公开(公告)号：US20130165361A1

公开(公告)日：2013-06-27

申请号：US13332478

申请日：2011-12-21

申请人： ABHIMANYU O. PATIL ,  SATISH BODIGE ,  RANJAN TRIPATHY

发明人： ABHIMANYU O. PATIL ,  SATISH BODIGE ,  RANJAN TRIPATHY

IPC分类号： C10M169/04 ,  C07C41/30 ,  C10M107/20 ,  C07C43/04

CPC分类号： C10M169/04 ,  C10M107/20 ,  C10M107/24 ,  C10M145/04 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2205/173 ,  C10M2209/04 ,  C10M2209/043 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2230/70 ,  C10N2240/10 ,  C10N2270/00

摘要： The synthesis of high performance polyvinyl ether (PVE) fluids using a Lewis acid based cationic polymerization process is disclosed. The polyvinyl ether fluid have repeating vinyl ether units of the general formula —[CH2—CH(O—R)]n, wherein R is comprised of a branched or linear alkyl group having at least 4 carbon atoms and n is a whole number representing the average number of repeating units in the polyvinyl ether. The resulting PVE fluids exhibit excellent lubricant properties, similar to poly-alpha olefins (PAOs), but the PVE fluids have the benefit of higher polarity than PAOs and thus have better solubility and dispersity of polar additives.

摘要翻译： 公开了使用路易斯酸阳离子聚合方法合成高性能聚乙烯醚（PVE）流体。 聚乙烯基醚流体具有通式 - [CH 2 -CH（OR）] n的重复乙烯基醚单元，其中R由具有至少4个碳原子的支链或直链烷基组成，n是表示平均值的整数 聚乙烯醚中的重复单元数。 所得到的PVE流体表现出优异的润滑性能，类似于聚α-烯烃（PAO），但是PVE流体具有比PAO更高的极性，因此具有更好的极性添加剂的溶解性和分散性。

公开(公告)号：US20140213834A1

公开(公告)日：2014-07-31

申请号：US13751757

申请日：2013-01-28

申请人： ABHIMANYU O. PATIL ,  SATISH BODIGE ,  SHUJI LUO ,  JOHN W. CHU ,  KEVIN STAVENS ,  BRUCE A. HARRINGTON

发明人： ABHIMANYU O. PATIL ,  SATISH BODIGE ,  SHUJI LUO ,  JOHN W. CHU ,  KEVIN STAVENS ,  BRUCE A. HARRINGTON

IPC分类号： C10M107/10

CPC分类号： C10M107/10 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/14 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2270/00 ,  C08F2500/17 ,  C08F2500/03 ,  C08F4/65927

摘要： Provided is a polyalphaolefin (PAO) fluid including a polymer of one or more C8 to C12 alphaolefin monomers. The PAO has a viscosity (Kv100) from 300 to 900 cSt at 100° C.; a viscosity index (VI) greater than 250; a pour point (PP) less than −25° C.; a molecular weight distribution (Mw/Mn) less than 2.0 as synthesized; a residual unsaturation (Bromine Number) less than 2.0; and a glass transition temperature Tg less than −60° C. The PAO also has no crystallization peak as measured by differential scanning calorimetry and high thermal stability. A process to make and use the PAOs, including those having any combination of characteristics above is also provided. The PAOs are useful as synthetic base stocks and co-base stocks in lubricating oils, e.g., industrial lubes.

摘要翻译： 提供了包含一种或多种C 8 -C 12α-烯烃单体的聚合物的聚α-烯烃（PAO）流体。 PAO在100℃下的粘度（Kv100）为300-900cSt; 粘度指数（VI）大于250; 倾点（PP）小于-25°C; 合成的分子量分布（Mw / Mn）小于2.0; 残余不饱和度（溴数）小于2.0; 玻璃化转变温度Tg小于-60℃。通过差示扫描量热法和高热稳定性测定，PAO也没有结晶峰。 还提供了制作和使用PAO的方法，包括具有上述特征组合的那些。 PAO可用作润滑油（如工业润滑油）中的合成基础油和合成基础油。