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1.发明授权Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst composition, use of the catalysts for conducting such reactions, and the products of such reactions 有权制备高活性一氧化碳氢化催化剂的方法; 催化剂组合物，用于进行这种反应的催化剂的使用以及这些反应的产物公开(公告)号：US06313062B1
公开(公告)日：2001-11-06
申请号：US09430805
申请日：1999-10-29
IPC分类号： B01J2340
CPC分类号： C10G2/332 , B01J21/04 , B01J23/40 , B01J23/8913 , B01J37/0205 , B01J37/06 , B01J37/086 , B01J37/18 , C10G2/333
摘要： A process for the preparation of a catalyst useful for conducting carbon monoxide hydrogenation reactions, particularly Fischer-Tropsch reactions; the catalyst compositions, use of the catalyst compositions for conducting such reactions, and the products of these reactions. The steps of the process for producing the catalyst comprise impregnating a powder, or particulate refractory inorganic oxide solids, preferably silica, with a) a soluble compound or salt of a catalytic metal of the Iron Group, preferably cobalt, and b) a soluble compound, or salt, of a Group VIII noble metal, preferably platinum, suitably by sequential contact of the solids with a solution of (a) and a solution of (b), by sequential contact of the solids with a solution of (b) and a solution of (a), or by contact with a solution which contains both (a) and (b). The metals impregnated solids, or particulate solids precursor material, after impregnation with the Group VIII noble metal, is washed with a hydrocarbyl ammonium hydroxide or ammonium hydroxide solution, the material shaped, dried and calcined, and the metals components thereof thereafter reduced to form the finished catalyst. The catalyst formed from the hydrocarbyl ammonium hydroxide or ammonium hydroxide-washed catalyst precursor, quite surprisingly, is more active and selective in conducting a carbon monoxide hydrogenation reaction to produce hydrocarbon waxes, with lower gas make, than a catalyst of corresponding composition similarly prepared except that the catalyst was prepared from a catalyst precursor which was not washed with a hydrocarbyl ammonium hydroxide or ammonium hydroxide solution.
摘要翻译： 一种用于制备用于进行一氧化碳氢化反应，特别是费 - 托反应的催化剂的方法; 催化剂组合物，催化剂组合物用于进行这种反应的用途，以及这些反应的产物。 制备催化剂的方法的步骤包括用a）可溶性化合物或铁组的催化金属的盐，优选钴浸渍粉末或颗粒难熔的无机氧化物固体，优选二氧化硅，和b）可溶化合物 ，或第（VIII）族贵金属，优选铂，适当地通过固体与（a）和（b）的溶液的顺序接触，通过将固体与（b）和 （a）的溶液或通过与包含（a）和（b）的溶液的接触）。 在用VIII族贵金属浸渍之后，将金属浸渍的固体或固体颗粒的前体材料用烃基氢氧化铵或氢氧化铵溶液洗涤，将其成型，干燥和煅烧，然后将其金属组分还原形成 成品催化剂。 由烃基氢氧化铵或氢氧化铵洗涤的催化剂前体形成的催化剂相当令人惊奇地在进行一氧化碳氢化反应以产生具有较低气体产生的烃蜡的催化剂中，比类似制备的相应组合物的催化剂更具活性和选择性， 催化剂由未用烃基氢氧化铵或氢氧化铵溶液洗涤的催化剂前体制备。
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公开(公告)号：US06765026B2
公开(公告)日：2004-07-20
申请号：US10376584
申请日：2003-02-28
IPC分类号： C07C2706
CPC分类号： C10G2/332 , B01J21/04 , B01J23/40 , B01J23/8913 , B01J37/0205 , B01J37/06 , B01J37/086 , B01J37/18 , C10G2/333
摘要： A process for the preparation of a catalyst useful for conducting carbon monoxide hydrogenation reactions, particularly Fischer-Tropsch reactions; the catalyst compositions, use of the catalyst compositions for conducting such reactions, and the products of these reactions. The steps of the process for producing the catalyst comprise impregnating a powder, or particulate refractory inorganic oxide solids, preferably silica, with a) a soluble compound or salt of a catalytic metal of the Iron Group, preferably cobalt, and b) a soluble compound, or salt, of a Group VIII noble metal, preferably platinum, suitably by sequential contact of the solids with a solution of (a) and a solution of (b), by sequential contact of the solids with a solution of (b) and a solution of (a), or by contact with a solution which contains both (a) and (b). The metals impregnated solids, or particulate solids precursor material, after impregnation with the Group VIII noble metal, is washed with a hydrocarbyl ammonium hydroxide or ammonium hydroxide solution, the material shaped, dried and calcined, and the metals components thereof thereafter reduced to form the finished catalyst. The catalyst formed from the hydrocarbyl ammonium hydroxide or ammonium hydroxide-washed catalyst precursor, quite surprisingly, is more active and selective in conducting a carbon monoxide hydrogenation reaction to produce hydrocarbon waxes, with lower gas make, than a catalyst of corresponding composition similarly prepared except that the catalyst was prepared from a catalyst precursor which was not washed with a hydrocarbyl ammonium hydroxide or ammonium hydroxide solution.
摘要翻译： 一种用于制备用于进行一氧化碳氢化反应，特别是费 - 托反应的催化剂的方法; 催化剂组合物，催化剂组合物用于进行这种反应的用途，以及这些反应的产物。 制备催化剂的方法的步骤包括用a）可溶性化合物或铁组的催化金属的盐，优选钴浸渍粉末或颗粒难熔的无机氧化物固体，优选二氧化硅，和b）可溶化合物 ，或第（VIII）族贵金属，优选铂，适当地通过固体与（a）和（b）的溶液的顺序接触，通过将固体与（b）和 （a）的溶液或通过与包含（a）和（b）的溶液的接触）。 在用VIII族贵金属浸渍之后，将金属浸渍的固体或固体颗粒的前体材料用烃基氢氧化铵或氢氧化铵溶液洗涤，将其成型，干燥和煅烧，然后将其金属组分还原形成 成品催化剂。 由烃基氢氧化铵或氢氧化铵洗涤的催化剂前体形成的催化剂相当令人惊奇地在进行一氧化碳氢化反应以产生具有较低气体产生的烃蜡的催化剂中，比类似制备的相应组合物的催化剂更具活性和选择性， 催化剂由未用烃基氢氧化铵或氢氧化铵溶液洗涤的催化剂前体制备。
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公开(公告)号：US06355593B1
公开(公告)日：2002-03-12
申请号：US09654183
申请日：2000-09-01
申请人： Michel A. Daage , Russell John Koveal , Albert L'Vovich Lapidus , Alla Jurievna Krylova , Shawn Paul Brennan
发明人： Michel A. Daage , Russell John Koveal , Albert L'Vovich Lapidus , Alla Jurievna Krylova , Shawn Paul Brennan
IPC分类号： B01J3100
摘要： A process of enhancing both the activity and the methane selectivity of a Dispersed Active Metal (“DAM”) hydrogenation catalyst is disclosed wherein the DAM undergoes low temperature oxidation in a slurry phase to form an oxidized catalyst precursor that is unique in comparison to those formed by conventional high temperature deactivation processes. The oxidized catalyst precursor, which is stable, is subsequently reduced to form an enhanced catalyst by treatment with hydrogen-containing gas at elevated temperature. The process is useful in a wide variety of DAMs formed by art-recognized techniques. The process is equally applicable to the enhanced catalysts formed from the oxidized precursors and their use in hydrogenation reactions.
摘要翻译： 公开了一种提高分散活性金属（“DAM”）氢化催化剂的活性和甲烷选择性的方法，其中DAM在淤浆相中经历低温氧化以形成氧化催化剂前体，与所形成的催化剂前体相比是独特的 通过常规的高温失活过程。 随后通过在高温下用含氢气体处理，将氧化的催化剂前体还原，以形成增强的催化剂。 该方法在由艺术公认技术形成的各种DAM中是有用的。 该方法同样适用于由氧化前体形成的增强催化剂及其在氢化反应中的应用。
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公开(公告)号：US06486221B2
公开(公告)日：2002-11-26
申请号：US09865796
申请日：2001-05-25
IPC分类号： C07C2700
CPC分类号： C10G2/331 , B01J23/75 , B01J37/18 , C07C1/0445 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/46 , C07C2523/75 , C07C2523/89
摘要： A hydrocarbon synthesis catalyst is formed by contacting the catalyst precursor with a reducing gas comprising a mixture of hydrogen reducing gas and ammonia, at elevated temperature and pressure effective for conventional hydrocarbon synthesis catalyst formation by reduction in hydrogen.
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5.发明授权公开(公告)号：US06300268B1
公开(公告)日：2001-10-09
申请号：US09393517
申请日：1999-09-10
申请人： Albert L'Vovich Lapidus , Michel A. Daage , Russell J. Koveal , Alla Jurievna Krylova , Anatoliy B. Erofeev
发明人： Albert L'Vovich Lapidus , Michel A. Daage , Russell J. Koveal , Alla Jurievna Krylova , Anatoliy B. Erofeev
IPC分类号： B01J3810
摘要： A process for the desulfurization, and reactivation of a sulfur deactivated catalyst constituted of cobalt composited with a titania support. The sulfur deactivated cobalt titania catalyst is first contacted with a gaseous stream of molecular oxygen at temperature sufficiently high to oxidize the sulfur component of the catalyst. The sulfur oxidized catalyst is next contacted with a liquid, preferably water, to remove the oxide, or oxides of the sulfur. The catalyst is then contacted with a reducing agent, suitably hydrogen, to restore the activity of the catalyst. During the treatment there is no substantial loss, if any, of cobalt from the catalyst.
摘要翻译： 用于与二氧化钛载体合成的钴构成的硫失活催化剂的脱硫和再活化的方法。 硫失活的二氧化钛催化剂首先在足够高的温度下与分子氧的气流接触以氧化催化剂的硫组分。 硫氧化催化剂接着与液体，优选水接触，以除去氧化物或硫的氧化物。 然后将催化剂与还原剂（合适的是氢）接触，以恢复催化剂的活性。 在处理过程中，催化剂没有钴的显着损失（如果有的话）。
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公开(公告)号：US06337353B1
公开(公告)日：2002-01-08
申请号：US09477531
申请日：2000-01-04
IPC分类号： C07C2700
CPC分类号： C10G2/331 , B01J23/75 , B01J37/18 , C07C1/0445 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/46 , C07C2523/75 , C07C2523/89
摘要： A hydrocarbon synthesis catalyst is formed by contacting the catalyst precursor with a reducing gas comprising a mixture of hydrogen reducing gas and ammonia, at elevated temperature and pressure effective for conventional hydrocarbon synthesis catalyst formation by reduction in hydrogen.
摘要翻译： 通过使催化剂前体与包含氢还原气体和氨的混合物的还原气体在升高的温度和压力下接触来形成烃合成催化剂，其通过氢还原生成常规烃合成催化剂。
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公开(公告)号：US06716886B2
公开(公告)日：2004-04-06
申请号：US10285985
申请日：2002-11-01
申请人： Alla Jurievna Krylova , Albert L'Vovich Lapidus , Lilia Vadimovna Sineva , Michel A. Daage , Russell John Koveal
发明人： Alla Jurievna Krylova , Albert L'Vovich Lapidus , Lilia Vadimovna Sineva , Michel A. Daage , Russell John Koveal
IPC分类号： C07C2700
摘要： A process of enhancing both the activity and the methane selectivity of a Dispersed Active Metal (“DAM”) hydrogenation catalyst is disclosed wherein the DAM undergoes low temperature oxidation in a slurry phase to form a stable, unique oxidized catalyst precursor that is subsequently reduced to form an enhanced catalyst by treatment with hydrogen-containing gas at elevated temperature, wherein reducible promoter metals comprising one or more of rhenium, ruthenium, palladium, iron and cobalt are added to the DAM. The promoter metals are mixed with the oxidized catalyst precursor as a solution of their reducible salts. The oxidized catalyst precursors are again recovered from the mixture and treated with hydrogen-containing gas to simultaneously form the metals and reactivate the DAM catalyst.
摘要翻译： 公开了一种提高分散活性金属（“DAM”）氢化催化剂的活性和甲烷选择性的方法，其中DAM在浆料相中经历低温氧化以形成稳定的独特的氧化催化剂前体，随后将其还原为 通过在升高的温度下用含氢气体处理形成增强的催化剂，其中将包含铼，钌，钯，铁和钴中的一种或多种的可还原助催化剂金属加入到DAM中。 助催化剂金属与其可还原盐的溶液与氧化的催化剂前体混合。 氧化的催化剂前体再次从混合物中回收并用含氢气体处理以同时形成金属并重新活化DAM催化剂。
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公开(公告)号：US06706661B1
公开(公告)日：2004-03-16
申请号：US09653719
申请日：2000-09-01
申请人： Alla Jurievna Krylova , Albert L'Vovich Lapidus , Lilia Vadimovna Sineva , Michel A. Daage , Russell John Koveal
发明人： Alla Jurievna Krylova , Albert L'Vovich Lapidus , Lilia Vadimovna Sineva , Michel A. Daage , Russell John Koveal
IPC分类号： B01J2340
摘要： A process of enhancing both the activity and the methane selectivity of a Dispersed Active Metal (“DAM”) hydrogenation catalyst is disclosed wherein the DAM undergoes low temperature oxidation in a slurry phase to form a stable, unique oxidized catalyst precursor that is subsequently reduced to form an enhanced catalyst by treatment with hydrogen-containing gas at elevated temperature, wherein reducible promoter metals comprising one or more of rhenium, ruthenium, palladium, iron and cobalt are added to the DAM. The promoter metals are mixed with the oxidized catalyst precursor as a solution of their reducible salts. The oxidized catalyst precursors are again recovered from the mixture and treated with hydrogen-containing gas to simultaneously form the metals and reactivate the DAM catalyst.
摘要翻译： 公开了一种提高分散活性金属（“DAM”）氢化催化剂的活性和甲烷选择性的方法，其中DAM在浆料相中经历低温氧化以形成稳定的独特的氧化催化剂前体，随后将其还原为 通过在升高的温度下用含氢气体处理形成增强的催化剂，其中将包含铼，钌，钯，铁和钴中的一种或多种的可还原助催化剂金属加入到DAM中。 助催化剂金属与其可还原盐的溶液与氧化的催化剂前体混合。 氧化的催化剂前体再次从混合物中回收并用含氢气体处理以同时形成金属并重新活化DAM催化剂。
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公开(公告)号：US06531518B1
公开(公告)日：2003-03-11
申请号：US09653915
申请日：2000-09-01
申请人： Albert L'Vovich Lapidus , Alla Jurievna Krylova , Lilia Vadimovna Sineva , Russell John Koveal , Michel A. Daage
发明人： Albert L'Vovich Lapidus , Alla Jurievna Krylova , Lilia Vadimovna Sineva , Russell John Koveal , Michel A. Daage
IPC分类号： C07C2700
摘要： A process of enhancing both the activity and the methane selectivity of a particulate Dispersed Active Metal (“DAM”) hydrogenation catalyst is disclosed wherein the DAM undergoes low temperature oxidation in a slurry phase to form a stable, unique oxidized catalyst precursor that is subsequently reduced to form an enhanced catalyst by treatment with hydrogen-containing gas at elevated temperature, wherein one or more promoter metal oxides of chromium, lanthanum and manganese are added to the DAM. Precursors of the promoter metal oxides may be combined with the DAMs prior to or during formation of the initial slurry, during the oxidation step or between recovery of the oxidized catalyst precursor and treatment of it with hydrogen-containing gas to reactivate the catalyst. Conversion of the precursors to the promoter metal oxides is carried out prior to the treatment with hydrogen-containing gas unless said treatment itself produces the conversion.
摘要翻译： 公开了一种提高颗粒分散活性金属（“DAM”）氢化催化剂的活性和甲烷选择性的方法，其中DAM在浆料相中经历低温氧化以形成稳定的独特的氧化催化剂前体，随后还原 通过在高温下用含氢气体处理形成增强的催化剂，其中将一种或多种铬，镧和锰的助催化剂金属氧化物加入到DAM中。 助催化剂金属氧化物的前体可以在氧化步骤期间或在氧化的催化剂前体的回收之前或期间在初始浆料形成之前或期间与含氢气体进行处理以重新催化催化剂，与DAM组合。 在用含氢气体处理之前，将前体转化为助催化剂金属氧化物，除非所述处理本身产生转化。
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10.发明授权PROCESS FOR THE REACTIVATION OF SULFUR DEACTIVATED COBALT TITANIA CATALYSTS; THE CATALYST COMPOSITIONS, USE OF THE REACTIVATED CATALYSTS FOR CONDUCTING CARBON MONOXIDE HYDROGENATION, REACTIONS AND THE PRODUCTS OF SUCH REACTIONS 有权硫化还原铁氰化钛催化剂反应的方法; 催化剂组合物，反应催化剂用于引发一氧化碳氢化反应，反应和这种反应的产物公开(公告)号：US06455596B2
公开(公告)日：2002-09-24
申请号：US09757219
申请日：2001-01-09
申请人： Albert L'Vovich Lapidus , Michel A. Daage , Russell J. Koveal , Alla Jurievna Krylova , Anatoliy B. Erofeev
发明人： Albert L'Vovich Lapidus , Michel A. Daage , Russell J. Koveal , Alla Jurievna Krylova , Anatoliy B. Erofeev
IPC分类号： C07C2700
摘要： A process for the desulfurization, and reactivation of a sulfur deactivated catalyst constituted of cobalt composited with a titania support. The sulfur deactivated cobalt titania catalyst is first contacted with a gaseous stream of molecular oxygen at temperature sufficiently high to oxidize the sulfur component of the catalyst. The sulfur oxidized catalyst is next contacted with a liquid, preferably water, to remove the oxide, or oxides of the sulfur. The catalyst is then contacted with a reducing agent, suitably hydrogen, to restore the activity of the catalyst. During the treatment there is no substantial loss, if any, of cobalt from the catalyst.
摘要翻译： 用于与二氧化钛载体合成的钴构成的硫失活催化剂的脱硫和再活化的方法。 硫失活的二氧化钛催化剂首先在足够高的温度下与分子氧的气流接触以氧化催化剂的硫组分。 硫氧化催化剂接着与液体，优选水接触，以除去氧化物或硫的氧化物。 然后将催化剂与还原剂（合适的是氢）接触，以恢复催化剂的活性。 在处理过程中，催化剂没有钴的显着损失（如果有的话）。
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