公开(公告)号：US20040181104A1

公开(公告)日：2004-09-16

申请号：US10791565

申请日：2004-03-02

Applicant: ABB Lummus Global Inc.

Inventor： Chuen Y. Yeh ,  Zhiping Shan ,  Philip J. Angevine ,  Dinesh Gandhi

IPC: C07C004/02 ,  B01J031/00

CPC classification number: B01J29/0308 ,  B01J31/1633 ,  B01J31/18 ,  B01J2531/0244 ,  B01J2531/10 ,  B01J2531/80 ,  C07C5/3332 ,  C07C5/367 ,  C07C2521/08 ,  Y02P20/127 ,  Y02P20/52 ,  Y02P20/588 ,  C07C15/46 ,  C07C15/06

Abstract: A dehydrogenation catalyst includes an organometallic pincer complex bonded to a mesoporous inorganic oxide support, the organometallic pincer complex possessing catalytic activity for alkyl group dehydrogenation. The pincer complex includes at least one element selected from Group VIII or Group IB of the Periodic Table of the elements, and at least one element selected from Group VA of the Periodic Table of the elements in each of two molecular arms, the Group VIII or Group IB element being bonded to each of the Group VA elements. The catalyst is advantageously employed in conjunction with catalytic distillation to permit the dehydrogenation of organic compounds at lower temperatures and at lower cost than conventional methods.

Abstract translation: 脱氢催化剂包括与介孔无机氧化物载体结合的有机金属夹子络合物，具有烷基脱氢催化活性的有机金属螯合物。 钳形复合物包括选自元素周期表第VIII族或第IB族中的至少一种元素，以及选自两种分子臂中的每一种元素的元素周期表第VA族中的至少一种元素，第VIII族或 IB族元素键合到每个VA族元素上。 催化剂有利地与催化蒸馏结合使用以允许有机化合物在较低温度下以比常规方法更低的成本脱氢。

公开(公告)号：US20040162454A1

公开(公告)日：2004-08-19

申请号：US10774774

申请日：2004-02-09

Applicant: ABB Lummus Global Inc.

Inventor： Xiangtao Gao ,  Johannes Hendrik Koegler ,  Lawrence L. Murrell ,  Philip J. Angevine

IPC: C07C002/68 ,  C07C002/58

CPC classification number: B01J29/088 ,  B01J29/084 ,  B01J35/023 ,  B01J37/08 ,  B01J2229/40 ,  B01J2229/42 ,  B01J2229/64 ,  C01B39/04 ,  C01B39/24 ,  C07C2/58 ,  C07C2/66 ,  C07C6/126 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/08 ,  C07C2529/12 ,  C07C2529/14 ,  C07C2529/16 ,  C10G29/205 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/1096 ,  C10G2300/305 ,  C10G2300/4018 ,  C10G2400/02 ,  C10G2400/30 ,  Y02P20/52 ,  C07C9/14 ,  C07C15/073 ,  C07C15/085

Abstract: A process for alkylation of a hydrocarbon compound includes providing a catalyst including a zeolite Y having a crystal size of no more than 100 nm, and reacting an alkylatable hydrocarbon with an alkylating agent in the presence of the catalyst under alkylation reaction conditions to provide a gasoline product having a Research Octane Number of over 99.5.

Abstract translation: 烃化合物的烷基化方法包括提供包含结晶尺寸不超过100nm的沸石Y的催化剂，并且在烷基化反应条件下在催化剂存在下使烷基化烃与烷基化剂反应以提供汽油 研究辛烷值超过99.5的产品。

公开(公告)号：US20040179996A1

公开(公告)日：2004-09-16

申请号：US10795771

申请日：2004-03-08

Applicant: ABB Lummus Global Inc.

Inventor： Zhiping Shan ,  Jacobus Cornelius Jansen ,  Chuen Y. Yeh ,  Philip J. Angevine ,  Thomas Maschmeyer

IPC: C01F007/36

CPC classification number: C01B37/00 ,  B01J21/04 ,  B01J35/10 ,  B01J35/1061 ,  B01J37/0018 ,  C01F7/36 ,  C01F7/448 ,  C01P2002/01 ,  C01P2002/72 ,  C01P2002/86 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17

Abstract: Mesoporous aluminum oxides with high surface areas have been synthesized using inexpensive, small organic templating agents instead of surfactants. Optionally, some of the aluminum can be framework-substituted by one or more other elements. The material has high thermal stability and possesses a three-dimensionally randomly connected mesopore network with continuously tunable pore sizes. This material can be used as catalysts for dehydration, hydrotreating, hydrogenation, catalytic reforming, steam reforming, amination, Fischer-Tropsch synthesis and Diels-Alder synthesis, etc.

Abstract translation: 使用廉价的小型有机模板剂代替表面活性剂，已经合成了具有高表面积的介孔氧化铝。 可选地，一些铝可以被一个或多个其它元素框架取代。 该材料具有高热稳定性，并具有连续可调孔径的三维随机连接的中孔网络。 该材料可用作脱水，加氢处理，氢化，催化重整，蒸汽重整，胺化，费 - 托合成和狄尔斯 - 阿尔德合成等催化剂。