METHODS AND APPARATUS FOR FORMING STABILIZATION LAYERS

    公开(公告)号:US20220037204A1

    公开(公告)日:2022-02-03

    申请号:US16983402

    申请日:2020-08-03

    Abstract: Methods and apparatus that forms a stabilization layer on copper-based material to inhibit formation of copper voids in the copper-based material. In some embodiments, a method of forming the stabilization layer on the copper-based material includes depositing a first stabilization layer on the copper-based material where the first stabilization layer forms a continuous film on the copper-based material and is formed of a first material that does not alloy with copper, depositing a second stabilization layer on the first stabilization layer where the second stabilization layer is formed from a second material that alloys with copper and where the first stabilization layer is configured to inhibit formation of voids in the copper-based material during subsequent high thermal budget processing.

    METHODS AND APPARATUS FOR INTERMIXING LAYER FOR ENHANCED METAL REFLOW

    公开(公告)号:US20220084882A1

    公开(公告)日:2022-03-17

    申请号:US17022058

    申请日:2020-09-15

    Abstract: Methods and apparatus for filling features on a substrate are provided herein. In some embodiments, a method of filling features on a substrate includes: depositing a first metallic material on the substrate and within a feature disposed in the substrate in a first process chamber via a chemical vapor deposition (CVD) process at a first temperature; depositing a second metallic material on the first metallic material in a second process chamber at a second temperature and at a first bias power to form a seed layer of the second metallic material; etching the seed layer in the second process chamber at a second bias power greater than the first bias power to form an intermix layer within the feature comprising the first metallic material and the second metallic material; and heating the substrate to a third temperature greater than the second temperature, causing a reflow of the second metallic material.

    SELECTIVE COBALT DEPOSITION ON COPPER SURFACES

    公开(公告)号:US20210062330A1

    公开(公告)日:2021-03-04

    申请号:US17002296

    申请日:2020-08-25

    Abstract: A method for capping a copper surface on a substrate. In embodiments, the methods include exposing a substrate including a copper surface and a dielectric surface to a cobalt precursor gas and a process gas including a reducing agent to selectively form a first cobalt capping layer over the copper surface while leaving exposed the dielectric surface during a vapor deposition process, wherein a flow rate ratio of process gas to cobalt precursor gas is at least 300:1.

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