公开(公告)号：US20190202951A1

公开(公告)日：2019-07-04

申请号：US16325831

申请日：2017-08-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Harald Kaspar ,  Klaus Hintzer ,  Markus E. Hirschberg ,  Herbert Koenigsmann ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08F214/26 ,  C08F214/28 ,  C08L27/18 ,  C08L27/20 ,  H01B3/44

CPC classification number: C08F214/262 ,  C08F214/26 ,  C08F214/28 ,  C08L27/18 ,  C08L27/20 ,  C08L2203/16 ,  C08L2203/18 ,  H01B3/445

Abstract: A copolymer having tetrafluoroethylene units and second polymerized monomer units in a range from 0.2 to 1 percent by weight, based on the total weight of the copolymer. Rf is a linear or branched perfluoroalkyl group having from 1 to 8 carbon atoms and optionally interrupted by one or more —O— groups, n is independently from 1 to 6, and z is 0, 1, or 2. The copolymer has a melt flow index in a range from 0.02 grams per 10 minutes to 19.4 grams per 10 minutes. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed.

公开(公告)号：US09714307B2

公开(公告)日：2017-07-25

申请号：US14646451

申请日：2013-11-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Herbert Koenigsmann ,  Helmut Traunspurger ,  Tilman C. Zipplies

IPC: C08L27/18 ,  C08F214/26 ,  C08F214/18

CPC classification number: C08F214/262 ,  C08F214/184 ,  C08L27/18 ,  C08L2201/54

Abstract: A method of making a partially fluorinated polymer dispersions and resulting aqueous mixtures. The method comprising polymerizing one or more fluorinated monomers in an aqueous emulsion polymerization in the presence of a polymerizable fluorinated emulsifier to form a fluorinated polymer. The polymerizable fluorinated emulsifier has the formula X2C═CX(CF2)m(CH2)n[O—(CX2)p]q-[O—(CX2)r]s—[O—(CX2—CX2)]t—[(O)w—(CX2)u]v-[CH2]z—Y.

公开(公告)号：US20170037166A1

公开(公告)日：2017-02-09

申请号：US15331604

申请日：2016-10-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Michael Juergens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman C. Zipplies

IPC: C08F214/26 ,  C07C51/41

CPC classification number: C08F214/262 ,  B01F17/0035 ,  C07C51/41 ,  C07C59/135 ,  C08F2400/00 ,  C08F2500/24 ,  C08L71/02 ,  C09D127/12 ,  C08L2666/22

Abstract: The invention provides a method for making a fluoropolymer and a method for preparing a fluorinated surfactant.

Abstract translation: 本发明提供一种制备氟聚合物的方法和一种制备氟化表面活性剂的方法。

公开(公告)号：US09809658B2

公开(公告)日：2017-11-07

申请号：US15244148

申请日：2016-08-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Michael Juergens ,  Gunther J. Kaempf ,  Harald Kaspar ,  Kai H. Lochhaas ,  Andre Streiter ,  Oleg Shyshkov ,  Tilman C. Zipplies ,  Herbert Koenigsmann

IPC: C08F6/00 ,  C02F1/461 ,  C02F1/26 ,  C08F14/08 ,  C08F14/18

CPC classification number: C08F6/003 ,  C02F1/26 ,  C02F1/461 ,  C02F2001/46138 ,  C02F2001/46147 ,  C08F2/10 ,  C08F2/20 ,  C08F14/08 ,  C08F14/18 ,  C08F2800/10 ,  Y02P20/582 ,  C08F2/24

Abstract: Described herein is a method of purifying a product and recycling water comprising the following steps: (i) providing a crude product comprising at least one low molecular weight fluoroorganic compounds wherein the low molecular weight fluoroorganic compounds is partially fluorinated and comprises a polar group and/or a reactive group; (ii) extracting the impurity from the product using water to form an extract, (iii) contacting the extract with a radical-forming process to degrade the low molecular weight fluoroorganic compounds into carbon dioxide, water, fluorine ions, and optionally cations; and (iv) using the water from step (iii) in step (ii)

公开(公告)号：US20160122522A1

公开(公告)日：2016-05-05

申请号：US14992223

申请日：2016-01-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Herbert Koenigsmann ,  Helmut Traunspurger ,  Tilman C. Zipplies

IPC: C08L27/18

CPC classification number: C08L27/18 ,  C08F214/262

Abstract: A method of making a highly fluorinated polymers and resulting aqueous mixtures. The method comprising polymerizing one or more perfluorinated monomers in an aqueous emulsion polymerization in the presence of a polymerizable fluorinated emulsifier to form a perfluorinated polymer. The polymerizable fluorinated emulsifier has the formula X2C═CX(CF2)m(CH2)n[O—(CX2)p]q—[O—(CX2)r]s−[O—(CX2—CX2)]t—[(O)w—(CX2)u]v—[CH2]z—Y. The method also provides for isolating the highly fluorinated polymer and post-fluorinating the isolated highly fluorinated polymer.

Abstract translation: 制备高度氟化聚合物和所得含水混合物的方法。 该方法包括在可聚合的氟化乳化剂的存在下在水乳液聚合中聚合一种或多种全氟化单体以形成全氟化聚合物。 可聚合的氟化乳化剂具有式X2C≡CX（CF2）m（CH2）n [O-（CX2）p] q- [O-（CX2）r] s- [O-（CX2-CX2）] t- [ （O）w - （CX2）u] v- [CH2] z-Y。 该方法还提供了分离高度氟化的聚合物和后氟化分离的高度氟化的聚合物。

公开(公告)号：US09260553B2

公开(公告)日：2016-02-16

申请号：US14646980

申请日：2013-11-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Herbert Koenigsmann ,  Helmut Traunspurger ,  Tilman C. Zipplies

IPC: C08F214/26

CPC classification number: C08L27/18 ,  C08F214/262

Abstract: A method of making a highly fluorinated polymers and resulting aqueous mixtures. The method comprising polymerizing one or more perfluorinated monomers in an aqueous emulsion polymerization in the presence of a polymerizable fluorinated emulsifier to form a perfluorinated polymer. The polymerizable fluorinated emulsifier has the formula X2C═CX(CF2)m(CH2)n[O—(CX2)p]q—[O—(CX2)r]s—[O—(CX2—CX2)]t—[(O)w—(CX2)u]v—[CH2]z—Y. The method also provides for isolating the highly fluorinated polymer and post-fluorinating the isolated highly fluorinated polymer.

Abstract translation: 制备高度氟化聚合物和所得含水混合物的方法。 该方法包括在可聚合的氟化乳化剂的存在下在水乳液聚合中聚合一种或多种全氟化单体以形成全氟化聚合物。 可聚合的氟化乳化剂具有式X2C≡CX（CF2）m（CH2）n [O-（CX2）p] q- [O-（CX2）r] s- [O-（CX2-CX2）] t- [ （O）w - （CX2）u] v- [CH2] z-Y。 该方法还提供了分离高度氟化的聚合物和后氟化分离的高度氟化的聚合物。

公开(公告)号：US12018105B2

公开(公告)日：2024-06-25

申请号：US17053985

申请日：2019-05-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Florian D. Jochum ,  Herbert Koenigsmann ,  Jens Schrooten ,  Tilman C. Zipplies ,  Karl D. Weilandt

IPC: C08F214/26

CPC classification number: C08F214/262

Abstract: Method of reducing the amount of a fluorinated acid or its salts from a fluoropolymer, the method comprises: (i) providing a composition containing particles of the fluoropolymer, (ii) contacting the fluoropolymer particles with a treatment composition comprising at least one organic liquid; and, optionally, further comprising (iii) isolating, washing and subjecting the fluoropolymer to drying treatment, and wherein the fluoropolymer contains units derived from tetrafluoroethene (TFE) and is selected from the group of fluoroelastomers and the group of fluoropolymers having a melting point of less than 150° C. Also provided are fluoropolymer and compositions containing such polymers that are essentially free of fluorinated acids and their salts.

公开(公告)号：US20230286839A1

公开(公告)日：2023-09-14

申请号：US18007066

申请日：2021-07-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Herbert Koenigsmann ,  Stefan Huber ,  Valentina Krupp ,  Scott D. Schmick ,  Zhongxing Zhang

IPC: C02F1/54 ,  C08F6/16 ,  C02F1/26

CPC classification number: C02F1/54 ,  C08F6/16 ,  C02F1/26 ,  C02F2101/36

Abstract: The present disclosure provides a process for removing fluoroorganic acidic compounds from an emulsion of fluoroorganic polymer particles, the process comprising the following steps: (i) forming a mixture of a. an emulsion comprising fluoroorganic polymer particles, at least one fluoroorganic acidic compound and at least one protic solvent, with b. at least one alkylamine; (ii) reacting the fluoroorganic acidic compound with the alkylamine to form a hydrophobic ionic compound comprising the anion of the fluoroorganic acidic compound and the cation of the alkyl amine; (iii) separating the mixture into a first phase comprising the at least one protic solvent and no greater than 80% by weight, preferably no greater than 50% by weight of the total amount of the at least one fluoroorganic acidic compound initially present in the solution in step (i); and a second phase comprising the hydrophobic ionic compound; (iva) removing the first phase from the second phase; and then (va) removing the fluoroorganic polymer particles from the second phase and/or the first phase, or (ivb) removing the fluoroorganic polymer particles from the second phase and/or the first phase, and then (vb) removing the first phase from the second phase.

公开(公告)号：US20210230328A1

公开(公告)日：2021-07-29

申请号：US17053985

申请日：2019-05-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Florian D. Jochum ,  Herbert Koenigsmann ,  Jens Schrooten ,  Tilman C. Zipplies ,  Karl D. Weilandt

IPC: C08F214/26

Abstract: Method of reducing the amount of a fluorinated acid or its salts from a fluoropolymer, the method comprises: (i) providing a composition containing particles of the fluoropolymer, (ii) contacting the fluoropolymer particles with a treatment composition comprising at least one organic liquid; and, optionally, further comprising (iii) isolating, washing and subjecting the fluoropolymer to drying treatment, and wherein the fluoropolymer contains units derived from tetrafluoroethene (TFE) and is selected from the group of fluoroelastomers and the group of fluoropolymers having a melting point of less than 150° C. Also provided are fluoropolymer and compositions containing such polymers that are essentially free of fluorinated acids and their salts.

公开(公告)号：US11028198B2

公开(公告)日：2021-06-08

申请号：US16325831

申请日：2017-08-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Harald Kaspar ,  Klaus Hintzer ,  Markus E. Hirschberg ,  Herbert Koenigsmann ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08F214/26 ,  C08F214/28 ,  H01B3/44 ,  C08L27/18 ,  C08L27/20 ,  C08F214/18

Abstract: A copolymer having tetrafluoroethylene units and second polymerized monomer units in a range from 0.2 to 1 percent by weight, based on the total weight of the copolymer. Rf is a linear or branched perfluoroalkyl group having from 1 to 8 carbon atoms and optionally interrupted by one or more —O— groups, n is independently from 1 to 6, and z is 0, 1, or 2. The copolymer has a melt flow index in a range from 0.02 grams per 10 minutes to 19.4 grams per 10 minutes. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed.