-
公开(公告)号:US11292763B2
公开(公告)日:2022-04-05
申请号:US16613900
申请日:2018-05-17
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Klaus Hintzer , Markus E. Hirschberg , Romana Pajkert , Gerd-Volker Röschenthaler , Sergey N. Tverdomed
IPC: C07C303/26 , C07C41/14 , C07C309/06 , C07C303/24 , C07C305/26
Abstract: A method includes combining first components including at least one of CF2═CF—CF2—OSO2Cl or CF2═CF—CF2—OSO2CF3, a polyfluorinated compound having at least one ketone or carboxylic acid halide, and fluoride ion to provide a compound comprising at least one perfluorinated allyl ether group. A method includes combining second components including B(OSO2Cl)3 and hexafluoropropylene to provide CF2═CF—CF2—OSO2Cl. Another method includes combining second components including M(OSO2CF3)3 and hexafluoropropylene at a temperature above 0° C. to provide CF2═CF—CF2—OSO2CF3, wherein M is Al or B. The compound CF2═CF—CF2—OSO2Cl is also provided.
-
公开(公告)号:US20190144370A1
公开(公告)日:2019-05-16
申请号:US16065454
申请日:2016-12-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Markus E. Hirschberg , Klaus Hintzer , Zai-Ming Qiu , Gerd-Volker Röschenthaler , Romana Pajkert , Sergey Tverdomed
IPC: C07C51/58 , C07C59/135 , C07C69/96 , B01J23/28
CPC classification number: C07C51/58 , B01J23/28 , B01J2523/55 , B01J2523/68 , C07C45/42 , C07C51/00 , C07C51/04 , C07C59/135 , C07C67/00 , C07C67/14 , C07C68/00 , C07C69/96 , C07C49/175 , C07C69/708
Abstract: Methods of converting a fluorinated compound into a fluorinated acyl fluoride or derivative thereof, the method including reacting the fluorinated compound with a catalytic amount of at least one transition metal compound and an oxygen-containing compound to form the fluorinated acyl fluoride or derivative thereof. Compounds formed using such methods are also included, including for example and derivatives thereof, or combinations thereof.
-
公开(公告)号:US20220227696A1
公开(公告)日:2022-07-21
申请号:US17614608
申请日:2020-06-02
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Markus E. Hirschberg , Klaus Hintzer , Gerd-Volker Röschenthaler , Sergey N. Tverdomed , Romana Pajkert
IPC: C07C69/65 , C08F214/18 , C07C67/347 , C07C57/52 , C07C51/09 , C07F7/18 , C07C57/76 , C07C51/60
Abstract: The multifunctional compound is represented by formula X—C(R)RF—Y, in which X and Y are each independently —C(O)—O-M, —C(O)-HAL, —C(O)—NR12, —C≡N, —C(O)NR1—SO2—Rf1-W, or a fluorinated alkenyl group that is optionally interrupted by one or more —O— groups. HAL is —F, —Cl, or —Br. Rf1 is a fluorinated alkylene group that is optionally interrupted by one or more —O— groups. W is —F, —SO2Z, —CF═CF2, —O—CF═CF2, or —O—CF2—CF═CF2. Z is —F, —Cl, —NR12, or —OM. Each R1 is a hydrogen atom or alkyl having up to four carbon atoms. M is an alkyl group, a trimethylsilyl group, a hydrogen atom, a metallic cation, or a quaternary ammonium cation. R is a bromine, chloride, fluorine or hydrogen atom; and RF is a fluorinated alkenyl group that is unsubstituted or substituted by at least one chlorine atom, aryl group, or a combination thereof or RF is a fluorinated alkyl group or arylalkylenyl group that is substituted by bromine or iodine and uninterrupted or interrupted by at least one —O— group. A process for making the compound is also disclosed. A fluoropolymer made from the compound and a method of making the fluoropolymer are also disclosed.
-
公开(公告)号:US10737998B2
公开(公告)日:2020-08-11
申请号:US16065454
申请日:2016-12-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Markus E. Hirschberg , Klaus Hintzer , Zai-Ming Qiu , Gerd-Volker Röschenthaler , Romana Pajkert , Sergey Tverdomed
IPC: C07C51/58 , C07C69/96 , C07C59/135 , C07C68/00 , C07C45/42 , C07C67/14 , C07C51/04 , C07C51/00 , C07C67/00 , B01J23/28
Abstract: Methods of converting a fluorinated compound into a fluorinated acyl fluoride or derivative thereof, the method including reacting the fluorinated compound with a catalytic amount of at least one transition metal compound and an oxygen-containing compound to form the fluorinated acyl fluoride or derivative thereof. Compounds formed using such methods are also included, including for example and derivatives thereof, or combinations thereof.
-
5.
公开(公告)号:US20180370888A1
公开(公告)日:2018-12-27
申请号:US16065502
申请日:2016-12-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Markus E. Hirschberg , Klaus Hintzer , Zai-Ming Qiu , Gerd-Volker Röschenthaler , Romana Pajkert , Sergey N. Tverdomed
IPC: C07C41/30 , C07C43/12 , C07C249/02 , C07C251/08 , C07C253/18 , C07C255/03
Abstract: Methods of converting a fluorinated vinyl ether to a saturated partially fluorinated ether, the method comprising: reacting the fluorinated vinyl ether with an amine, ammonia, or combination thereof to form the saturated partially fluorinated ether.
-
公开(公告)号:US20210276946A1
公开(公告)日:2021-09-09
申请号:US16613900
申请日:2018-05-17
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Klaus Hintzer , Markus E. Hirschberg , Romana Pajkert , Gerd-Volker Röschenthaler , Sergey N. Tverdomed
IPC: C07C303/26 , C07C309/06 , C07C41/14 , C07C43/12
Abstract: A method includes combining first components including at least one of CF2═CF—CF2—OSO2Cl or CF2═CF—CF2—OSO2CF3, a polyfluorinated compound having at least one ketone or carboxylic acid halide, and fluoride ion to provide a compound comprising at least one perfluorinated allyl ether group. A method includes combining second components including B(OSO2Cl)3 and hexafluoropropylene to provide CF2═CF—CF2—OSO2Cl. Another method includes combining second components including M(OSO2CF3)3 and hexafluoropropylene at a temperature above 0° C. to provide CF2═CF—CF2—OSO2CF3, wherein M is Al or B. The compound CF2═CF—CF2—OSO2Cl is also provided.
-
公开(公告)号:US20210070686A1
公开(公告)日:2021-03-11
申请号:US16955618
申请日:2018-12-19
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Markus E. Hirschberg , Klaus Hintzer , William M. Lamanna , Sean M. Smith , Gerd-Volker Röschenthaler , Romana Pajkert , Sergey N. Tverdomed
Abstract: A method of making a polyfunctional polyfluorinated compound includes combining first components that include a polyfluorinated cyclic compound having 4 to 7 ring carbon atoms and at least one of osmium tetroxide, ruthenium tetroxide or a precursor thereof and forming a polyfluorinated dicarboxylic acid. Two of the ring carbon atoms of the polyfluorinated cyclic compound form a double bond or an epoxide. The precursor reacts with an oxidant to form ruthenium tetroxide. Methods also include converting the polyfluorinated dicarboxylic acid to a polyfluorinated dicarboxylic acid halide and converting the polyfluorinated dicarboxylic acid halide to other polyfunctional polyfluorinated compounds.
-
8.
公开(公告)号:US10723683B2
公开(公告)日:2020-07-28
申请号:US16065502
申请日:2016-12-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Markus E. Hirschberg , Klaus Hintzer , Zai-Ming Qiu , Gerd-Volker Röschenthaler , Romana Pajkert , Sergey N. Tverdomed
IPC: C07C41/30 , C07C249/02 , C07C253/18 , C07C41/18 , C07C43/12 , C07C251/08 , C07C255/13
Abstract: Methods of converting a fluorinated vinyl ether to a saturated partially fluorinated ether, the method comprising: reacting the fluorinated vinyl ether with an amine, ammonia, or combination thereof to form the saturated partially fluorinated ether.
-
-
-
-
-
-
-