摘要:
Coupling agents suitable to be synthetized by cyclo-oligomerization of 3-methylbutyn-1-ol-3 with subsequent dehydration of the alcohol compounds, and their use in a method for the termination of living polymers obtained by means of the anionic polymerization of diene and/or vinylaromatic monomers.
摘要:
There are disclosed oligomeric aluminum hydride iminic derivatives, to be employed as catalysts in polymerization processes and which are prepared by causing alkali-metal or alkaline-earth-metal alanates to react with a primary amine which contains a group of the type --X--R".sub.m, wherein X is a nitrogen atom or an oxygen atom and m is equal to the valence of X minus one. The compounds have a trimeric or a tetrameric "open cage" spatial configuration.
摘要:
There are disclosed oligomeric aluminum hydride iminic derivatives to be employed as catalysts in polymerization processes and, which are prepared by causing alkali-metal or alkaline-earth-metal alanates to react with a primary amine which contains a group of the type --X--R".sub.m, wherein X is a nitrogen atom or an oxygen atom and m is equal to the valence of X minus one. The compounds have a trimeric or a tetrameric "open cage" spatial configuration.
摘要:
An oligomer N-alkyl-iminoalane, made up of a plurality of four and/or six member rings of the formulae: ##STR1## wherein R is an aliphatic, cycloaliphatic or aromatic hydrocarbon combined in a tridimensional cage structure having the chemical composition (HAl-NR).sub.n, in which R has the above meaning and n is a whole number lower than or equal to 10, is prepared by reacting a primary amine containing a secondary or tertiary carbon atom in alpha or beta position with respect to the amine nitrogen atom or amide derivative thereof wherein the amine radical contains a secondary or tertiary carbon atom in alpha or beta position with respect to the nitrogen atom with a complex formed by AlH.sub.3 and a Lewis base, or by reacting said primary amine with an alkali or alkaline-earth metal alanate.
摘要:
This invention relates to particular polyolefin compositions which contain, as stabilizers against UV-light radiations, open-chain amine compounds which are hindered in the alpha-position by alkyl radicals, said amine compounds corresponding to the following general formula: ##STR1## wherein R', R", R"', R.sup.IV, R.sup.V and R.sup.VI which can be equal or different, are radicals of aliphatic hydrocarbons with a number of C-atoms variable from 1 to 20, or can be hydrogen atoms, n is an integer variable from 2 to 12, and n' is an integer comprised between 1 and 15.
摘要:
Novel organic aluminum imides, highly resistant to oxidation and moisture and useful for polymerization and alkylation reactions, are prepared by reacting a poly(N-alkyliminoalane) with an aluminum alkyl, or with a halogen acid and then with an alkyl derivative of an alkali metal.