公开(公告)号：US20140012059A1

公开(公告)日：2014-01-09

申请号：US13932032

申请日：2013-07-01

Applicant: AXENS

Inventor： Daniel-Jean VINEL ,  Jean-Alain CHODORGE ,  Jerome PIGOURIER ,  Pierre-Yves MARTIN ,  Laurent BOURNAY

IPC: C07C7/04

CPC classification number: C07C7/04 ,  C07C7/005 ,  C07C11/107

Abstract: A process for recovering 1-hexene comprising: a) separating the mixture obtained from the ethylene trimerization reaction into a top fraction comprising ethylene and a bottom fraction, b) separating a portion of the bottom fraction obtained from step a) into a top fraction comprising 1-hexene and 1-butene and a bottom fraction, c) separating a portion of the fraction comprising 1-hexene and 1-butene obtained from step b) into a top fraction principally comprising 1-butene and into a bottom fraction principally comprising 1-hexene, and in said process: a portion of the bottom fraction obtained from step b) is returned to the reaction section and another portion of said bottom fraction obtained from step b) is used in a recirculation loop connecting the reaction section and the column of said step b), said recirculation loop being used to cool the reaction section and to reboil said column of step b).

Abstract translation: 一种回收1-己烯的方法，包括：a）将由乙烯三聚反应获得的混合物分离成包含乙烯和底部馏分的顶部馏分，b）将由步骤a）获得的底部馏分的一部分分离成顶馏分， 1-己烯和1-丁烯和底部馏分，c）将由步骤b）获得的包含1-己烯和1-丁烯的馏分的一部分分离成主要包含1-丁烯的顶馏分，并将其分馏成主要包含1 - 己烯，并且在所述方法中：将从步骤b）获得的底部馏分的一部分返回到反应段，并且将从步骤b）获得的所述底部馏分的另一部分用于连接反应段和塔的再循环回路 在所述步骤b）中，所述再循环回路用于冷却反应段并重新沸腾步骤b）的所述塔。