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1.发明申请Polymer Composition, Plastic Optical Fiber, Plastic Optical Fiber Cable, and Method for Manufacturing Plastic Optical Fiber 有权聚合物组合物，塑料光纤，塑料光缆，以及塑料光纤制造方法公开(公告)号：US20080166091A1
公开(公告)日：2008-07-10
申请号：US11794313
申请日：2005-12-27
CPC分类号： C08F224/00 , G02B6/02033
摘要： There is provided a polymer composition comprising 5 to 100% by mass of a unit (A) of a lactone compound represented by a general formula (1) and 0 to 95% by mass of a unit (B) of (meth)acrylate as constitutional units, wherein the unit (A) of a lactone compound comprises a unit of an (S) isomer represented by a general formula (2) and a unit of an (R) isomer represented by a general formula (3) at a mass ratio of from 70/30 to 30/70; and wherein the polymer composition has a total light scattering loss of not more than 100 dB/km. The polymer composition is excellent in heat resistance and transparency.
摘要翻译： 提供一种聚合物组合物，其含有5〜100质量％的由通式（1）表示的内酯化合物的单元（A）和0〜95质量％的（甲基）丙烯酸酯单元（B） 结构单元，其中内酯化合物的单元（A）包含由通式（2）表示的（S）异构体的单元和由通式（3）表示的（R）异构体的单元，以质量计 比例为70/30至30/70; 并且其中所述聚合物组合物具有不大于100dB / km的总光散射损失。 聚合物组合物的耐热性和透明性优异。
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2.发明授权Polymer composition, plastic optical fiber, plastic optical fiber cable, and method for manufacturing plastic optical fiber 有权聚合物组合物，塑料光纤，塑料光缆，以及塑料光纤制造方法公开(公告)号：US07512309B2
公开(公告)日：2009-03-31
申请号：US11794313
申请日：2005-12-27
IPC分类号： G02B6/00
CPC分类号： C08F224/00 , G02B6/02033
摘要： There is provided a polymer composition comprising 5 to 100% by mass of a unit (A) of a lactone compound represented by a general formula (1) and 0 to 95% by mass of a unit (B) of (meth)acrylate as constitutional units, wherein the unit (A) of a lactone compound comprises a unit of an (S) isomer represented by a general formula (2) and a unit of an (R) isomer represented by a general formula (3) at a mass ratio of from 70/30 to 30/70; and wherein the polymer composition has a total light scattering loss of not more than 100 dB/km. The polymer composition is excellent in heat resistance and transparency.
摘要翻译： 提供一种聚合物组合物，其含有5〜100质量％的由通式（1）表示的内酯化合物的单元（A）和0〜95质量％的（甲基）丙烯酸酯单元（B） 结构单元，其中内酯化合物的单元（A）包含由通式（2）表示的（S）异构体的单元和由通式（3）表示的（R）异构体的单元，以质量计 比例为70/30至30/70; 并且其中所述聚合物组合物具有不大于100dB / km的总光散射损失。 聚合物组合物的耐热性和透明性优异。
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公开(公告)号：US07609930B2
公开(公告)日：2009-10-27
申请号：US11919983
申请日：2006-05-09
IPC分类号： G02B6/02
CPC分类号： G02B6/02033 , G02B1/048
摘要： The invention provides a plastic optical fiber cable comprising a plastic optical fiber having a core/clad structure, a light blocking coating layer provided around the plastic optical fiber, and a protective coating layer provided between the outermost layer of the core/clad structure and the light blocking coating layer. The outermost layer of the core/clad structure is made of a fluorine-containing olefin polymer containing at least a tetrafluoroethylene unit, the crystal melting heat of the fluorine-containing olefin polymer being 59 mJ/mg or lower. The light blocking coating layer is made of a resin primarily containing a polyamide resin, the content of polyamide resin-derived monomers and oligomers being 1.5% by weight or lower.
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公开(公告)号：US20090067794A1
公开(公告)日：2009-03-12
申请号：US11919983
申请日：2006-05-09
IPC分类号： G02B6/036
CPC分类号： G02B6/02033 , G02B1/048
摘要： The invention provides a plastic optical fiber cable comprising a plastic optical fiber having a core/clad structure, a light blocking coating layer provided around the plastic optical fiber, and a protective coating layer provided between the outermost layer of the core/clad structure and the light blocking coating layer. The outermost layer of the core/clad structure is made of a fluorine-containing olefin polymer containing at least a tetrafluoroethylene unit, the crystal melting heat of the fluorine-containing olefin polymer being 59 mJ/mg or lower. The light blocking coating layer is made of a resin primarily containing a polyamide resin, the content of polyamide resin-derived monomers and oligomers being 1.5% by weight or lower.
摘要翻译： 本发明提供一种塑料光缆，其包括具有芯/包层结构的塑料光纤，设置在塑料光纤周围的遮光涂层，以及设置在芯/包层结构的最外层与保护涂层之间的保护涂层 遮光涂层。 芯/包层结构的最外层由含有至少四氟乙烯单元的含氟烯烃聚合物制成，含氟烯烃聚合物的结晶熔融热为59mJ / mg以下。 遮光涂层由主要包含聚酰胺树脂的树脂制成，聚酰胺树脂衍生的单体和低聚物的含量为1.5重量％以下。
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5.发明申请公开(公告)号：US20090279837A1
公开(公告)日：2009-11-12
申请号：US12311360
申请日：2007-09-28
IPC分类号： G02B6/44
CPC分类号： G02B1/045 , G02B6/02033
摘要： A plastic optical fiber cable includes: a bare optical fiber including a core made of a poly(methyl methacrylate) or a copolymer including methyl methacrylate as a major component and a cladding layer including, at least in the outermost layer, a layer made of a certain fluorine-containing olefin-based resin; and a coating layer provided on the outer surface thereof. The coating layer includes a protective coating layer, a light blocking coating layer, and a functional coating layer, the layers being provided in the order mentioned from inner side. The protective coating layer is made of a certain resin material. The light blocking coating layer is made of a nylon-based resin including, as a major component, nylon 11 or nylon 12, the nylon-based resin containing monomer and oligomer compounds derived from the nylon-based resin in an amount of a certain range. The functional coating layer is made of a nylon-based resin composition having a crystalline melting point within a certain range, the nylon-based resin composition containing a certain amount of melamine cyanurate or bromine atoms and further containing a certain amount of inorganic chromatic pigments, or the layer is made of a nylon-based resin composition having a crystalline melting point of within a certain range and an oxygen transmission rate within a certain range.
摘要翻译： 塑料光缆包括：包括由聚（甲基丙烯酸甲酯）制成的芯或包含甲基丙烯酸甲酯作为主要成分的共聚物的裸光纤，以及至少在最外层中包含由 某些含氟烯烃类树脂; 以及设置在其外表面上的涂层。 涂层包括保护涂层，遮光涂层和功能性涂层，这些层以从内侧提到的顺序提供。 保护涂层由某种树脂材料制成。 防光涂层由尼龙类树脂制成，尼龙系树脂包括尼龙11或尼龙12作为主要成分，尼龙系树脂含有单体和衍生自尼龙系树脂的低聚物化合物，其量为一定范围 。 功能性涂层由结晶熔点在一定范围内的尼龙系树脂组合物构成，尼龙系树脂组合物含有一定量的氰尿酸三聚氰胺或溴原子，并含有一定量的无机彩色颜料， 或者该层由结晶熔点在一定范围内且氧气透过率在一定范围内的尼龙类树脂组合物制成。
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6.发明授权公开(公告)号：US08023789B2
公开(公告)日：2011-09-20
申请号：US12311360
申请日：2007-09-28
CPC分类号： G02B1/045 , G02B6/02033
摘要： A plastic optical fiber cable includes: a bare optical fiber including a core made of a poly(methyl methacrylate) or a copolymer including methyl methacrylate as a major component and a cladding layer including, at least in the outermost layer, a layer made of a certain fluorine-containing olefin-based resin; and a coating layer provided on the outer surface thereof. The coating layer includes a protective coating layer, a light blocking coating layer, and a functional coating layer, the layers being provided in the order mentioned from inner side. The protective coating layer is made of a certain resin material. The light blocking coating layer is made of a nylon-based resin including, as a major component, nylon 11 or nylon 12, the nylon-based resin containing monomer and oligomer compounds derived from the nylon-based resin in an amount of a certain range. The functional coating layer is made of a nylon-based resin composition having a crystalline melting point within a certain range, the nylon-based resin composition containing a certain amount of melamine cyanurate or bromine atoms and further containing a certain amount of inorganic chromatic pigments, or the layer is made of a nylon-based resin composition having a crystalline melting point of within a certain range and an oxygen transmission rate within a certain range.
摘要翻译： 塑料光缆包括：包括由聚（甲基丙烯酸甲酯）制成的芯或包含甲基丙烯酸甲酯作为主要成分的共聚物的裸光纤，以及至少在最外层中包含由 某些含氟烯烃类树脂; 以及设置在其外表面上的涂层。 涂层包括保护涂层，遮光涂层和功能性涂层，这些层以从内侧提到的顺序提供。 保护涂层由特定的树脂材料制成。 防光涂层由尼龙类树脂制成，尼龙系树脂包括尼龙11或尼龙12作为主要成分，尼龙系树脂含有单体和衍生自尼龙系树脂的低聚物化合物，其量为一定范围 。 功能性涂层由结晶熔点在一定范围内的尼龙系树脂组合物构成，尼龙系树脂组合物含有一定量的氰尿酸三聚氰胺或溴原子，并含有一定量的无机彩色颜料， 或者该层由结晶熔点在一定范围内且氧气透过率在一定范围内的尼龙类树脂组合物制成。
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