公开(公告)号：US11958046B1

公开(公告)日：2024-04-16

申请号：US18336936

申请日：2023-06-16

申请人： KELLOGG BROWN & ROOT LLC

发明人： Rajeev Ranjan ,  Anubhav Kapil

IPC分类号： B01J8/04 ,  C07C2/54 ,  C07C2/56 ,  C07C2/58 ,  C07C2/76

CPC分类号： B01J8/0492 ,  B01J8/0446 ,  C07C2/76 ,  B01J2208/00752 ,  B01J2208/00761 ,  C07C2/54 ,  C07C2/56 ,  C07C2/58

摘要： Methods and systems for alkylate production involving a multi-zone alkylation reactor. The multi-zone alkylation reactor includes a plurality of alkylation zones spaced vertically in a series configuration and a partition splitting the plurality of alkylation zones into at least two mechanically separated catalytic volumes.

公开(公告)号：US11724972B2

公开(公告)日：2023-08-15

申请号：US17935962

申请日：2022-09-28

申请人： UOP LLC

发明人： Matthew C. Cole ,  Dominic P. Weber ,  Rajeswar R. Gattupalli ,  Hye Kyung Timken ,  Huping Luo ,  Bong Kyu Chang ,  Rebecca Mudrock

IPC分类号： C07C2/60 ,  B01J31/02 ,  C07C2/58 ,  C07C2/62

CPC分类号： C07C2/60 ,  B01J31/0284 ,  C07C2/58 ,  C07C2/62 ,  B01J2231/30 ,  C07C2531/02

摘要： Processes for the direct alkylation of ethylene with isobutane or isopentane using a highly active ionic liquid alkylation catalyst are described. Ethylene is sent to a high-temperature alkylation reactor loop, and C3, C4, and C5 olefins are routed to a low temperature alkylation reactor loop. In each reactor, the olefins are contacted with an excess of isobutane or isopentane in the presence of a highly active ionic liquid catalyst. Portions of the reactor effluent streams are fed to a common downstream catalyst separation and product fractionation sections. The remainder of the reactor effluent is recycled back to the respective alkylation reactor.

公开(公告)号：US10077219B2

公开(公告)日：2018-09-18

申请号：US15402304

申请日：2017-01-10

申请人： E I DU PONT DE NEMOURS AND COMPANY

发明人： Mark Coleman Puett ,  Minye Liu

IPC分类号： B01J19/00 ,  B01J19/18 ,  C07C2/62

CPC分类号： C07C2/62 ,  B01F5/108 ,  B01J19/006 ,  B01J19/18 ,  B01J2219/00081 ,  B01J2219/00768 ,  B01J2219/00777 ,  B01J2219/182 ,  C07C2/58 ,  C07C2/60 ,  C07C2527/054 ,  C07C2527/12 ,  C07C2527/1206 ,  C07C2527/1213 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2527/173 ,  C07C2529/04 ,  C07C2531/025 ,  C07C2531/08 ,  C07C9/16

摘要： A continuous mixing reactor has an outer shell having a cylindrical portion with a central section and two opposite conical end sections; a circulation tube within the shell so that an annular passage forms between the shell and the circulation tube; an impeller within and positioned adjacent to one end of the circulation tube; and heat exchange means penetrating the outer shell and extending into the end of the circulation tube opposite the impeller. The outer shell has a hydraulic head forming one end of the shell, a heat exchange medium header at the opposite end of the shell. The circulation tube nearer the heat exchange medium header terminates at or downstream from a tangential plane extending through the shell at the intersection of the central section and the conical end section of the cylindrical portion of shell. The reactor is useful in an alkylation process.

公开(公告)号：US20180127352A1

公开(公告)日：2018-05-10

申请号：US15866393

申请日：2018-01-09

申请人： UOP LLC

发明人： Erin M. Broderick ,  Avram M. Buchbinder ,  Alakananda Bhattacharyya

IPC分类号： C07C233/89 ,  C07C231/12

CPC分类号： C07C233/89 ,  C07C2/58 ,  C07C231/12 ,  C07C2527/125 ,  C07C9/16

摘要： Non-cyclic amide or thioamide based ionic liquids and methods of making them are disclosed. The non-cyclic amide or thioamide based ionic liquid comprises a cation and an anion and has the formula:

公开(公告)号：US20160263547A1

公开(公告)日：2016-09-15

申请号：US14656950

申请日：2015-03-13

申请人： Chevron U.S.A. Inc.

发明人： Donald Henry Mohr ,  Huping Luo ,  Clifford Michael Lowe ,  Hye Kyung Cho Timken ,  Krishniah Parimi ,  Michael John Girgis ,  Bong-Kyu Chang

IPC分类号： B01J19/26 ,  B01J19/00

CPC分类号： B01J19/246 ,  B01J4/002 ,  B01J4/004 ,  B01J19/0013 ,  B01J19/2405 ,  B01J19/2465 ,  B01J19/26 ,  B01J2219/00047 ,  B01J2219/00103 ,  B01J2219/00108 ,  B01J2219/0011 ,  B01J2219/182 ,  B01J2219/185 ,  B01J2219/1943 ,  B01J2219/24 ,  C07C2/58 ,  C07C2527/125 ,  C07C9/16

摘要： Systems and apparatus for ionic liquid catalyzed hydrocarbon conversion, such as alkylation, using vaporization to remove reaction heat from an ionic liquid reactor and to provide mixing therein, wherein hydrocarbon vapors are withdrawn from the ionic liquid reactor and the withdrawn hydrocarbon vapor is recovered by a hydrocarbon vapor recovery unit in fluid communication with the ionic liquid reactor for recycling condensed hydrocarbons to the ionic liquid reactor. Processes for ionic liquid catalyzed alkylation are also disclosed.

摘要翻译： 用于离子液体催化的烃转化的系统和装置，例如烷基化，使用蒸发来除去离子液体反应器的反应热并提供其中的混合，其中烃蒸气从离子液体反应器中取出并且取出的烃蒸气通过 烃蒸气回收单元与离子液体反应器流体连通，用于将冷凝的烃再循环到离子液体反应器。 还公开了用于离子液体催化烷基化的方法。

公开(公告)号：US20160237004A1

公开(公告)日：2016-08-18

申请号：US15014300

申请日：2016-02-03

申请人： Kun WANG ,  Robert T. CARR ,  Elise MARUCCHI-SOOS

发明人： Kun WANG ,  Robert T. CARR ,  Elise MARUCCHI-SOOS

IPC分类号： C07C5/333 ,  C07C2/58 ,  C07C5/03

CPC分类号： C07C5/3337 ,  B01J29/12 ,  B01J29/22 ,  B01J29/44 ,  B01J29/7415 ,  B01J29/7461 ,  B01J29/7492 ,  B01J2229/186 ,  C07C2/12 ,  C07C2/58 ,  C07C2529/74 ,  C10G50/00 ,  C10G2300/1081 ,  C07C9/16 ,  C07C9/14

摘要： A process for converting paraffins, especially light paraffins, e.g. C3-C8 paraffins, to higher boiling range paraffinic liquid hydrocarbons comprises endothermically dehydrogenating the light paraffin combined with a thermally coupled, exothermic reaction such as olefin oligomerization to supply heat for the endothermic conversion.

摘要翻译： 链烷烃，特别是轻链烷烃的转化方法。 C3-C8链烷烃与较高沸点的链烷烃液体烃包括将光链烷烃与热偶合的放热反应（例如烯烃低聚）组合进行吸热脱氢，以提供热量进行吸热转化。

公开(公告)号：US09302200B2

公开(公告)日：2016-04-05

申请号：US13901935

申请日：2013-05-24

申请人： Hye Kyung Cho Timken ,  Bong-Kyu Chang

发明人： Hye Kyung Cho Timken ,  Bong-Kyu Chang

IPC分类号： B01J8/00 ,  C07C2/54 ,  B01J38/10 ,  B01D3/00 ,  C07C2/58

CPC分类号： B01D3/009 ,  B01J38/10 ,  C07C2/54 ,  C07C2/58 ,  C07C2527/125 ,  Y02P20/582 ,  Y02P20/584 ,  C07C9/16

摘要： We provide alkylation process units, one comprising: a) a hydrogenation reactor that produces a regenerated catalyst effluent; b) a fractionation unit that separates the effluent into gas and light hydrocarbon; c) a connection between the fractionation unit for transmitting the gas to the hydrogenation reactor; and d) a connection between the fractionation unit and an alkylation reactor to transmit the light hydrocarbon to the alkylation reactor. The other comprising: a) a separator, connected between the hydrogenation reactor and a fractionation unit; that separates the effluent into gas and liquid; and wherein the fractionation unit separates a hydrocarbon stream from the liquid into a light hydrocarbon comprising a hydrogen chloride and an extracted conjunct polymer naphtha; b) a connection between the separator and the hydrogenation reactor for transmitting the gas to the hydrogenation reactor; and c) a connection between the fractionation unit and an alkylation reactor to transmit the light hydrocarbon.

摘要翻译： 我们提供烷基化处理单元，一个包括：a）产生再生催化剂流出物的氢化反应器; b）将流出物分离成气体和轻烃的分馏单元; c）用于将气体传送到氢化反应器的分馏单元之间的连接; 和d）分馏单元和烷基化反应器之间的连接，以将轻烃传输到烷基化反应器。 另一个包括：a）连接在氢化反应器和分馏单元之间的分离器; 将流出物分离成气体和液体; 并且其中所述分馏单元将烃流从液体分离成包含氯化氢和提取的结合聚合物石脑油的轻质烃; b）分离器和氢化反应器之间的连接，用于将气体传送到氢化反应器; 和c）分馏单元和烷基化反应器之间的连接以透过轻质烃。

公开(公告)号：US09302199B2

公开(公告)日：2016-04-05

申请号：US13563355

申请日：2012-07-31

申请人： Hye Kyung Cho Timken ,  Bong-Kyu Chang

发明人： Hye Kyung Cho Timken ,  Bong-Kyu Chang

IPC分类号： C07C2/58 ,  C07C5/02 ,  C07C2/60 ,  B01D3/00

CPC分类号： B01D3/009 ,  B01J38/10 ,  C07C2/54 ,  C07C2/58 ,  C07C2527/125 ,  Y02P20/582 ,  Y02P20/584 ,  C07C9/16

摘要： We provide processes, and process units for practicing the processes, comprising a. regenerating a used catalyst comprising an ionic liquid catalyst and a chloride, from an alkylation reactor, in a hydrogenation reactor to produce a regenerated catalyst effluent; b. separating at least a portion of the regenerated catalyst effluent into a gas fraction comprising a hydrogen gas and into a light hydrocarbon fraction comprising a hydrogen chloride; c. recycling at least a part of the gas fraction comprising the hydrogen gas to the hydrogenation reactor; and d. recovering at least an amount of the light hydrocarbon fraction comprising the hydrogen chloride and recycling the at least the amount of the light hydrocarbon fraction to the alkylation reactor. The alkylation process units comprise a hydrogenation reactor, a fractionation unit, and connections for transmitting the gas fraction to the hydrogenation reactor and for transmitting the light hydrocarbon fraction to the alkylation reactor.

摘要翻译： 我们为实施流程提供流程和流程单元，包括a。 在氢化反应器中将来自烷基化反应器的包含离子液体催化剂和氯化物的二氧化碳再生，生成再生催化剂流出物; b。 将至少一部分再生的催化剂流出物分离成包含氢气的气体馏分并进入包含氯​​化氢的轻质烃馏分中; C。 将至少一部分包含氢气的气体馏分再循环到氢化反应器中; 和d。 回收至少一定量的包含氯化氢的轻烃馏分，并将至少一定量的轻烃馏分再循环到烷基化反应器中。 烷基化方法单元包括氢化反应器，分馏单元和用于将气体馏分传送到氢化反应器并将轻质烃馏分传输到烷基化反应器的连接。

公开(公告)号：US20150329443A1

公开(公告)日：2015-11-19

申请号：US14701552

申请日：2015-05-01

申请人： Suzzy Chen Hsi HO ,  David B. SPRY ,  Elizabeth Louise WALKER

发明人： Suzzy Chen Hsi HO ,  David B. SPRY ,  Elizabeth Louise WALKER

IPC分类号： C07C6/04 ,  C07C2/58 ,  C07C6/06

CPC分类号： C07C6/04 ,  C07C2/58 ,  C07C6/06 ,  C07C7/177 ,  C07C2531/22 ,  C10G29/205 ,  C10G50/00 ,  C10G2400/02 ,  C07C11/107 ,  C07C9/14 ,  C07C11/10

摘要： A process for removing cyclopentene from the C5 fraction of a light olefin feed useful in an isoparaffin/olefin alkylation process redistributes fragments of C5 olefins formed by ring opening metathesis (ROM) in the presence of a catalyst. The higher molecular weight olefins produced in the reaction can be blended into the gasoline blend pool without imposing a significant or any vapor pressure penalty. Cyclopentene present in the C5 portion of the feed undergoes various ring opening reactions while other pentenes are converted to hydrocarbon products of lower and higher molecular weight relative to pentene. The reduction in cyclopentene results in a reduced tendency for the formation of acid soluble oil (ASO) during alkylation.

摘要翻译： 从用于异链烷烃/烯烃烷基化方法的轻质烯烃原料的C5馏分中除去环戊烯的方法在催化剂存在下重新分配由开环复分解（ROM）形成的C5烯烃的片段。 在反应中产生的较高分子量的烯烃可以混合到汽油混合池中，而不会造成显着的或任何蒸气压的损失。 存在于进料的C5部分中的环戊烯经历各种开环反应，而其它戊烯转化为相对于戊烯的较低和较高分子量的烃产物。 在烷基化过程中，环戊烯的还原导致形成酸溶性油（ASO）的倾向降低。

公开(公告)号：US20150274613A1

公开(公告)日：2015-10-01

申请号：US14229437

申请日：2014-03-28

申请人： UOP LLC

发明人： Trung Pham ,  Susie C. Martins ,  Douglas A. Nafis

IPC分类号： C07C5/32 ,  C07C7/00

CPC分类号： C07C7/005 ,  C07C2/58 ,  C07C5/41 ,  C10G11/18 ,  C10G45/58 ,  C10G45/68 ,  C10G69/04 ,  C10G69/123 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2400/02 ,  C10G2400/30 ,  C07C9/16 ,  C07C15/08 ,  C07C11/06

摘要： An integrated hydrocarbon conversion process is described. The process includes contacting a heavy hydrocarbon feedstock with a hydrocarbon cracking catalyst in a fluidized reactor zone to produce light olefins to form a fluid catalytic cracker (FCC) effluent stream comprising a range of hydrocarbons. The FCC effluent stream is separated to form at least a stream rich in C4 hydrocarbons which comprises isobutane and 1-butene. The stream rich in C4 hydrocarbons is introduced into an alkylation reaction zone where the isobutane and the 1-butene are alkylated to form a reaction product mixture comprising dimethylhexanes and C9+ hydrocarbons. The reaction product mixture is dehydrocyclized to form a stream rich in xylenes.

摘要翻译： 描述了一种综合烃转化方法。 该方法包括在流化反应器区中使重质烃原料与烃裂化催化剂接触以产生轻质烯烃以形成包含一系列烃的流化催化裂化器（FCC）流出物流。 FCC流出物流被分离以形成至少一种富含C4烃的物流，其中包含异丁烷和1-丁烯。 将富含C 4烃的物流引入烷基化反应区，其中异丁烷和1-丁烯被烷基化以形成包含二甲基己烷和C 9+烃的反应产物混合物。 将反应产物混合物脱氢环化以形成富含二甲苯的物流。