的游离脂肪酸转化为可酯化转化的甘油酯的方法。 因此,该方法和系统提供有效的生物柴油生产。

    Weather resistant signage and a process for fabrication thereof
    9.
    发明授权
    Weather resistant signage and a process for fabrication thereof 失效
    耐候标志及其制造工艺

    公开(公告)号:US6148723A

    公开(公告)日:2000-11-21

    申请号:US157781

    申请日:1998-09-21

    摘要: A process of fabricating weather resistant signage by screen printing indicia on a UV-treated impregnated polyester protective film using a Cellosolve acetate-based ink. The resulting sign is extremely resistant to solar UV, thus preserving the indicia brightness and clarity for a very long period of time even under the most extreme conditions. The screen printing process of the preferred embodiment comprises the steps of first preparing a film image, then preparing a fabric mesh ranging from 125 to 230 mesh for black and white images and ranging from 355 to 425 mesh for halftone color images. The fabric mesh is attached to a stencil and the film image is attached to the stencil. The combination is placed into a vacuum frame for exposure to high intensity light, after which the stencil is washed with pressurized water, dried by fan, taped and touched up for pinholes or other blemishes. The ink used in the preferred embodiment comprises a clear base having Cellosolve acetate, SC-150 aromatic solvent, VITEL PE-200, VITEL PE-222 and VITEL PE-307 solvent-based coating resins, as well as thinner and resin and other ingredients. The preferred embodiment of the invention uses a unique substrate for the sign material. Generally, the substrate comprises a UV treated, impregnated polyester protective film.

    摘要翻译: 通过丝网印刷标记在使用乙酸溶纤剂的油墨的UV处理的浸渍的聚酯保护膜上制造耐候标志的方法。 所得到的标志极其耐紫外线,因此即使在最极端的条件下也能保持很长一段时间的标记亮度和清晰度。 优选实施例的丝网印刷方法包括以下步骤:首先制备胶片图像,然后为半色调彩色图像制备用于黑白图像的范围为125至230目的范围为355至425目的织物网格。 织物网连接到模板上,并且胶片图像附着在模板上。 将该组合物放置在用于暴露于高强度光的真空框架中,之后用加压水洗涤模版,通过风扇干燥,粘贴并接触针孔或其它瑕疵。 在优选实施方案中使用的油墨包括具有溶纤剂乙酸酯,SC-150芳族溶剂,VITEL PE-200,VITEL PE-222和VITEL PE-307溶剂基涂料树脂的透明碱,以及稀释剂和树脂和其它成分 。 本发明的优选实施例使用用于标志材料的唯一基底。 通常,基材包括经UV处理的浸渍聚酯保护膜。

    Process for oligomerization of polyunsaturated acids and esters,
products obtained and use thereof
    10.
    发明授权
    Process for oligomerization of polyunsaturated acids and esters, products obtained and use thereof 失效
    多不饱和酸和酯的低聚方法,获得的产品及其用途

    公开(公告)号:US5880298A

    公开(公告)日:1999-03-09

    申请号:US186483

    申请日:1994-01-14

    IPC分类号: C07C67/465 C09F7/00 C07B35/08

    CPC分类号: C07C67/465

    摘要: For the oligomerization of a fatty ester or fatty acid containing conjugated double bonds, the reaction uses a catalyst consisting of an activated earth, e.g., montmorillonite, at a temperature of from 100.degree.-180.degree. C., preferably from 130.degree.-160.degree. C. The process can be carried out continuously or in a batch process on a fixed bed and is particularly applicable to conjugated methyl esters obtained by conjugating and transesterifying sunflower seed oil. The oligomerized products obtained are particularly useful as lubricants or polycondensation reactants.

    摘要翻译: 对于含有共轭双键的脂肪酸酯或脂肪酸的低聚反应,使用由活化土如蒙脱石组成的催化剂,温度为100-180℃,优选130-160℃。 C.该方法可以在固定床上连续进行或以间歇方式进行,特别适用于通过将向日葵籽油接合和酯交换得到的共轭甲酯。 获得的低聚产物特别可用作润滑剂或缩聚反应物。