公开(公告)号：US06593437B1

公开(公告)日：2003-07-15

申请号：US09959382

申请日：2001-10-24

申请人： Andrei Gonioukh ,  Wolfgang Micklitz ,  Benno Bildstein ,  Michael Malaun ,  Andreas Hradsky

发明人： Andrei Gonioukh ,  Wolfgang Micklitz ,  Benno Bildstein ,  Michael Malaun ,  Andreas Hradsky

IPC分类号： C08F470

CPC分类号： C08G67/02 ,  C07C249/02 ,  C07C2603/20 ,  C07F17/02 ,  C08F4/00 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/61925 ,  C08F10/00 ,  C08F110/02 ,  C08F2410/03 ,  C08F2500/17 ,  C07C251/08 ,  C07C251/20 ,  C07C251/24 ,  C08F4/7006

摘要： A process for preparing 1,2-diimine compounds of the formula I where R1 and R2 are, independently of one another, alkyl, aryl or metallocenyl radicals, and R3, R4 are, independently of one another, H, alkyl or aryl radicals or R3 and R4 are joined so as to form, with inclusion of the two imine carbon atoms, a 5- to 8-membered ring which may be saturated or unsaturated and may be unsubstituted or substituted by any hydrocarbon radicals. The process involves reacting 1,2-dicarbonyl compounds with primary amines, which have been activated with trialkylaluminum compounds prior to the reaction with the 1,2-dicarbonyl compounds. 1,2-Diimine compounds of the formula I in which R1 and R2 are, independently of one another, metallocenyl radicals can be used to prepare metal complexes which can be used as catalysts in a process for the polymerization of unsaturated compounds.

摘要翻译： 制备式I的1,2-二亚胺化合物的方法，其中R 1和R 2彼此独立地为烷基，芳基或金属茂基，且R 3，R 4彼此独立地为H，烷基或芳基或R 3 并且R4连接以形成包含两个亚胺碳原子的5-8元环，其可以是饱和或不饱和的，并且可以是未取代的或被任何烃基取代。 该方法包括使1,2-二羰基化合物与伯胺反应，伯胺在与1,2-二羰基化合物反应之前已用三烷基铝化合物活化。 其中R 1和R 2彼此独立地为金属茂基的式I的1,2-二亚胺化合物可用于制备可在不饱和化合物的聚合方法中用作催化剂的金属络合物。