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1.发明授权
公开(公告)号：US4330292A
公开(公告)日：1982-05-18
申请号：US215531
申请日：1980-12-11
摘要： The invention resides in the use of the compounds having the formula given below, or an acid salt thereof, as couplers in dyeing compositions for keratin fibres which contain an oxidation base: ##STR1## in which formula n is equal to 2, 3 or 4 and R.sub.1 and R.sub.2 are identical or different and represent an alkyl group having from 1 to 4 carbon atoms.
摘要翻译： 本发明在于使用下面给出的化合物或其酸式盐作为含有氧化基质的角蛋白纤维的染色组合物中的成色剂：其中式n等于2,3或4 并且R 1和R 2相同或不同，表示具有1至4个碳原子的烷基。
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2.发明授权Meta-phenylenediamines, dyeing compositions in which they are present and the corresponding dyeing process 失效亚苯基二胺，其中存在的染色组合物和相应的染色过程
公开(公告)号：US4333730A
公开(公告)日：1982-06-08
申请号：US142572
申请日：1980-04-18
IPC分类号： A61K8/00 , A61K8/22 , A61K8/23 , A61K8/25 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/365 , A61K8/37 , A61K8/39 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61K8/73 , A61Q5/10 , C07C67/00 , C07C213/00 , C07C217/84 , C07C233/12 , C07D209/48 , C09B53/00 , A61K7/13
CPC分类号： C07D209/48 , A61K8/411 , A61Q5/10
摘要： Novel meta-phenylenediamines are provided for use as couplers with dye bases in hair dye compositions. These meta-phenylenediamines have the formula: ##STR1## in which n is 2, 3 or 4. Their acid addition salts may also be used.
摘要翻译： 提供新的间苯二胺可用作染发剂组合物中染料基的成色剂。 这些间苯二胺具有以下分子式：其中n为2,3或4的
。它们的酸加成盐也可以使用。 -
公开(公告)号：US4010200A
公开(公告)日：1977-03-01
申请号：US529922
申请日：1974-12-05
申请人： Gregoire Kalopissis , Andree Bugaut
发明人： Gregoire Kalopissis , Andree Bugaut
摘要： N,N'-diaryl alkylene diamine oxidation dye compounds that are suitable for dyeing live human hair.
摘要翻译： N，N'-二芳基亚烷基二胺氧化染料化合物，适用于染色活人的头发。
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公开(公告)号：US3984402A
公开(公告)日：1976-10-05
申请号：US536292
申请日：1974-12-24
IPC分类号： A61K8/41 , A61Q5/10 , C09B53/02 , C07C119/14 , C07D265/36
CPC分类号： A61Q5/10 , A61K8/413 , C09B53/02 , Y10S424/01 , Y10S424/02
摘要： Indoaniline having the formula ##SPC1##Wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, lower alkyl or halogen with 1 - 2 of these substituents being other than hydrogen; R.sub.5, R.sub.6 and R.sub.7 each independently represent a member selected from the group consisting of hydrogen, lower alkyl and lower alkoxy; R.sub.8 and R.sub.9 each independently represent a member selected from the group consisting of hydrogen, lower alkyl and lower alkyl substituted with a member selected from the group consisting of amino, hydroxy, carbamoyl, piperidinyl and acylamino, R.sub.8 and R.sub.5 or R.sub.9 and R.sub.6 being able to form with the adjacent nitrogen atom a dihydro-oxazine or pyrroline heterocycle; Z represents a member selected from the group consisting of amino, acylamino and hydroxy, and the salts formed by these indoanilines with organic or inorganic acids, in particular, their acetates, oxalates, hydrochlorides, hydrobromides, persulfates, perchlorates and the double zinc salts of these compounds, which can, of course, be in a tautomeric form of that represented by the above formula. These indoanilines are usefully employed for dyeing keratinous fibers, and, in particular, human hair.
摘要翻译： 具有式WHEREIN R 1，R 2，R 3和R 4的吲哚苯胺各自独立地表示选自氢，低级烷基或卤素的这些取代基中的1-2个不同于氢的成员; R5，R6和R7各自独立地表示选自氢，低级烷基和低级烷氧基的成员; R8和R9各自独立地表示选自氢，低级烷基和被选自氨基，羟基，氨基甲酰基，哌啶基和酰基氨基的基团取代的低级烷基的基团，R 8和R 5或R 9和R 6可以 与相邻的氮原子形成二氢恶嗪或吡咯啉杂环; Z表示选自氨基，酰氨基和羟基的成员，以及由这些吲哚苯胺与有机酸或无机酸形成的盐，特别是其乙酸盐，草酸盐，盐酸盐，氢溴酸盐，过硫酸盐，高氯酸盐和双锌盐 这些化合物当然可以是由上式表示的互变异构体形式。 这些吲哚尼尔可有效地用于染色角质纤维，特别是人的头发。
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公开(公告)号：US3953508A
公开(公告)日：1976-04-27
申请号：US432982
申请日：1974-01-14
IPC分类号： A61K8/41 , A61Q5/10 , C07C103/34
摘要： Diphenylamines having the formula ##SPC1##Wherein: Y represents a member selected from the group consisting of a hydroxy and amino, R.sub.1 and R.sub.3, each independently, represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, a ureido residue, and -NHCOR wherein R is lower alkyl, R.sub.2 represents a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, a ureido residue, -NHCOR wherein R is lower alkyl, and --NHR.sub.8 wherein R.sub.8 represents a member selected from the group consisting of hydrogen, lower alkyl, lower hydroxyalkyl and carbamyl lower alkyl, with the proviso that when R.sub.2 is --NHR.sub.8, R.sub.3 is not hydrogen R.sub.4, R.sub.5, R.sub.6, and R.sub.7 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl and lower alkoxy, with the proviso that when Y is hydroxy, R.sub.2 is not hydrogen, halogen, lower alkyl or alkoxy and that when Y is amino, at least two of R.sub.1, R.sub.2 and R.sub.3 are other than a hydrogen and R.sub. 2 is not hydrogen when R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are all hydrogen and the acid addition salts of said diphenylamines.
摘要翻译： 具有式WHEREIN：Y的二苯胺表示选自羟基和氨基的成员，R 1和R 3各自独立地表示选自氢，卤素，低级烷基，低级烷氧基，脲基残基的成员 和-NHCOR，其中R是低级烷基，R 2表示选自氢，卤素，低级烷基，低级烷氧基，脲基残基，-NHCOR，其中R是低级烷基，-NHR 8，其中R8代表成员 选自氢，低级烷基，低级羟烷基和氨甲酰基低级烷基，条件是当R 2为-NHR 8时，R 3不为氢。R4，R5，R6和R7各自独立地表示选自 的氢，卤素，低级烷基和低级烷氧基，条件是当Y是羟基时，R 2不是氢，卤素，低级烷基或烷氧基，当Y是氨基时，R 1，R 2和R 3中的至少两个不同 氢和R 当R4，R5，R6和R7都是氢和所述二苯胺的酸加成盐时，2不是氢。
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6.发明授权N,N-Dialkylamino diphenylamines and the use thereof in compositions for dyeing keratinic fibers 失效N，N-二烷基氨基二苯胺及其在用于染色角蛋白纤维的组合物中的用途
公开(公告)号：US4288622A
公开(公告)日：1981-09-08
申请号：US741495
申请日：1976-11-12
IPC分类号： A61K8/41 , A61Q5/10 , C07C275/40 , C07C91/42 , D06P1/32
CPC分类号： A61K8/415 , A61K8/413 , A61Q5/10 , C07C275/40
摘要： Diphenylamine of the formula ##STR1## wherein R.sub.1 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, amino, lower alkyl amino wherein the alkyl moiety has 1-6 carbon atoms, acylamino, lower carbamylalkyl amino wherein the alkyl moiety has 1-6 carbon atoms, lower hydroxyalkyl amino wherein the alkyl moiety has 1-6 carbon atoms, lower carbalkoxy amino wherein the alkoxy moiety has 1-6 carbon atoms and ureido;R.sub.2 and R.sub.3 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, acylamino and ureido;R.sub.5 and R.sub.8 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl having 1-6 carbon atoms and lower alkoxy having 1-6 carbon atoms; andR.sub.6 and R.sub.7 are lower alkyl having 1-6 carbon atoms, with the proviso that (a) when both R.sub.6 and R.sub.7 represent methyl (1) one of R.sub.1 and R.sub.4 must represent a member selected from the group consisting of amino, lower alkyl amino wherein the alkyl moiety has 1-6 carbon atoms, lower carbamylalkyl amino wherein the alkyl moiety has 1-6 carbon atoms, lower hydroxyalkyl amino wherein the alkyl moiety has 1-6 carbon atoms and ureido, or (2) one of R.sub.1 and R.sub.4 represent acylamino and R.sub.2 and R.sub.3 are not both hydrogen, and (b) that when both R.sub.6 and R.sub.7 represent ethyl, R.sub.2 and R.sub.3 are other than tertiobutyl.The said diphenylamine is employed in a dye composition for dyeing keratinic fibers.
摘要翻译： 式IMA的二苯胺其中R 1和R 4各自独立地表示选自氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基，氨基，低级烷基氨基， 烷基部分具有1-6个碳原子，酰基氨基，低级氨基甲酰基烷基氨基，其中烷基部分具有1-6个碳原子，其中烷基部分具有1-6个碳原子的低级羟烷基氨基，低级烷氧基氨基，其中烷氧基部分具有1- 6个碳原子和脲基; R2和R3各自独立地表示选自氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基，酰氨基和脲基的成员; R5和R8各自独立地表示选自氢，卤素，具有1-6个碳原子的低级烷基和具有1-6个碳原子的低级烷氧基的成员; 并且R 6和R 7为具有1-6个碳原子的低级烷基，条件是（a）当R 6和R 7均表示甲基时，R 1和R 4中的一个必须表示选自氨基，低级烷基 氨基，其中烷基部分具有1-6个碳原子，其中烷基部分具有1-6个碳原子的低级氨基甲酰基烷基氨基，其中烷基部分具有1-6个碳原子的低级羟烷基氨基和脲基，或（2）R1和 R4代表酰基氨基，R2和R3不同时为氢，（b）当R6和R7都表示乙基时，R2和R3不是叔丁基。 所述二苯胺用于染色角蛋白纤维的染料组合物中。
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7.发明授权Indoanilines, process for producing the same and keratinic fiber dye composition containing the same 失效联苯胺，其生产方法和含有它们的角质纤维染料组合物
公开(公告)号：US4248591A
公开(公告)日：1981-02-03
申请号：US43892
申请日：1979-05-30
IPC分类号： A61K8/41 , A61Q5/10 , C07C275/26 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/413 , C07C275/26
摘要： Indoaniline of the formula ##STR1## wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy; R.sub.2 and R.sub.3 represent alkyl; R.sub.4, R.sub.5 and R.sub.6 each independently represent hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino and R.sub.5 can also represent amino, alkylmaino, hydroxy alkylamino or carbamylalkylamino, the alkyl and alkoxy groups above being able to contain 1 to 6 carbon atoms and the acyl group from 2 to 7 carbon atoms with the condition that R.sub.5 does not represent hydrogen, chlorine, methyl or methoxy and when R.sub.5 represents acetylamino, R.sub.6 does not represent hydrogen; it being understood that the above compounds can be present in the tautomeric form of that represented by formula (I). The indoaniline is usefully employed in dye copositions for keratinic fibers, especially living human hair.
摘要翻译： 式（I）的吲哚苯胺其中R1代表氢，卤素，烷基或烷氧基; R2和R3表示烷基; R 4，R 5和R 6各自独立地表示氢，卤素，烷基，烷氧基，酰氨基，脲基或烷氧基氨基，R5也可以表示氨基，烷基亚氨基，羟基烷基氨基或氨基甲酰基烷基氨基，上述烷基和烷氧基能够含有1至6个碳原子 和2〜7个碳原子的酰基，其中R5不代表氢，氯，甲基或甲氧基，当R5表示乙酰氨基时，R6不代表氢; 应当理解，上述化合物可以以由式（I）表示的互变异构体形式存在。 吲哚苯胺有效地用于角蛋白纤维，特别是活人的头发的染料组合物中。
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8.发明授权4,4'-Disubstituted diphenylamines and the use thereof in dye composition for keratinic fibers 失效4,4'-二取代二苯胺及其在角质纤维染料组合物中的应用
公开(公告)号：US4222958A
公开(公告)日：1980-09-16
申请号：US797807
申请日：1977-05-17
IPC分类号： A61K8/41 , A61Q5/10 , C07C275/40 , C07C127/19 , C07C91/40 , C07C103/127
CPC分类号： A61K8/415 , A61K8/413 , A61Q5/10 , C07C275/40 , Y10S424/01 , Y10S424/02
摘要： Diphenylamine of the formula ##STR1## wherein R.sub.1 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, amino, lower alkyl amino, acylamino, lower carbamylalkyl amino, lower hydroxyalkyl amino, lower carbalkoxy amino and ureido;R.sub.2 and R.sub.3 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, acylamino and ureido;R.sub.5 represents a member selected from the group consisting of hydrogen, halogen, lower alkyl and lower alkoxy;R.sub.6 represents a member selected from the group consisting of lower hydroxyalkyl, lower amino alkyl, lower acylamino alkyl, lower mesylamino alkyl, lower carbamylalkyl, lower sulfoalkyl, lower piperidinoalkyl, lower morpholinoalkyl, lower mono alkyl lower amino alkyl and lower dialkyl lower amino alkyl; andR.sub.7 represents a member selected from the group consisting of lower alkyl, lower hydroxyalkyl, lower aminoalkyl, lower acylamino alkyl, lower mesylamino alkyl, lower carbamyl alkyl, lower sulfoalkyl, lower piperidinoalkyl, lower morpholinoalkyl, lower monoalkyl lower amino alkyl and lower dialkyl lower amino alkyl, each of said alkyl and alkoxy moieties containing 1-6 carbon atoms and each of said acyl moieties representing R--CO-- wherein R is selected from the group consisting of an aliphatic and aromatic group.The said diphenylamine is usefully employed in a dye composition for dyeing keratinic fibers.
摘要翻译： 其中R 1和R 4各自独立地表示选自氢，卤素，低级烷基，低级烷氧基，氨基，低级烷基氨基，酰氨基，低级氨基甲酰基烷基氨基，低级羟烷基氨基，低级烷氧基 氨基和脲基; R2和R3各自独立地表示选自氢，卤素，低级烷基，低级烷氧基，酰氨基和脲基的成员; R5表示选自氢，卤素，低级烷基和低级烷氧基的成员; R6代表选自低级羟烷基，低级氨基烷基，低级酰氨基烷基，下甲磺酰氨基烷基，低级氨基甲酰基烷基，低级磺基烷基，低级哌啶子基烷基，低级吗啉代烷基，低级单烷基低级氨基烷基和低级二烷基低级氨基烷基的成员。 并且R 7表示选自低级烷基，低级羟烷基，低级氨基烷基，低级酰氨基烷基，下甲磺酰氨基烷基，低级氨基甲酰基烷基，低级磺基烷基，低级哌啶子基烷基，低级吗啉代烷基，低级单烷基低级氨基烷基和低级二烷基低级 氨基烷基，所述烷基和烷氧基部分各自含有1-6个碳原子，并且每个所述酰基部分代表R-CO-，其中R选自脂族和芳族基团。 所述二苯胺可用于染色角质纤维的染料组合物中。
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公开(公告)号：US4200432A
公开(公告)日：1980-04-29
申请号：US853813
申请日：1977-11-21
摘要： A hair dye composition comprising at least one oxidation dye and at least one diphenylamine of the formula ##STR1## wherein R.sub.1 and R.sub.4 each independently represent hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, acylamino or ureido;R.sub.2 and R.sub.3 each independently represent hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, amino, N-alkylamino wherein the alkyl has 1-6 carbon atoms, N-hydroxyalkylamino wherein the alkyl has 1-6 carbon atoms, acylamino, N-carbamylalkylamino wherein the alkyl has 1-6 carbon atoms or ureido;R.sub.5 represents hydrogen, halogen, lower alkyl having 1-6 carbon atoms or lower alkoxy having 1-6 carbon atoms;R.sub.6, R.sub.7 and R.sub.8, each independently represent hydrogen, halogen, lower alkyl having 1-6 carbon atoms or lower alkoxy having 1-6 carbon atoms;Y represents hydroxy or amino; andZ represents hydroxy or ##STR2## wherein R.sub.9 and R.sub.10 each independently represents hydrogen, lower alkyl containing 1-6 carbon atoms, hydroxyalkyl containing 1-6 carbon atoms, carbamyl alkyl wherein the alkyl has 1-6 carbon atoms, amino alkyl wherein the alkyl has 1-6 carbon atoms, monoalkylamino alkyl wherein each alkyl has 1-6 carbon atoms, dialkylamino alkyl wherein each alkyl has 1-6 carbon atoms, acylaminoalkyl wherein the alkyl has 1-6 carbon atoms, alkylsulfonamido alkyl wherein each alkyl has 1-6 carbon atoms, arylsulfonamidoalkyl wherein the alkyl has 1-6 carbon atoms, sulfoalkyl wherein the alkyl has 1-6 carbon atoms, piperidinoalkyl wherein the alkyl has 1-6 carbon atoms or morpholinoalkyl wherein the alkyl has 1-6 carbon atoms; ora salt thereof.
摘要翻译： 一种染发剂组合物，其包含至少一种氧化染料和至少一种下式的二苯胺：其中R 1和R 4各自独立地表示氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基， 酰氨基或脲基; R2和R3各自独立地表示氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基，氨基，其中烷基具有1-6个碳原子的N-烷基氨基，其中烷基具有 1-6个碳原子，酰氨基，N-氨基甲酰基烷基氨基，其中烷基具有1-6个碳原子或脲基; R5表示氢，卤素，具有1-6个碳原子的低级烷基或具有1-6个碳原子的低级烷氧基; R6，R7和R8各自独立地表示氢，卤素，具有1-6个碳原子的低级烷基或具有1-6个碳原子的低级烷氧基; Y表示羟基或氨基; 并且Z表示羟基或者其中R9和R10各自独立地表示氢，含有1-6个碳原子的低级烷基，含有1-6个碳原子的羟基烷基，其中烷基具有1-6个碳原子的氨基甲酰基烷基，其中 烷基具有1-6个碳原子，其中每个烷基具有1-6个碳原子的一烷基氨基烷基，其中每个烷基具有1-6个碳原子的二烷基氨基烷基，其中烷基具有1-6个碳原子的酰氨基烷基，烷基亚磺酰氨基烷基，其中每个烷基具有1个 -6个碳原子，其中烷基具有1-6个碳原子的芳基亚磺酰氨基烷基，其中烷基具有1-6个碳原子的磺基烷基，其中烷基具有1-6个碳原子的哌啶子基烷基或其中烷基具有1-6个碳原子的吗啉代烷基; 或其盐。
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公开(公告)号：US4042627A
公开(公告)日：1977-08-16
申请号：US618244
申请日：1975-09-30
IPC分类号： A61K8/41 , A61Q5/10 , C07C275/40 , C09B53/02 , C07C91/42
CPC分类号： A61Q5/10 , A61K8/413 , C07C275/40 , C09B53/02
摘要： Diphenylamines of the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently represent hydrogen, halogen or lower alkyl containing 1-4 carbon atoms with at least one of R.sub.1 and R.sub.2 being other than hydrogen; R.sub.3, R.sub.4, R.sub.5, R.sub.6, and R.sub.7 each independently represent hydrogen or lower alkyl optionally substituted with hydroxy, carbamyl, piperidinyl or acylamino; R.sub.3 and R.sub.6 or R.sub.4 and R.sub.7 also optionally forming together with the carbon and nitrogen atoms to which they are attached, a dihydrooxazine or pyrroline heterocycle; and Z represents amino, acylamino or hydroxy; and the acid salts of said diphenylamines. These diphenylamines are usefully employed in cosmetic compositions for the hair including hair dye compositions and hair setting lotion compositions.
摘要翻译： 其中R 1和R 2各自独立地表示氢，卤素或含有1-4个碳原子的低级烷基，其中R 1和R 2中的至少一个不是氢; R3，R4，R5，R6和R7各自独立地表示氢或任选被羟基，氨基甲酰基，哌啶基或酰基氨基取代的低级烷基; R 3和R 6或R 4和R 7还任选地与它们所连接的碳原子和氮原子一起形成，二氢恶嗪或吡咯啉杂环; Z表示氨基，酰氨基或羟基; 和所述二苯胺的酸式盐。 这些二苯胺可用于头发的化妆品组合物中，包括染发组合物和头发定型洗剂组合物。
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