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1.发明授权Trihydrocarbyl silyl substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous hydroformylation-aldolization catalysts 失效三烃基甲硅烷基取代的烷基二芳基膦过渡金属络合物及其作为均相加氢甲酰化 - 醛醇化催化剂的用途
公开(公告)号：US4454353A
公开(公告)日：1984-06-12
申请号：US426663
申请日：1982-09-29
CPC分类号： B01J31/1608 , B01J31/20 , B01J31/2404 , B01J31/2409 , C07C29/16 , C07C31/125 , C07C45/49 , C07C45/50 , C07F15/004 , C07F15/0053 , C07F9/5009 , C07F9/5045 , B01J2231/321 , B01J2231/34 , B01J2531/0258 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845
摘要： Described is a carbonylation process using novel homogeneous trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes of the general formula:[(Ar.sub.2 PQ).sub.y SiR.sub.4 -y].sub.g (MX.sub.n).sub.swherein Ar is a C.sub.6 to C.sub.10 aromatic hydrocarbyl radical, Q is a C.sub.1 to C.sub.30 saturated straight chain divalent radical, R is a C.sub.1 to C.sub.10 hydrocarbyl, wherein Ar, Q and R, can be substituted or unsubstituted, y is 1 to 4, g times y is 1 to 6, M is a transition metal selected from the group consisting of Group VIII transition metals, X is an anion or organic ligand excluding halogen satisfying the valence and coordination sites of the metal, n is 2 to 6 and s is 1 to 3, are disclosed. These materials exhibit high thermal stability and are superior catalysts for the selective hydroformylation of olefins, particularly in the presence of excess quantities of ligand of the formula:(Ar.sub.2 PQ)ySiR.sub.4-ywherein Ar, Q, R, and y are as previously defined.Specifically, tris-(trimethyl silyl-ethyl diphenyl phosphine) rhodium carbonyl hydride,[(CH.sub.3).sub.3 Si-CH.sub.2 CH.sub.2 -PPh.sub.2 ].sub.3 Rh(CO)Hand tris [bis-(diphenylphosphinoethyl)dimethyl silane] rhodium carbonyl hydride,[(CH.sub.3).sub.2 Si-CH.sub.2 CH.sub.2 -PPh.sub.2 ].sub.3 Rh(CO)H,are selective olefin hydroformylation catalysts, particularly in the presence of excess trihydrocarbyl silyl-substituted alkyl diaryl phosphine ligand.
摘要翻译： 描述了使用通式为[（Ar 2 PQ）y SiR 4-y] g（MXn）s的新型均相三烃基甲硅烷基取代的烷基二芳基膦过渡金属络合物的羰基化方法，其中Ar为C 6至C 10芳族烃基，Q为 C1至C30饱和直链二价基团，R为C1至C10烃基，其中Ar，Q和R可以是取代或未取代的，y为1至4，g为y为1至6，M为选定的过渡金属 从由VIII族过渡金属组成的组中，X是除了满足金属的化合价和配位的卤素的阴离子或有机配体，n为2〜6，s为1〜3。 这些材料表现出高的热稳定性，并且是用于烯烃的选择性加氢甲酰化的优异催化剂，特别是在过量的式（I 2 PQ）y SiR 4-y配位体的存在下，其中Ar，Q，R和y如前所定义。 具体地，三（甲基甲硅烷基 - 乙基二苯基膦）羰基氢化铑，[（CH3）3Si-CH2CH2-PPh2] 3Rh（CO）H和三[双 - （二苯基膦基乙基）二甲基硅烷]铑羰基氢化物，[（CH 3） 2Si-CH2CH2-PPh2] 3Rh（CO）H是选择性烯烃加氢甲酰化催化剂，特别是在过量的三烃基甲硅烷基取代的烷基二芳基膦配体的存在下。
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2.发明授权Trihydrocarbyl silyl substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous carbonylation catalysts 失效三烃基甲硅烷基取代的烷基二芳基膦过渡金属络合物及其作为均相羰基化催化剂的用途
公开(公告)号：US4480137A
公开(公告)日：1984-10-30
申请号：US426664
申请日：1982-09-29
CPC分类号： B01J31/1608 , B01J31/20 , B01J31/2404 , B01J31/2409 , C07C29/16 , C07C31/125 , C07C45/49 , C07C45/50 , C07F15/004 , C07F15/0053 , C07F9/5009 , C07F9/5045 , B01J2231/321 , B01J2231/34 , B01J2531/0258 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845
摘要： Described is a carbonylation process using novel homogeneous trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes of the general formula:[(Ar.sub.2 PQ).sub.y SiR.sub.4 --y].sub.g (MX.sub.n).sub.swherein Ar is a C.sub.6 to C.sub.10 aromatic hydrocarbyl radical, Q is a C.sub.1 to C.sub.30 saturated straight chain divalent radical, R is a C.sub.1 to C.sub.10 hydrocarbyl, wherein Ar, Q and R, can be substituted or unsubstituted, y is 1 to 4, g times y is 1 to 6, M is a transition metal selected from the group consisting of Group VIII transition metals, X is an anion or organic ligand excluding halogen satisfying the valence and coordination sites of the metal, n is 2 to 6 and s is 1 to 3, are disclosed. These materials exhibit high thermal stability and are superior catalysts for the selective hydroformylation of olefins, particularly in the presence of excess quantities of ligand of the formula:(Ar.sub.2 PQ).sub.y SiR.sub.4 -.sub.ywherein Ar, Q, R, and y are as previously defined.Specifically, tris-(trimethyl silyl-ethyl diphenyl phosphine) rhodium carbonyl hydride,[(CH.sub.3).sub.3 Si--CH.sub.2 CH.sub.2 -PPh.sub.2 ].sub.3 Rh(CO)Hand tris [bis-(diphenylphosphinoethyl) dimethyl silane] rhodium carbonyl hydride,[(CH.sub.3).sub.2 Si--CH.sub.2 CH.sub.2 -PPh.sub.2 ].sub.3 Rh(CO)H,are selective olefin hydroformylation catalysts, particularly in the presence of excess trihydrocarbyl silyl-substituted alkyl diaryl phosphine ligand.
摘要翻译： 描述了使用通式为[（Ar 2 PQ）y SiR 4-y] g（MXn）s的新型均相三烃基甲硅烷基取代的烷基二芳基膦过渡金属络合物的羰基化方法，其中Ar为C6至C10芳族烃基，Q为 C1至C30饱和直链二价基团，R为C1至C10烃基，其中Ar，Q和R可以是取代或未取代的，y为1至4，g为y为1至6，M为选定的过渡金属 从由VIII族过渡金属组成的组中，X是除了满足金属的化合价和配位的卤素以外的阴离子或有机配体，n为2〜6，s为1〜3。 这些材料表现出高的热稳定性，并且是用于烯烃的选择性加氢甲酰化的优异催化剂，特别是在过量的式（I 2 PQ）y SiR 4-y配位体的存在下，其中Ar，Q，R和y如前所定义。 具体地，三（甲基甲硅烷基 - 乙基二苯基膦）羰基氢化铑，[（CH3）3Si-CH2CH2-PPh2] 3Rh（CO）H和三[双 - （二苯基膦基乙基）二甲基硅烷]铑羰基氢化物，[（CH 3） 2Si-CH2CH2-PPh2] 3Rh（CO）H是选择性烯烃加氢甲酰化催化剂，特别是在过量的三烃基甲硅烷基取代的烷基二芳基膦配体的存在下。
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3.发明授权Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes 失效用甲硅烷基取代的烷基二芳基膦金属络合物进行均相加氢甲酰化催化
公开(公告)号：US4450299A
公开(公告)日：1984-05-22
申请号：US295193
申请日：1981-08-21
IPC分类号： B01J31/24 , C07C29/16 , C07C31/125 , C07C45/49 , C07C45/50 , C07F9/50 , C07F15/00 , C07C49/50
CPC分类号： B01J31/1608 , B01J31/20 , B01J31/2404 , B01J31/2409 , C07C29/16 , C07C31/125 , C07C45/49 , C07C45/50 , C07F15/004 , C07F15/0053 , C07F9/5009 , C07F9/5045 , B01J2231/321 , B01J2231/34 , B01J2531/0258 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845
摘要： Described is a carbonylation process using novel homogeneous trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes of the general formula:[(Ar.sub.2 PQ).sub.y SiR.sub.4 -y].sub.g (MX.sub.n).sub.swherein Ar is a C.sub.6 to C.sub.10 aromatic hydrocarbyl radical, Q is a C.sub.1 to C.sub.30 saturated straight chain divalent radical, R is a C.sub.1 to C.sub.10 hydrocarbyl, wherein Ar, Q and R, can be substituted or unsubstituted, y is 1 to 4, g times y is 1 to 6, M is a transition metal selected from the group consisting of Group VIII transition metals, X is an anion or organic ligand excluding halogen satisfying the valence and coordination sites of the metal, n is 2 to 6 and s is 1 to 3, are disclosed. These materials exhibit high thermal stability and are superior catalysts for the selective hydroformylation of olefins, particularly in the presence of excess quantities of ligand of the formula:(Ar.sub.2 PQ).sub.y SiR.sub.4-ywherein Ar, Q, R, and y are as previously defined.Specifically, tris-(trimethyl silyl-ethyl diphenyl phosphine) rhodium carbonyl hydride,[(CH.sub.3).sub.3 Si--CH.sub.2 CH.sub.2 --PPh.sub.2 ].sub.3 Rh(CO)Hand tris [bis-(diphenylphosphinoethyl)dimethylsilane] rhodium carbonyl hydride,[(CH.sub.3).sub.2 Si--CH.sub.2 CH.sub.2 --PPh.sub.2 ].sub.3 Rh(CO)H,are selective olefin hydroformulation catalysts, particularly in the presence of excess trihydrocarbyl silyl-substituted alkyl diaryl phosphine ligand.
摘要翻译： 描述了使用通式为[（Ar 2 PQ）y SiR 4-y] g（MXn）s的新型均相三烃基甲硅烷基取代的烷基二芳基膦过渡金属络合物的羰基化方法，其中Ar为C6至C10芳族烃基，Q为 C1至C30饱和直链二价基团，R为C1至C10烃基，其中Ar，Q和R可以是取代或未取代的，y为1至4，g为y为1至6，M为选定的过渡金属 从由VIII族过渡金属组成的组中，X是除了满足金属的化合价和配位的卤素以外的阴离子或有机配体，n为2〜6，s为1〜3。 这些材料表现出高的热稳定性，并且是用于烯烃的选择性加氢甲酰化的优异催化剂，特别是在过量的式（I 2 PQ）y SiR 4-y配位体的存在下，其中Ar，Q，R和y如前所定义。 具体地，三（三甲基甲硅烷基 - 乙基二苯基膦）羰基氢化铑，[（CH3）3Si-CH2CH2-PPh2] 3Rh（CO）H和三[双 - （二苯基膦基乙基）二甲基硅烷]羰基氢化铑，[（CH 3） -CH 2 CH 2 -PPh 2] 3Rh（CO）H是选择性烯烃加氢配制催化剂，特别是在过量的三烃基甲硅烷基取代的烷基二芳基膦配体的存在下。
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4.发明授权Trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous catalysts 失效三烃基甲硅烷基取代的烷基二芳基膦过渡金属络合物及其作为均相催化剂的用途
公开(公告)号：US4298541A
公开(公告)日：1981-11-03
申请号：US11238
申请日：1979-02-12
CPC分类号： B01J31/1608 , B01J31/2404 , C07C45/49 , C07C45/50 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845
摘要： Novel homogeneous trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes of the general formula:[(Ar.sub.2 PQ).sub.y SiR.sub.4-y ].sub.g (MX.sub.n).sub.swherein Ar is a C.sub.6 to C.sub.10 aromatic hydrocarbyl radical, Q is a C.sub.1 to C.sub.30 saturated straight chain divalent radical either unsubstituted or substituted, R is an unsubstituted C.sub.1 to C.sub.10 hydrocarbyl, C.sub.1 to C.sub.10 monosubstituted hydrocarbyl, phenyl radical, y is 1 to 4, g times y is 1 to 6, M is a transition metal selected from the group consisting of Group VIII transition metals, X is an anion or organic ligand excluding halogen satisfying the coordination sites of the metal, n is 2 to 6 and s is 1 to 3, are disclosed. These materials are superior catalysts for the selective hydroformylation of olefins, particularly in the presence of excess quantities of the ligand of the formula:[(Ar.sub.2 P)[Q].sub.y SiR.sub.4-y ]wherein Ar, Q, R, and y are as previously defined.
摘要翻译： 新型均相三烃基甲硅烷基取代的通式为[（Ar2PQ）ySiR4-y] g（MXn）的烷基二芳基膦过渡金属络合物，其中Ar为C6至C10芳族烃基，Q为C1至C30饱和直链 未取代或取代的二价基团，R为未取代的C1至C10烃基，C1至C10单取代的烃基，苯基，y为1至4，g为y为1至6，M为选自以下的过渡金属： VIII族过渡金属，X是不含卤素的阴离子或有机配体，满足金属的配位点，n为2-6，s为1〜3。 这些材料是用于烯烃的选择性加氢甲酰化的优异催化剂，特别是在过量的下式配位体存在下：[（Ar 2 P）[Q] y SiR 4-y]其中Ar，Q，R和y如前所定义 。
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5.发明授权Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes 失效支链烷基二芳基膦铑配合物的羰基化催化
公开(公告)号：US4593141A
公开(公告)日：1986-06-03
申请号：US756564
申请日：1985-07-18
CPC分类号： B01J31/20 , B01J31/24 , B01J31/2404 , B01J31/2409 , B01J31/2414 , C07C45/49 , C07C45/50 , C07C45/74 , B01J2231/321 , B01J2531/0258 , B01J2531/822
摘要： Branched alkyl diaryl phosphine rhodium carbonyl hydride complexes are surprisingly effective, stable and selective hydroformylation catalysts particularly in the presence of a large excess of t-phosphine ligands. As such, they are advantageously employed as catalysts in a novel low pressure rhodium hydroformylation process producing normal and iso aldehydes by reacting olefins with H.sub.2 and CO.
摘要翻译： 分支烷基二芳基膦铑羰基氢化物络合物是惊人的有效，稳定和选择性加氢甲酰化催化剂，特别是在大量过量的t-膦配体的存在下。 因此，它们有利地用作新颖的低压铑加氢甲酰化方法中的催化剂，其通过使烯烃与H 2和CO反应生成正醛和异醛。
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6.发明授权Trihydrocarbyl silyl substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous isomerization hydroformylation catalysts 失效三烃基甲硅烷基取代的烷基二芳基膦过渡金属络合物及其作为均相异构化加氢甲酰化催化剂的用途
公开(公告)号：US4451673A
公开(公告)日：1984-05-29
申请号：US426662
申请日：1982-09-29
CPC分类号： B01J31/1608 , B01J31/20 , B01J31/2404 , B01J31/2409 , C07C29/16 , C07C31/125 , C07C45/49 , C07C45/50 , C07F15/004 , C07F15/0053 , C07F9/5009 , C07F9/5045 , B01J2231/321 , B01J2231/34 , B01J2531/0258 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845
摘要： Described is a carbonylation process using novel homogeneous trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes of the general formula:[(Ar.sub.2 PQ).sub.y SiR.sub.4 --y].sub.g (MX.sub.n).sub.swherein Ar is a C.sub.6 to C.sub.10 aromatic hydrocarbyl radical, Q is a C.sub.1 to C.sub.30 saturated straight chain divalent radical, R is a C.sub.1 to C.sub.10 hydrocarbyl, wherein Ar, Q and R, can be substituted or unsubstituted, y is 1 to 4, g times y is 1 to 6, M is a transition metal selected from the group consisting of Group VIII transition metals, X is an anion or organic ligand excluding halogen satisfying the valence and coordination sites of the metal, n is 2 to 6 and s is 1 to 3, are disclosed. These materials exhibit high thermal stability and are superior catalysts for the selective hydroformylation of olefins, particularly in the presence of excess quantities of ligand of the formula:(Ar.sub.2 PQ)ySiR.sub.4-ywherein Ar, Q, R, and y are as previously defined.Specifically, tris-(trimethyl silyl-ethyl diphenyl phosphine) rhodium carbonyl hydride,[(CH.sub.3).sub.3 Si--CH.sub.2 CH.sub.2 --PPh.sub.2 ].sub.3 Rh(CO)Hand tris [bis-(diphenylphosphinoethyl)dimethyl silane] rhodium carbonyl hydride,[(CH.sub.3).sub.2 Si--CH.sub.2 CH.sub.2 --PPh.sub.2 ].sub.3 Rh(CO)H,are selective olefin hydroformylation catalysts, particularly in the presence of excess trihydrocarbyl silyl-substituted alkyl diaryl phosphine ligand.
摘要翻译： 描述了使用通式为[（Ar 2 PQ）y SiR 4-y] g（MXn）s的新型均相三烃基甲硅烷基取代的烷基二芳基膦过渡金属络合物的羰基化方法，其中Ar为C 6至C 10芳族烃基，Q为 C1至C30饱和直链二价基团，R为C1至C10烃基，其中Ar，Q和R可以是取代或未取代的，y为1至4，g为y为1至6，M为选定的过渡金属 从由VIII族过渡金属组成的组中，X是除了满足金属的化合价和配位的卤素的阴离子或有机配体，n为2〜6，s为1〜3。 这些材料表现出高的热稳定性，并且是用于烯烃的选择性加氢甲酰化的优异催化剂，特别是在过量的式（I 2 PQ）y SiR 4-y配位体的存在下，其中Ar，Q，R和y如前所定义。 具体地，三（甲基甲硅烷基 - 乙基二苯基膦）羰基氢化铑，[（CH3）3Si-CH2CH2-PPh2] 3Rh（CO）H和三[双 - （二苯基膦基乙基）二甲基硅烷]铑羰基氢化物，[（CH 3） 2Si-CH2CH2-PPh2] 3Rh（CO）H是选择性烯烃加氢甲酰化催化剂，特别是在过量的三烃基甲硅烷基取代的烷基二芳基膦配体的存在下。
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7.发明授权Branched alkyl-aromatic sulfonic acid dispersants for solublizing asphaltenes in petroleum oils 有权用于在石油中溶解沥青质的支链烷基 - 芳族磺酸分散剂
公开(公告)号：US6048904A
公开(公告)日：2000-04-11
申请号：US203141
申请日：1998-12-01
申请人： Irwin A. Wiehe , Ramesh Varadaraj , Torris G. Jermansen , Raymond J. Kennedy , Cornelius H. Brons
发明人： Irwin A. Wiehe , Ramesh Varadaraj , Torris G. Jermansen , Raymond J. Kennedy , Cornelius H. Brons
IPC分类号： B01F17/12 , C07C309/31 , C07C309/33 , C07C309/34 , C07C309/37 , C08L95/00 , C10C3/00 , C10G75/04 , C10L1/24 , C10L10/00 , C07C7/20 , C07C303/02
CPC分类号： C07C309/31 , C07C309/33 , C07C309/34 , C07C309/37 , C10L1/2437 , C10L1/2475 , C10L10/04 , C07C2102/10 , C07C2103/26 , Y10S516/909
摘要： The present invention is an asphaltene dispersant containing an aromatic, a sulfonic acid head, and an alkyl tail containing 16 carbons or more and at least one branch of a methyl or longer alkyl. Preferably, the aromatic is a fused two ring aromatic and the tail is a two, branched alkyl tail of 30 carbons or longer.
摘要翻译： 本发明是一种沥青质分散剂，其含有芳香族，磺酸类和含有16个以上碳原子的烷基尾
部和至少一个甲基或更长烷基的分支。 优选地，芳族化合物是稠合的两环芳族化合物，尾部是30个碳原子或更长的两个支链烷基尾部。
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