公开(公告)号：US20240253998A1

公开(公告)日：2024-08-01

申请号：US18418344

申请日：2024-01-22

Applicant: NANJING TECH UNIVERSITY

Inventor： Xuerui WANG ,  Xingyu PENG ,  Lekai YOU ,  Shengyuan REN ,  Wen BO ,  Xuehong GU

IPC: C01B39/04

CPC classification number: C01B39/04

Abstract: The present disclosure relates to a preparation method of an SSZ-13 zeolite membrane, and belongs to the technical field of zeolite membranes. The present disclosure solves the problem that the SSZ-13 zeolite membranes synthesized in the art have a poor quality and a large thickness. In the present disclosure, a FAU-type zeolite is used as a raw material, and transformed into an SSZ-13 zeolite with a particle size of 210 nm through intergranular transformation, with a mass yield of 91.2%. A crystal seed prepared by the preparation method of the present disclosure has a small particle size and a small thickness.

公开(公告)号：US20230331563A1

公开(公告)日：2023-10-19

申请号：US17719848

申请日：2022-04-13

Applicant: Saudi Arabian Oil Company

Inventor： Robert P. HODGKINS ,  Omer Refa KOSEOGLU

IPC: C01B39/02 ,  C01B39/04

CPC classification number: C01B39/023 ,  C01B39/04

Abstract: The present disclosure is directed to a method of manufacture of co-crystallized *BEA/MOR zeolites. This is accomplished by using an improved sol-gel formulation including a water-soluble fraction of ODSO as an additional component. The resulting products are, or contain, co-crystallized *BEA/MOR zeolites, whereas in the absence of the ODSO, the resulting products are zeolite beta.

公开(公告)号：US11766667B2

公开(公告)日：2023-09-26

申请号：US17195087

申请日：2021-03-08

Applicant: Mitsubishi Chemical Corporation ,  JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS

Inventor： Hiroaki Onozuka ,  Masahiro Hara ,  Masato Yoshioka ,  Toshiyuki Yokoi

IPC: B01J29/70 ,  B01D53/00 ,  C07C11/06 ,  C07C11/04 ,  C07C11/08 ,  C07C1/20 ,  B01J35/00 ,  B01J29/76 ,  B01J29/72 ,  B01D53/94 ,  B01J29/48 ,  B01J37/04 ,  B01J20/18 ,  B01J20/28 ,  C01B39/48 ,  B01J35/02 ,  C01B39/04

CPC classification number: B01J29/70 ,  B01D53/00 ,  B01D53/9418 ,  B01J20/18 ,  B01J20/28002 ,  B01J20/28004 ,  B01J20/28011 ,  B01J29/48 ,  B01J29/72 ,  B01J29/76 ,  B01J35/002 ,  B01J35/023 ,  B01J37/04 ,  C01B39/48 ,  C07C1/20 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  B01D2255/104 ,  B01D2255/106 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1028 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9202 ,  B01D2255/9205 ,  B01D2255/9207 ,  C01B39/04 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P30/20 ,  Y02P30/40 ,  C07C1/20 ,  C07C11/06 ,  C07C1/20 ,  C07C11/08

Abstract: A CON zeolite satisfying the following (1) to (2): (1) The framework is CON as per the code specified by the International Zeolite Association (IZA); and (2) It contains silicon and aluminum, and the molar ratio of aluminum to silicon is 0.04 or more.

公开(公告)号：US20230150827A1

公开(公告)日：2023-05-18

申请号：US17917331

申请日：2021-03-23

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Tress Maria De Baerdemaeker ,  Ute Kolb ,  Bernd Marler ,  Feng-Shou Xiao ,  Toshiyuki Yokoi ,  Weiping Zhang ,  Dirk De Vos ,  Xiangju Meng

IPC: C01B39/12 ,  C01B39/04

CPC classification number: C01B39/12 ,  C01B39/04 ,  C01P2002/77 ,  C01P2002/76 ,  C01P2002/72

Abstract: The present invention relates to a crystalline material having a framework structure comprising O and one or more tetravalent elements Y, and optionally comprising one or more trivalent elements X, wherein the crystalline material displays a crystallographic unit cell of the monoclinic space group C2, wherein the unit cell parameter a is in the range of from 14.5 to 20.5 Å, the M unit cell parameter b is in the range of from 14.5 to 20.5 Å, the unit cell parameter c in the range of from 11.5 to 17.5 Å and the unit cell parameter β is in the range of from 109 to 118°, wherein the framework density is in the range of from 11 to 23 T-atoms/1000 Å3 wherein the framework structure comprises 12 membered rings, and wherein the framework structure displays a 2-dimensional channel e dimensionality of 12 membered ring channels. The present invention further relates to a process for the production of said material, as N well as to its use, in particular as a catalyst or catalyst component.

公开(公告)号：US20180327523A1

公开(公告)日：2018-11-15

申请号：US16043791

申请日：2018-07-24

Applicant: Saudi Arabian Oil Company ,  King Abdullah University of Science and Technology

Inventor： Yu Han ,  Qiwei Tian ,  Xinglong Dong ,  Zhaohui Liu ,  Jean-Marie Basset ,  Youssef Saih ,  Miao Sun ,  Wei Xu ,  Sohel Shaikh

IPC: C08F8/30 ,  C01B39/04 ,  B01J29/00 ,  B01J37/02 ,  B01J37/06 ,  B01J37/10 ,  B01J37/04 ,  B01J37/00 ,  B01J35/02 ,  B01J29/80 ,  B01J29/70 ,  B01J29/08 ,  B01J29/89 ,  B01J29/40 ,  C08F8/40 ,  C08F8/32 ,  C08F230/02 ,  C08F226/04

CPC classification number: C08F8/30 ,  B01J29/00 ,  B01J29/084 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/89 ,  B01J35/026 ,  B01J37/0018 ,  B01J37/0221 ,  B01J37/04 ,  B01J37/06 ,  B01J37/10 ,  B01J2029/062 ,  C01B39/04 ,  C08F8/32 ,  C08F8/40 ,  C08F226/04 ,  C08F230/02

Abstract: According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to form mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m2/g and a pore volume of greater than 0.3 cm3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.

公开(公告)号：US09895684B2

公开(公告)日：2018-02-20

申请号：US14534642

申请日：2014-11-06

Applicant: BASF SE

Inventor： Ivor Bull ,  Ulrich Müller

IPC: C01B39/48 ,  B01J29/70 ,  B01J29/76 ,  B01D53/94 ,  B01J37/02 ,  C01B39/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/46 ,  B01J35/04

CPC classification number: B01J29/763 ,  B01D53/9418 ,  B01D2251/2067 ,  B01D2253/108 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2258/012 ,  B01J29/7015 ,  B01J35/04 ,  B01J37/0246 ,  C01B39/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/46 ,  C01B39/48 ,  Y02C20/10 ,  Y02P20/153

Abstract: Zeolites having CHA framework structure and a composition comprising the molar ratio (n SiO2): X203, wherein X is a trivalent element, and wherein n is at least 10, wherein the crystal size, as determined from Scanning Electron Microscopy, is greater than 1 micrometer and wherein the chabazite framework is phase-pure having an impurity of other zeolitic frameworks, such as RUT 25 as determined by X-ray Diffraction, of less than 5%. The process for the preparation comprises:(i) preparation of an aqueous solution containing at least one source for X203 , wherein X is selected from Al, B, Ga, and a mixture of two or more, and at least one source for SiO2, at least one organic structure directing agent (SDA) other than Tetramethylammonium hydroxide (TMAOH), acting as a template for the CHA structure, and Tetramethylammonium hydroxide (TMAOH), wherein the SDA or mixtures thereof are employed in such amounts that the aqueous solution in (i) exhibits a molar ratio of SDA : TMAOH of 0.01 to 5;(ii) hydrothermal crystallization of the aqueous solution according to (i); wherein the aqueous solution of (i) contains copper in an amount less than 0.005 Cu:((n YO2)+X203) where n is in the range of 10 to 50.

公开(公告)号：US09738537B2

公开(公告)日：2017-08-22

申请号：US15215657

申请日：2016-07-21

Applicant: Chevron U.S.A. Inc.

Inventor： Stacey Ian Zones

IPC: C01B39/48 ,  B01D53/02 ,  B01J29/70 ,  C01B39/04 ,  B01J20/18 ,  B01J20/30 ,  B01J29/04 ,  B01J29/18 ,  B01J29/86 ,  B01J39/14 ,  C01B39/00 ,  C01B39/26 ,  C01B37/02 ,  C01B39/12

CPC classification number: C01B39/04 ,  B01J20/18 ,  B01J20/3057 ,  B01J29/041 ,  B01J29/047 ,  B01J29/18 ,  B01J29/70 ,  B01J29/86 ,  B01J39/14 ,  C01B37/02 ,  C01B39/00 ,  C01B39/12 ,  C01B39/265 ,  C01B39/48

Abstract: Crystalline molecular sieves and their synthesis using quaternary N-methyl-diisoalkylammonium cations as organic structure directing agents are disclosed. The structure directing agent has the following structure (1): in which R1 is selected from hydrogen, a methyl group, an ethyl group, a propyl group, and a hydroxymethyl group; and R2, R3, R4 and R5 are independently selected from a methyl group, an ethyl group, and a propyl group.

公开(公告)号：US09656251B2

公开(公告)日：2017-05-23

申请号：US14527631

申请日：2014-10-29

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC

Inventor： Xingtian Shu ,  Changjiu Xia ,  Min Lin ,  Bin Zhu ,  Xinxin Peng ,  Aiguo Zheng ,  Mudi Xin ,  Yanjuan Xiang ,  Chunfeng Shi

IPC: B01J29/40 ,  C01B39/04 ,  B01J29/70 ,  B01J29/03 ,  C01B39/36 ,  C01B39/40 ,  C01B37/02

CPC classification number: B01J29/0308 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  C01B37/02 ,  C01B39/04 ,  C01B39/365 ,  C01B39/40

Abstract: The present invention relates to a full-Si molecular sieve, wherein the full-Si molecular sieve has a Q4/Q3 of (10-90):1 wherein Q4 is the peak strength at the chemical shift of −112±2 ppm in the 29Si NMR spectrum of the full-Si molecular sieve, expressed as the peak height relative to the base line; and Q3 is the peak strength at the chemical shift of −103±2 ppm in the 29Si NMR spectrum of the full-Si molecular sieve, expressed as the peak height relative to the base line.

公开(公告)号：US20170114157A1

公开(公告)日：2017-04-27

申请号：US15298647

申请日：2016-10-20

Applicant: Saudi Arabian Oil Company ,  King Abdullah University of Science and Technology

Inventor： Yu Han ,  Qiwei Tian ,  Xinglong Dong ,  Zhaohui Liu ,  Jean-Marie Basset ,  Youssef Saih ,  Miao Sun ,  Wei Xu ,  Sohel Shaikh

IPC: C08F8/30 ,  B01J29/40 ,  B01J29/89 ,  B01J29/08 ,  B01J29/70 ,  B01J37/02 ,  B01J35/02 ,  B01J37/00 ,  B01J37/04 ,  B01J37/10 ,  B01J37/06 ,  C01B39/04 ,  B01J29/80

CPC classification number: C08F8/30 ,  B01J29/00 ,  B01J29/0308 ,  B01J29/084 ,  B01J29/40 ,  B01J29/44 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/89 ,  B01J35/002 ,  B01J35/008 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0221 ,  B01J2029/062 ,  B01J2229/186 ,  C01B39/04 ,  C08F8/32 ,  C08F8/40 ,  C08F8/44 ,  C08F226/04 ,  C08F230/02 ,  C10G3/44 ,  C10G3/49 ,  C10G2400/30

Abstract: According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to form mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m2/g and a pore volume of greater than 0.3 cm3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.

公开(公告)号：US09550684B2

公开(公告)日：2017-01-24

申请号：US14891537

申请日：2014-05-05

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Simon C. Weston ,  Hilda B. Vroman ,  Karl G. Strohmaier

IPC: C07C2/02 ,  C01B33/36 ,  C01B39/00 ,  C08F210/00 ,  C01B39/04 ,  C01B39/48 ,  C10G50/00 ,  B01J29/70 ,  B01J35/00

CPC classification number: C01B39/04 ,  B01J29/7026 ,  B01J35/002 ,  C01B39/48 ,  C07C2/02 ,  C07C2529/70 ,  C10G50/00

Abstract: The invention relates to a process for preparing molecular sieves, such as ZSM-57, using one or more structure directing agents selected from the group consisting of N1,N1,N5,N5-tetraethyl-N1,N5-dimethylpentane-1,5-diaminium, 1-ethyl-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)piperidin-1-ium, 1,1′-(hexane-1,6-diyl)bis(1-ethylpiperidin-1-ium), and 1,1-diethylpyrrolidin-1-ium.

Abstract translation: 本发明涉及一种使用一种或多种选自N1，N1，N5，N5-四乙基-N1，N5-二甲基戊烷-1,5-二醇的结构定向剂制备分子筛的方法，例如ZSM-57， 二（1-（1-甲基哌啶-1-基）戊基）哌啶-1-基，1,1' - （己烷-1,6-二基）双（1- 乙基哌啶-1-基）和1,1-二乙基吡咯烷-1-酮。