公开(公告)号：US3538093A

公开(公告)日：1970-11-03

申请号：US3538093D

申请日：1969-09-04

Applicant: ALLIED CHEM

Inventor： JAMES PAUL ,  ULMER HARRY EDWARDS

IPC: A01N43/70 ,  C07D251/50 ,  C07D55/20

CPC classification number: C07D251/50 ,  A01N43/70

公开(公告)号：US3873624A

公开(公告)日：1975-03-25

申请号：US32797973

申请日：1973-01-30

Applicant: ALLIED CHEM

Inventor： MATHEW CHEMPOLIL THOMAS ,  ULMER HARRY EDWARDS

IPC: C07C323/22 ,  C07C45/63 ,  C07C47/14 ,  C07C67/00 ,  C07C313/00 ,  C07C319/14 ,  C07C319/20 ,  C07C323/47 ,  C07C325/00 ,  C07F9/40 ,  C07C47/00

CPC classification number: C07C319/14 ,  C07C45/63 ,  C07C47/14 ,  C07F9/4006 ,  C07C323/22 ,  C07C323/47 ,  C07C323/60

Abstract: AND OXIMATING THE Alpha -FORMYL SULFIDE TO FORM A 2HYDROCARBYLTHIOALDOXIME OF THE FORMULA

WHEREIN X is defined as above, reacting in an aqueous medium the Alpha -haloaldehyde with a thiol salt of the formula R''''''SM, wherein R'''''' and M are defined as above, to form an Alpha formyl sulfide of the formula

WHEREIN R'' and R'''' are defined as above, to form an Alpha haloaldehyde of the formula

Also, 2-hydrocarbylthioaldoximes are prepared by oximating the above Alpha -formyl sulfides by reaction with a source of hydroxylamine. Additionally, 2-hydrocarbylthioaldoximes are prepared by a process which comprises halogenating an aldehyde having the formula

WHEREIN R'' and R'''' independently are hydrogen, hydrocarbon radicals of 1 to 18 carbon atoms selected from the group consisting of alkyl, cycloalkyl, alkenyl, cycloalkenyl and aryl, or substituted hydrocarbon radicals of the above group, and X is a halogen selected from the group consisting of chlorine, bromine, and iodine, with a thiol salt of the formula R''''''SM, wherein R'''''' is a hydrocarbon radical of 1 to 18 carbon atoms selected from the group consisting of alkyl, cycloalkyl, alkenyl, cycloalkenyl and aryl or a substituted hydrocarbon radical of the above group; and M is an alkali or alkaline earth metal, thereby forming an Alpha -formyl sulfide of the formula

An Alpha -formyl sulfide is prepared by a process which comprises reacting in an aqueous medium an Alpha -haloaldehyde of the formula

Abstract translation: 通过一种方法制备α-甲酰基硫化物，该方法包括在水性介质中使式WHEREIN R'和R“的α-卤代醛独立地为氢，1至18个碳原子的烃基选自烷基 ，环烷基，烯基，环烯基和芳基或上述取代的烃基，X是选自氯，溴和碘的卤素，其具有式R“'SM的硫醇盐，其中 R“是选自上述基团的烷基，环烷基，烯基，环烯基和芳基或取代的烃基的1至18个碳原子的烃基; M是碱金属或碱土金属，从而形成下式的α-甲酰硫醚。另外，通过与羟胺源反应，使上述α-甲酰基硫化物肟化，制备2-烃基硫代肟。 另外，2-烃基硫代肟通过一种方法制备，该方法包括卤化具有如上定义的式WHEREIN R'和R“的醛，以形成式WHEREIN X如上所定义的α-卤代醛， 用式R“'SM的硫醇盐介导α-卤代醛，其中R”'和M如上所定义，以形成下式的α-甲酰硫醚，并且将α-甲酰硫醚氧化成形式A 公式的2-羟基乙酰氧基

公开(公告)号：US3494759A

公开(公告)日：1970-02-10

申请号：US3494759D

申请日：1968-09-13

Applicant: ALLIED CHEM

Inventor： MASON PAUL JAMES ,  ULMER HARRY EDWARDS

IPC: A01N43/70 ,  C07D251/50 ,  C07D55/22

CPC classification number: C07D251/50 ,  A01N43/70