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公开(公告)号：US3984486A
公开(公告)日：1976-10-05
申请号：US588930
申请日：1975-06-20
IPC分类号： C07C29/16
摘要： It has been discovered that heating C.sub.4 -C.sub.17 internal olefins to 300.degree.F to 500.degree.F for about 15 to 30 minutes in the presence of an oxo catalyst prior to hydroformylation results in a higher selectivity to primary alcohols than does the conventional hydroformylation procedure of heating all the reactants together.
摘要翻译： 已经发现，在加氢甲酰化之前，在羰基催化剂存在下，将C4-C17内烯烃加热至约300至500°F约15至30分钟，导致对伯醇的选择性高于常规加氢甲酰化程序 将所有反应物加热在一起。
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公开(公告)号：US4089689A
公开(公告)日：1978-05-16
申请号：US592954
申请日：1975-07-03
IPC分类号： C10M159/12 , C07C51/41 , C07G99/00 , C09D5/08 , C09D131/00 , C10G27/00 , C10L1/18 , C10L1/188 , C10L1/19 , C10L10/08 , C10M169/00 , C10N10/04 , C10N20/00 , C10N20/02 , C10N30/12 , C10N60/04 , C23F11/12
CPC分类号： C07C51/412 , C10M1/08 , C10M2203/00 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108 , C10M2207/125 , C10M2207/129 , C10N2210/02 , C10N2230/12 , C10N2260/04
摘要： A petroleum oxidate of gel resistant properties characterized by a Neut. No. between about 40 and 50, a Sap. No. between about 85 and 105, a specific gravity between about 0.99 and 1.03, a viscosity (SUS at 210.degree. F.) of between about 1200 and 2500 and a melting point of between about 85.degree. and 115.degree. F.; a calcium soap thereof having a calcium content of between about 1.2 and 1.9 wt. % and a melting point between about 155.degree. and 230.degree. F. of gel resistant properties under cutback conditions; said oxidate, calcium soap and cutback thereof respectively prepared by contacting a deasphalted naphthene base residual oil having a molecular weight of between about 300 and 900, a saturate content between about 40 and 60 wt. %, an aromatic content between about 60 and 40 wt. %, a methylene to methyl group mole ratio of between about 1:1 and 2.5:1, and an SUS viscosity (210.degree. F.) of between about 150 and 170, with air at an air rate of between about 5 and 40 SCFH/lb. residual oil charge in the presence of between about 0.2 and 2 lbs. metaliferous oxidation catalyst per pound charge oil under a pressure of between about 0 and 500 atmospheres at a temperature between about 250.degree. and 400.degree. F. for a period of normally between about 1 and 5 hours to form said petroleum oxidate which is then further reacted with calcium hydroxide in a hydroxide amount of between about 100 and 125 wt. % of stoichiometric at a temperature of between about 275.degree. and 357.degree. F. and cutting back the formed calcium soap with inert petroleum hydrocarbon solvent to form a cutback calcium oxidate soap composition containing between 0.1 and 90 wt. % of said oxidate soap of corrosion inhibiting and anti gel properties.
摘要翻译： 以Neut为特征的耐凝胶性能的石油氧化物。 约40到50之间，一个Sap。 约85至105之间，比重在约0.99和1.03之间，粘度（在210°F下的SUS）在约1200和2500之间，熔点在约85°至115°F之间; 其钙皂含量在约1.2和1.9重量％之间。 ％，熔点在155〜230°F之间。 所述氧化物，钙皂和其分别通过使分子量为约300至900的脱沥青的环烷基残余油接触而制备，饱和物含量为约40至60重量％。 ％，芳族含量为约60至40wt。 ％，亚甲基与甲基摩尔比在约1:1至2.5:1之间，SUS粘度（210°F）为约150至170，空气的空气速率为约5至40SCFH /磅。 在约0.2和2磅之间的存在下的残余油装料。 在约0-500大气压的压力下，在约250-400°F的温度下，每磅充电油的金属氧化催化剂通常在约1-5小时之间以形成所述石油氧化物，然后进一步反应 氢氧化钙的氢氧化物量为约100至125重量％。 在约275°F至357°F的温度下化学计量的百分比，并用惰性石油烃溶剂切割形成的钙皂，以形成含有0.1-90wt。 ％的所述氧化皂具有腐蚀抑制和抗凝胶性能。
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公开(公告)号：US4060557A
公开(公告)日：1977-11-29
申请号：US588534
申请日：1975-06-19
CPC分类号： C07C45/50
摘要： Disclosed is a process for separating unreacted olefins, paraffins, aldehydes and alcohols from the catalyst and heavy ends from the hydroformylation process by using thin film distillation. In this process, the crude oxo product is metered into a thin film evaporator wherein the distillate containing olefins, paraffins, aldehydes and alcohols is rapidly separated by a continuous wiping action from the residue which contains the catalyst complex and the heavy ends. The various products are fractionated while the residue is directly recycled.
摘要翻译： 公开了通过使用薄膜蒸馏从催化剂和加氢甲酰化方法的重馏分分离未反应的烯烃，链烷烃，醛和醇的方法。 在该方法中，将粗产物计量加入到薄膜蒸发器中，其中含有烯烃，链烷烃，醛和醇的馏出物通过来自含有催化剂络合物和重馏分的残余物的连续擦拭作用快速分离。 将各种产品分馏，同时残留物直接再循环。
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公开(公告)号：US3950439A
公开(公告)日：1976-04-13
申请号：US488130
申请日：1974-07-12
IPC分类号： C07C29/16
CPC分类号： C07C29/16
摘要： A hydroformylation process for increasing the yield of straight chain unsubstituted primary alcohols from predominantly terminal olefins by contacting the olefins with carbon monoxide and hydrogen in the presence of a cobalt catalyst is characterized by the incorporation of aqueous base in a base to cobalt molar ratio of about 10:1 to 20:1 in the reaction mixture before or after heating the same to reaction temperature. The base introduced in the oxo reactor while hydroformylation is occurring continuously converts by-products acetals and esters to the corresponding primary alcohols, thereby considerably increasing the yield thereof.
摘要翻译： 通过在钴催化剂存在下使烯烃与一氧化碳和氢气接触来提高直链未取代的伯醇从主要为末端烯烃的产率的加氢甲酰化方法，其特征在于将碱水溶液与碱的摩尔比约为 10：1至20：1在反应混合物中或之后加热至反应温度。 在加氢甲酰化发生的同时引入羰基反应器中的碱连续地将副产物缩醛和酯转化成相应的伯醇，从而显着提高其产率。
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