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公开(公告)号：US20210147332A1
公开(公告)日：2021-05-20
申请号：US16623535
申请日：2018-06-20
Applicant: Archer Daniels Midland Company
Inventor： Pam Anklam , William Chris Hoffman , Mitchell Schultz , John G. Soper
Abstract: A method is provided for separating a dicarboxylic acid product from a mixture containing such dicarboxylic acids. The method involves: providing a dicarboxylic acid-containing mixture of which at least 35% of the carboxylic acid content of the mixture is a dicarboxylic acid product of interest; running an extraction of said dicarboxylic acid-containing mixture through a chromatographic column configured with an amphoteric resin, such that the dicarboxylic acid product elutes preferentially from the dicarboxylic acid-containing mixture. In certain embodiments, the dicarboxylic acid product of interest can be a glucaric or gluconic acid product from a mixture of either or both of these with still other carboxylic acids.
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Patent Agency Ranking
公开(公告)号：US11453636B2
公开(公告)日：2022-09-27
申请号：US16623535
申请日：2018-06-20
Applicant: Archer Daniels Midland Company
Inventor： Pam Anklam , William Chris Hoffman , Mitchell Schultz , John G. Soper
IPC: B01D15/36 , C07C51/47 , C07C59/105 , C07C59/285 , B01J43/00 , B01D15/18
Abstract: A method is provided for separating a dicarboxylic acid product from a mixture containing such dicarboxylic acids. The method involves: providing a dicarboxylic acid-containing mixture of which at least 35% of the carboxylic acid content of the mixture is a dicarboxylic acid product of interest; running an extraction of said dicarboxylic acid-containing mixture through a chromatographic column configured with an amphoteric resin, such that the dicarboxylic acid product elutes preferentially from the dicarboxylic acid-containing mixture. In certain embodiments, the dicarboxylic acid product of interest can be a glucaric or gluconic acid product from a mixture of either or both of these with still other carboxylic acids.
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公开(公告)号：US11078174B2
公开(公告)日：2021-08-03
申请号：US16622713
申请日：2018-06-20
Applicant: Archer Daniels Midland Company
Inventor： Pam Anklam , William Chris Hoffman , Stephen J. Howard , Alexandra Sanborn , Mitchell Schultz , John G. Soper
IPC: C07D307/68 , B01D15/18 , B01D15/36
Abstract: A process is provided for making esters of FDCA, in which an aqueous feed comprising glucaric acid is first reacted with a high boiling first alcohol in the presence of an acid catalyst and with removing water during the reaction, to form a first product mixture comprising a first ester of FDCA and the high boiling first alcohol, then unreacted high boiling first alcohol is removed from the first product mixture. The first ester of FDCA and the high boiling first alcohol is then transesterified with a lower boiling second alcohol selected from the group consisting of methanol, ethanol, isopropanol and n-propanol, to form a second product mixture comprising a second ester of FDCA with the lower boiling second alcohol, and the second ester of FDCA with the lower boiling second alcohol is recovered.
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公开(公告)号：US10308582B2
公开(公告)日：2019-06-04
申请号：US15532397
申请日：2015-11-23
Applicant: Archer Daniels Midland Company
Inventor： Thomas Binder , Ahmad K. Hilaly , Naveen S. Sudharsan , Kris N. Mani , Mitchell Schultz
IPC: C07C51/377 , C07C51/02 , C07C51/43 , C07C51/42 , C07C51/44 , C07C51/47 , C07C51/48 , C07C57/04 , C07C57/065 , C12P7/56 , B01D3/14 , B01D3/02 , B01D11/04 , B01D61/14 , B01J43/00 , C12P7/40 , B01D15/18 , B01D15/36 , B01D61/02 , C07C51/41
Abstract: A process is described for making acrylic acid from dextrose, which comprises fermenting dextrose; removing solids from the resulting fermentation broth; removing lactic acid from the clarified broth by extraction into an organic solvent; separating out the lactic acid-loaded organic solvent while recycling at least a portion of the remainder back to the fermentation step; reacting the lactic acid with ammonia to provide a dehydration feed comprising ammonium lactate while preferably recycling the organic solvent; carrying out a vapor phase dehydration of the ammonium lactate to produce a crude acrylic acid product; and purifying the crude acrylic acid by distillation followed by melt crystallization, chromatography or both melt crystallization and chromatography.
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公开(公告)号：US20160289161A1
公开(公告)日：2016-10-06
申请号：US15177488
申请日：2016-06-09
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor： Kenneth Stensrud , Mitchell Schultz , Padmesh VENKITASUBRAMANIAN
IPC: C07C67/10 , C07D307/68
CPC classification number: C07C67/10 , C07C67/11 , C07D307/68 , C07C69/40 , C07C69/675 , C07C69/716 , C07C69/704 , C07C69/44
Abstract: Esters and a process for making esters from organic acids by means of reacting a carboxylic acid with dialkylcarbonate in an alcohol-containing solvent without any extrinsic acid or base catalyst is described. A benefit of the preparation process is that it can make the separation and extraction of ester products simpler and more facile vis-à-vis conventional isolation techniques.
Abstract translation: 酯和通过使羧酸与碳酸二烷基酯在含醇溶剂中反应而无任何外来酸或碱催化剂从有机酸制备酯的方法。 制备过程的一个好处是它可以使酯类产品的分离和提取比传统的隔离技术更简单和更容易。
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6.发明授权公开(公告)号：US09272977B2
公开(公告)日：2016-03-01
申请号：US14399028
申请日：2013-04-17
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor： John G. Soper , Mitchell Schultz , Thomas P. Binder
CPC classification number: C07C51/47 , B01D15/327 , B01D15/426 , C07C51/42 , C12P7/46 , C07C55/10
Abstract: A process for purifying a filtered fermentation broth of succinic acid is described. The process involves separating succinic acid from the other organic acids and salts in a raw filtered broth using a non-functionalized chromatographic resin. The operation can be run either as an isocratic elution to yield free succinic acid, or as a gradient or binary elution to produce succinate salt.
Abstract translation: 描述了用于纯化过滤的琥珀酸发酵液的方法。 该方法包括使用非官能化色谱树脂将琥珀酸与原始过滤的肉汤中的其它有机酸和盐分离。 操作可以作为等度洗脱进行，以产生游离的琥珀酸，或者作为梯度或二元洗脱来产生琥珀酸盐。
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