CATALYSTS
    2.
    发明申请
    CATALYSTS 审中-公开
    催化剂

    公开(公告)号:US20100305286A1

    公开(公告)日:2010-12-02

    申请号:US12675545

    申请日:2008-08-27

    摘要: A complex comprising a ligand of formula (I), wherein each R1, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R1 groups on adjacent carbon atoms taken together may form an optionally substituted 5- to 8-membered fused ring; each R2, which may be the same or different is hydrogen, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, or an optionally substituted heterocyclyl group; R3, which binds to the 6-membered ring of the indenyl group, is —(Si(R5)2)p—, where p is 1 or 2, —(C(R5)2)n- where n is an integer of 2 or more; each R4 which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy, an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R4 groups on adjacent carbon atoms taken together can form an optionally substituted 5- to 8-membered fused carbon ring; each R5, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, or two R5 groups taken together can form an optionally substituted 5- to 8-membered ring; a is 0 to 3; b is 0 to 3; c is 0 to 4; complexed to a metal ion, M.

    摘要翻译: 包含式(I)的配体的络合物,其中每个R 1可以相同或不同,为氢,任选取代的C 1-20烃基,N(R 5)2,甲硅烷基,甲硅烷氧基; 任选取代的杂芳基,任选取代的杂环基或相邻碳原子上的两个R 1基团可以一起形成任选取代的5-至8-元稠环; 每个R 2可以相同或不同,为氢,为氢,任选取代的C 1-20烃基,N(R 5)2,甲硅烷基,甲硅烷氧基; 任选取代的杂芳基,或任选取代的杂环基; 结合茚基的6元环的R 3是 - (Si(R 5)2)p - ,其中p是1或2, - (C(R 5)2)n - ,其中n是 2以上; 每个R 4可以相同或不同,为氢,任选取代的C 1-20烃基,N(R 5)2,甲硅烷基,甲硅烷氧基,任选取代的杂芳基,任选取代的杂环基或相邻碳上的两个R 4基团 一起取代的原子可以形成任选取代的5至8元稠合碳环; 每个R 5可以相同或不同,为氢,任选取代的C 1-20烃基或两个R 5基团可以形成任选取代的5至8元环; a是0到3; b为0〜3; c为0〜4; 与金属离子络合