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    2-hydroxy-2-phosphinyl ethanals and 1,2-dihydroxy-1,2-bisphosphinyl ethanes
    1.
    发明授权
    2-hydroxy-2-phosphinyl ethanals and 1,2-dihydroxy-1,2-bisphosphinyl ethanes 失效
    2-羟基-2-氧膦基乙烷和1,2-二羟基-1,2-二膦基乙烷

    公开(公告)号：US4613674A

    公开(公告)日：1986-09-23

    申请号：US522866

    申请日：1983-09-23

    申请人： Alexandros K. Tsolis ,  Ioannis A. Mikroyannidis

    发明人： Alexandros K. Tsolis ,  Ioannis A. Mikroyannidis

    IPC分类号： C07F9/38 ,  C07F9/40 ,  C07F9/53 ,  C08K5/5397

    CPC分类号： C07F9/4006 ,  C07F9/386 ,  C07F9/404 ,  C07F9/5329 ,  C08K5/5397

    摘要： This invention relates to novel substituted 2-hydroxy-2-phosphinyl ethanals of the general Formula I. ##STR1## to 1,2-dihydroxy-1,2-bisphosphinylethanes of the general Formula II ##STR2## to methods of making the same, to compositions containing compounds of the general Formula I, and/or of the general Formula II, to the use of such compositions to impart flame-resistance to cellulose and cellulose containing materials, to flame-resistant compositions containing compounds of the general Formula II and to the use of the compounds of the general Formula II as metal complexing agents.In the compounds of the Formulas I and II R.sub.1 and R.sub.2 may be the same or different radicals including alkoxy, aryloxy, arylalkoxy, cycloalkoxy, alkyl, alkenyl, aryl, aralkyl, cycloalkyl as well as such radicals containing substituents such as halogen, amino, hydroxy, alkoxy, mercapto, carboxy, carbalkoxy and the like in addition R.sub.1 and/or R.sub.2 may be hydroxy.

    摘要翻译： 本发明涉及通式Ⅰ的新型取代的2-羟基-2-氧膦基乙醇。通式II的I-1,2-二羟基-1,2-二膦基乙烷与制备 对于使用这种组合物赋予纤维素和含纤维素材料的阻燃性的含有通式I和/或通式II的化合物的组合物，含有含有通式I化合物的阻燃组合物 II和使用通式II的化合物作为金属络合剂。 在式I和II的化合物中，R 1和R 2可以是相同或不同的基团，包括烷氧基，芳氧基，芳基烷氧基，环烷氧基，烷基，烯基，芳基，芳烷基，环烷基以及含有取代基如卤素，氨基， 羟基，烷氧基，巯基，羧基，烷氧羰基等，另外R 1和/或R 2可以是羟基。

    4-Hydroxy-5-(substituted phosphinyl)ethyleneureas
    2.
    发明授权
    4-Hydroxy-5-(substituted phosphinyl)ethyleneureas 失效
    4-羟基-5-（取代的氧膦基）亚乙基脲

    公开(公告)号：US4435533A

    公开(公告)日：1984-03-06

    申请号：US288473

    申请日：1981-07-30

    申请人： Alexandros K. Tsolis ,  Ioannis A. Mikroyannidis

    发明人： Alexandros K. Tsolis ,  Ioannis A. Mikroyannidis

    IPC分类号： C07F9/6506 ,  C08K5/5373 ,  C09K21/12 ,  D06M13/285 ,  D06M13/432 ,  H01B7/28 ,  C07F9/65

    CPC分类号： D21H21/34 ,  C07F9/65066 ,  C08K5/5373 ,  C09K21/12 ,  D06M13/285 ,  D06M13/432 ,  D21H5/0002

    摘要： This invention relates to novel 4-hydroxy-5-(substituted phosphinyl)ethyleneureas of the general Formula I ##STR1## to methods of making the same, to flame resistant compositions containing such compounds and to the use of compositions containing such compounds to impart flame resistance to cellulose and cellulose containing materials.In the compounds of the Formula I X or Y may be hydrogen or alkyl, R.sub.1 and R.sub.2 may be the same or different radicals including alkoxy, cycloalkoxy, aryloxy, arylalkoxy, alkyl, aryl as well as such radicals containing substituents such as halogen; in addition, R.sub.1 and/or R.sub.2 may be hydroxy.

    摘要翻译： 本发明涉及通式Ⅰ的新型4-羟基-5-（取代的氧膦基）亚乙烯基脲，其制备方法为含有这些化合物的阻燃组合物，以及含有这些化合物的组合物的用途 对纤维素和含纤维素材料的阻燃性。 在式I的化合物中，X或Y可以是氢或烷基，R 1和R 2可以是相同或不同的基团，包括烷氧基，环烷氧基，芳氧基，芳基烷氧基，烷基，芳基以及这些基团， 此外，R 1和/或R 2可以是羟基。

    2-Hydroxy-2-phosphinyl ethanals and 1,2-dihydroxy-1,2 bisphosphinyl ethanes
    3.
    发明授权
    2-Hydroxy-2-phosphinyl ethanals and 1,2-dihydroxy-1,2 bisphosphinyl ethanes 失效
    2-羟基-2-氧膦基乙烷和1,2-二羟基-1,2-二膦基乙烷

    公开(公告)号：US4431596A

    公开(公告)日：1984-02-14

    申请号：US288607

    申请日：1981-07-30

    申请人： Alexandros K. Tsolis ,  Ioannis A. Mikroyannidis

    发明人： Alexandros K. Tsolis ,  Ioannis A. Mikroyannidis

    IPC分类号： C07F9/38 ,  C07F9/40 ,  C07F9/53 ,  C08K5/5397

    CPC分类号： C07F9/4006 ,  C07F9/386 ,  C07F9/404 ,  C07F9/5329 ,  C08K5/5397

    摘要： This invention relates to novel substituted 2-hydroxy-2-phosphinyl ethanals of the general Formula I. ##STR1## to 1,2-dihydroxy-1,2-bisphosphinylethanes of the general Formula II ##STR2## to methods of making the same, to compositions containing compounds of the general Formula I, and/or of the general Formula II, to the use of such compositions to impart flame-resistance to cellulose and cellulose containing materials, to flame-resistant compositions containing compounds of the general Formula II and to the use of the compounds of the general Formula II as metal complexing agents.In the compounds of the Formulas I and II R.sub.1 and R.sub.2 may be the same or different radicals including alkoxy, aryloxy, arylalkoxy, cycloalkoxy, alkyl, alkenyl, aryl, aralkyl, cycloalkyl as well as such radicals containing substituents such as halogen, amino, hydroxy, alkoxy, mercapto, carboxy, carbalkoxy and the like in addition R.sub.1 and/or R.sub.2 may be hydroxy.

    摘要翻译： 本发明涉及通式Ⅰ的新型取代的2-羟基-2-氧膦基乙醇。通式II的I-1,2-二羟基-1,2-二膦基乙烷与制备 对于使用这种组合物赋予纤维素和含纤维素材料的阻燃性的含有通式I和/或通式II的化合物的组合物，含有含有通式I化合物的阻燃组合物 II和使用通式II的化合物作为金属络合剂。 在式I和II的化合物中，R 1和R 2可以是相同或不同的基团，包括烷氧基，芳氧基，芳基烷氧基，环烷氧基，烷基，烯基，芳基，芳烷基，环烷基以及含有取代基如卤素，氨基， 羟基，烷氧基，巯基，羧基，烷氧羰基等，另外R 1和/或R 2可以是羟基。

    N-(Substituted phosphinyl) polyamides
    5.
    发明授权
    N-(Substituted phosphinyl) polyamides 失效
    N-（取代的氧膦基）聚酰胺

    公开(公告)号：US4442268A

    公开(公告)日：1984-04-10

    申请号：US290087

    申请日：1981-08-04

    申请人： Alexandros K. Tsolis

    发明人： Alexandros K. Tsolis

    IPC分类号： C08G69/42 ,  C08G69/48

    CPC分类号： C08G69/42 ,  C08G69/48

    摘要： N-(Substituted phosphinyl) polyamides and a method for their production are disclosed. The N-(substituted phosphinyl) polyamides are characterized by the recurring unit structure represented by the formula ##STR1## wherein A is in part hydrogen and in part a substituted phosphinyl radical. One method of producing the N-(substituted phosphinyl) polyamides is treating N-chlorinated polyamide with substituted phosphinyl compounds. The disclosed N-(substituted phosphinyl) polyamides exhibit excellent thermal stability fire resistance, good processability, high water absorption and permeability. The N-(substituted phosphinyl) polyamides are useful for making flame resistant textile materials.

    摘要翻译： 公开了N-（取代的氧膦基）聚酰胺及其制备方法。 N-（取代的氧膦基）聚酰胺的特征在于由下式表示的重复单元结构：其中A部分为氢，部分为取代的氧膦基。 制备N-（取代的氧膦基）聚酰胺的一种方法是用取代的氧膦基化合物处理N-氯化聚酰胺。 所公开的N-（取代的氧膦基）聚酰胺表现出优异的热稳定性耐火性，良好的加工性，高吸水率和渗透性。 N-（取代的氧膦基）聚酰胺可用于制造阻燃纺织材料。