公开(公告)号：US06620551B1

公开(公告)日：2003-09-16

申请号：US09786750

申请日：2001-05-10

申请人： Masaaki Shiomi ,  Hideki Tanaka ,  Yuichi Tsuboi ,  Yuichi Okada

发明人： Masaaki Shiomi ,  Hideki Tanaka ,  Yuichi Tsuboi ,  Yuichi Okada

IPC分类号： H01M466

CPC分类号： H01M4/667 ,  H01M4/14 ,  H01M4/62 ,  H01M4/68 ,  H01M4/685 ,  H01M4/70 ,  H01M2004/028 ,  H01M2300/0011

摘要： A lead acid battery can be obtained which exhibits excellent life properties while keeping the level of self-discharging and electrolyte loss equal to that of those comprising a Pb—Ca alloy collector. In other words, the present invention lies in a positive collector for lead acid battery comprising a substrate and a surface layer made of an alloy composition different from that of the substrate formed on at least a part of the surface of the substrate, characterized in that the substrate is a Sb-free lead alloy or lead and said surface layer is a lead alloy layer comprising one or more metals selected from the group consisting of alkaline metals and alkaline earth metals.

摘要翻译： 可以获得具有优异的寿命特性的铅酸电池，同时保持自放电和电解液损失的水平与包含Pb-Ca合金集电体的那些相同。换句话说，本发明在于铅的正极集电体 酸性电池，其包含基板和由与形成在所述基板的至少一部分表面上的所述基板的合金组成不同的合金组成的表层，其特征在于，所述基板是不含Sb的铅合金或所述表面 层是包含一种或多种选自碱金属和碱土金属的金属的铅合金层。

公开(公告)号：US20080131774A1

公开(公告)日：2008-06-05

申请号：US11667015

申请日：2005-11-08

申请人： Yuichi Tsuboi

发明人： Yuichi Tsuboi

IPC分类号： H01M4/00

CPC分类号： H01M4/68 ,  H01M4/661 ,  H01M4/662 ,  H01M4/73 ,  H01M10/06 ,  Y02E60/126

摘要： A negative electrode current collector for a lead-acid battery having a grid part, upper frame part, and lug part according to the present invention, where the upper frame part and lug part have a surface layer, a surface layer is an alloy of Pb and Sn and the mass ratio of Sn accounts for 10% or more in the whole alloy, an alloy of Pb and Sb and the mass ratio of Sb accounts for 10% or more in the whole alloy, an alloy of Pb, Sn and Sb and the total mass ratio of Sn and Sb accounts for 10% or more in the whole alloy, Sn, or Sb.Further, a negative electrode current collector for a lead-acid battery having a grid part, upper frame part, and lug part according to the present invention, only upper frame part and lug part have a surface layer.

摘要翻译： 根据本发明的用于具有栅格部分，上框架部分和凸耳部分的铅酸蓄电池的负极集电体，其中上框架部分和凸耳部分具有表面层，表面层是Pb的合金 Sn和Sn的总质量比在整个合金中为10％以上，Pb和Sb的合金和Sb的质量比在整个合金中为10％以上，Pb，Sn和Sb的合金 Sn和Sb的总质量比在整个合金Sn或Sb中占10％以上。 此外，根据本发明的具有栅格部分，上框架部分和凸耳部分的铅酸蓄电池的负极集电体仅具有上框架部分和凸耳部分，具有表面层。