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1.发明申请USE OF A POROUS CRYSTALLINE HYBRID SOLID AS A NITROGEN OXIDE REDUCTION CATALYST AND DEVICES 审中-公开多孔结晶固体作为氮氧化物还原催化剂和器件的应用公开(公告)号：US20120129684A1
公开(公告)日：2012-05-24
申请号：US13322321
申请日：2010-05-28
申请人： Alexandre Vimont , Patricia Horcajada Cortes , Young Kyu Hwang , Gerard Ferey , Marco Daturi , Jong-San Chang , Christian Serre , Ji Yoon
发明人： Alexandre Vimont , Patricia Horcajada Cortes , Young Kyu Hwang , Gerard Ferey , Marco Daturi , Jong-San Chang , Christian Serre , Ji Yoon
CPC分类号： B01J31/1691 , B01D53/8628 , B01D53/9413 , B01D2255/20738 , B01J31/069 , B01J31/2239 , B01J2531/16 , B01J2531/22 , B01J2531/23 , B01J2531/26 , B01J2531/31 , B01J2531/32 , B01J2531/38 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/62 , B01J2531/72 , B01J2531/842
摘要： The present invention relates to the use of solids consisting of a metal-organic framework (MOF) and having the units of the following formula (I): MmOkXILp as a nitrogen-oxide catalyst. The present invention also relates to devices for enabling the implementation of said use. The nitrogen oxides in question are nitrogen monoxide and nitrogen dioxide, collectively referred to as NOx. The MOF solids of the present invention are advantageously capable of removing nitrogen oxides from a liquid or gaseous effluent, for example from water, from the exhaust gases of a vehicle, factory, workshop, laboratory, stored products, urban air vents, etc., without any reducing agent and at a low temperature. The DeNOx catalysis is a major issue for our societies. The invention can be used for reducing or even avoiding the consequences for public health of the toxic NOx gases resulting from human activity.
摘要翻译： 本发明涉及由金属 - 有机骨架（MOF）组成并具有下式（I）的单元的固体：MmOkXILp作为氮氧化物催化剂的用途。 本发明还涉及能够实现所述用途的装置。 所述氮氧化物是一氧化氮和二氧化氮，统称为NOx。 本发明的MOF固体有利地能够从车辆，工厂，车间，实验室，储存产品，城市通风口等的废气中除去来自液体或气态流出物例如水的氮氧化物， 没有任何还原剂和低温。 DeNOx催化是我们社会的一个主要问题。 本发明可用于减少或甚至避免由人类活动导致的有毒NOx气体对公众健康的后果。
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2.发明申请REDUCIBLE POROUS CRYSTALLINE HYBRID SOLID FOR THE SEPARATION OF MIXTURES OF MOLECULES HAVING DIFFERENT DEGREES AND/OR A DIFFERENT NUMBER OF UNSATURATIONS 有权用于分离具有不同程度和/或不同数量的不适感的分子混合物的可多孔多晶混合固体公开(公告)号：US20110172412A1
公开(公告)日：2011-07-14
申请号：US12996325
申请日：2009-06-11
申请人： Christian Serre , Alexandre Vimont , Philip Llewellyn , Jong-San Chang , Patricia Horcajada-Cortes , Gérard Ferey , Marco Daturi , Young-Kyu Hwang
发明人： Christian Serre , Alexandre Vimont , Philip Llewellyn , Jong-San Chang , Patricia Horcajada-Cortes , Gérard Ferey , Marco Daturi , Young-Kyu Hwang
摘要： The present invention relates to reducible porous crystalline solids, constituted of a metal-organic framework (MOF), for the separation of mixtures of molecules having different unsaturation degrees and/or a different number of unsaturations with a selectivity that can be adjusted by controlling the reduction of the MOF.The MOF solids of the present invention, after reduction, have a strong affinity for molecules containing at least one unsaturation. They can be used in various separation processes, especially those relating to hydrocarbons.
摘要翻译： 本发明涉及由金属 - 有机骨架（MOF）构成的可还原多孔结晶固体，用于分离具有不同不饱和度的分子和/或不同数目的不饱和度的分子的混合物，其选择性可以通过控制 减少财政部。 在还原后，本发明的MOF固体对含有至少一个不饱和键的分子具有强亲和力。 它们可用于各种分离过程，特别是与碳氢化合物有关的分离过程。
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3.发明授权Reducible porous crystalline hybrid solid for the separation of mixtures of molecules having different degrees and/or a different number of unsaturations 有权用于分离具有不同程度和/或不同数目的不饱和度的分子的混合物的可还原的多孔结晶杂化固体公开(公告)号：US08926736B2
公开(公告)日：2015-01-06
申请号：US12996325
申请日：2009-06-11
申请人： Christian Serre , Alexandre Vimont , Philip Llewellyn , Jong-San Chang , Patricia Horcajada-Cortes , Gérard Ferey , Marco Daturi , Young-Kyu Hwang
发明人： Christian Serre , Alexandre Vimont , Philip Llewellyn , Jong-San Chang , Patricia Horcajada-Cortes , Gérard Ferey , Marco Daturi , Young-Kyu Hwang
摘要： The present invention relates to reducible porous crystalline solids, constituted of a metal-organic framework (MOF), for the separation of mixtures of molecules having different unsaturation degrees and/or a different number of unsaturations with a selectivity that can be adjusted by controlling the reduction of the MOF. The MOF solids of the present invention, after reduction, have a strong affinity for molecules containing at least one unsaturation. They can be used in various separation processes, especially those relating to hydrocarbons.
摘要翻译： 本发明涉及由金属 - 有机骨架（MOF）构成的可还原多孔结晶固体，用于分离具有不同不饱和度的分子和/或不同数目的不饱和度的分子的混合物，其选择性可以通过控制 减少财政部。 在还原后，本发明的MOF固体对含有至少一个不饱和键的分子具有强亲和力。 它们可用于各种分离过程，特别是与碳氢化合物有关的分离过程。
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4.发明申请POROUS CRYSTALLINE HYBRID SOLID FOR ADSORBING AND RELEASING GAS OF BIOLOGICAL INTEREST 审中-公开多孔结晶固体吸附和释放生物利用气体公开(公告)号：US20110052650A1
公开(公告)日：2011-03-03
申请号：US12935642
申请日：2009-03-31
申请人： Russel Morris , Christian Serre , Patricia Horcajada Cortes , Alexandre Vimont , Thomas Devic , Gérard Ferey
发明人： Russel Morris , Christian Serre , Patricia Horcajada Cortes , Alexandre Vimont , Thomas Devic , Gérard Ferey
IPC分类号： A61K8/02 , A61K9/00 , A61K33/00 , A61K8/58 , A01N25/08 , A61K8/73 , A01N59/00 , A61P17/00 , A61P9/10 , A01P1/00 , A61P31/04
CPC分类号： C07F15/025 , A61K8/02 , A61K8/19 , A61K8/28 , A61K8/29 , A61K8/494 , A61K8/58 , A61K2800/58 , B01J20/226 , B01J20/28014 , B01J20/28069 , B01J20/28078 , B01J20/30 , B01J31/1691 , B01J31/2239 , B01J2531/842 , F17C11/00
摘要： The invention relates to solids made of a porous crystalline metal-organic framework (MOF) loaded with at least one gas of biological interest, and to a method for preparing the same. The MOF solids of the present invention are capable of adsorbing and releasing in a controlled manner gases having a biological interest. They can be used in the pharmaceutical field and/or for applications in the cosmetic field. They can also be used in the food industry.
摘要翻译： 本发明涉及由负载有至少一种生物学兴趣的气体的多孔结晶金属 - 有机骨架（MOF）制成的固体及其制备方法。 本发明的MOF固体能够以受控的方式吸附和释放具有生物学兴趣的气体。 它们可用于制药领域和/或用于化妆品领域。 它们也可用于食品工业。
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