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155 条记录 (耗时 0.022 秒)

    Hydrogenation of alkinols using a catalyst containing macropores
    1.
    发明授权
    Hydrogenation of alkinols using a catalyst containing macropores 失效
    使用含有大孔的催化剂氢化烷醇

    公开(公告)号：US6130360A

    公开(公告)日：2000-10-10

    申请号：US207622

    申请日：1998-12-09

    申请人： Arnd Bottcher ,  Melanie Brunner ,  Jochem Henkelmann ,  Heinz Rutter

    发明人： Arnd Bottcher ,  Melanie Brunner ,  Jochem Henkelmann ,  Heinz Rutter

    IPC分类号： C07C29/17 ,  C07C27/00

    CPC分类号： C07C29/172

    摘要： An alkinol or mixture of two or more thereof is hydrogenated by bringing the alkinol or the mixture of two or more thereof into contact with a hydrogen-containing gas in the presence of a catalyst comprising as active metal at least one metal of transition group VIII of the Periodic Table, either alone or together with at least one metal of transition group I or VII of the Periodic Table, applied to a support, wherein the support contains macropores.

    摘要翻译： 通过使烯醇或其两种或多种的混合物在含有活性金属的催化剂存在下与含氢气体接触来氢化烯醇或其混合物，所述催化剂包含至少一种第 单体或与周期表中的至少一种过渡组I或VII的金属一起施加到载体上，其中载体含有大孔。

    Method for producing 2-alkynoic acid esters
    2.
    发明授权
    Method for producing 2-alkynoic acid esters 失效
    2-炔酸酯的制备方法

    公开(公告)号：US6153786A

    公开(公告)日：2000-11-28

    申请号：US402893

    申请日：1999-10-13

    申请人： Jochem Henkelmann ,  Thomas Preiss ,  Arnd Bottcher ,  Rolf Gleiter ,  Christel de Backer

    发明人： Jochem Henkelmann ,  Thomas Preiss ,  Arnd Bottcher ,  Rolf Gleiter ,  Christel de Backer

    IPC分类号： C07C67/333 ,  C07B61/00 ,  C07C67/00 ,  C07C67/36 ,  C07C69/606 ,  C07C69/618 ,  C07C69/00

    CPC分类号： C07C67/00 ,  C07C67/36

    摘要： A process for preparing 2-alkynoic esters of the general formula (I),R.sup.1 --O--CO--C.tbd.C--R.sup.2 (I)in which R.sup.1 and R.sup.2 independently are C.sub.1-16 -alkyl, C.sub.6-12 -aryl, C.sub.7-12 -aralkyl or C.sub.7-12 -alkylaryl radicals, and R.sup.2 can also be hydrogen,by reacting a chloroformate of the general formula (II),R.sup.1 --O--CO--Cl (II)with an alkyne of the general formula (III),R.sup.2 --C.tbd.C--H (III)is carried out in the presence of a Pt and/or Pd complex which has phosphine ligands and/or phosphite ligands as catalyst.

    摘要翻译： PCT No.PCT / EP98 / 02021 Sec。 371 1999年10月13日第 102（e）1999年10月13日PCT 1998年4月7日提交PCT公布。 公开号WO98 / 46555 日期：1998年10月22日制备通式（I）的2-炔炔酯的方法，其中R 1和R 2独立地为C 1-6 - 烷基，C 6 -C 12 - 12芳基，C7-12芳烷基或C7-12烷基芳基，R2也可以是氢，通式（II）的氯甲酸酯，R1-O-CO-Cl（Ⅱ）与 在具有膦配体和/或亚磷酸酯配体作为催化剂的Pt和/或Pd络合物的存在下，通式（III），R2-C 3BOND CH（III）进行。

    Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores
    5.
    发明授权
    Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores 有权

    公开(公告)号：US06284917B1

    公开(公告)日：2001-09-04

    申请号：US09581843

    申请日：2000-06-19

    申请人： Melanie Brunner ,  Arnd Böttcher ,  Boris Breitscheidel ,  Klaus Halbritter ,  Jochem Henkelmann ,  Lucien Thil ,  Rolf Pinkos

    发明人： Melanie Brunner ,  Arnd Böttcher ,  Boris Breitscheidel ,  Klaus Halbritter ,  Jochem Henkelmann ,  Lucien Thil ,  Rolf Pinkos

    IPC分类号： C07C6974

    CPC分类号： C08K5/12 ,  C07C51/36 ,  C07C67/303 ,  C07C69/75 ,  C07C2601/14 ,  C07C61/09

    摘要： A process for hydrogenating a benzenepolycarboxylic acid or a derivative thereof or a mixture of two or more thereof by bringing the benzenepolycarboxylic acid or the derivative thereof or the mixture of two or more thereof into contact with a hydrogen-containing gas is carried out in the presence of a catalyst which comprises as active metal at least one metal of transition group VIII of the Periodic Table alone or together with at least one metal of transition group I or VII of the periodic table applied to a support which contains macropores with the proviso that if dimethyl terephthalate is hydrogenated, the hydrogenation using a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table applied to a support, where the support has a mean pore diameter of at least 50 nm and a BET surface area of at most 30 m2/g and the amount of the active metal is from 0.01 to 30% by weight, based on the total weight of the catalyst, and the ratio of the surface areas of the active metal and the catalyst support is less than 0.05, and/or a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a support, where from 10 to 50% of the pore volume of the support is formed by macropores having a pore diameter in the range from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support is formed by mesopores having a pore diameter in the range from 2 to 50 nm, where the sum of the pore volumes adds up to 100%, is excluded, and novel hydrogenation products, obtainable by hydrogenating benzenepolycarboxylic acid (derivatives) as well as their use as plasticizers in plastics.

    Method for producing butyrolactones
    7.
    发明授权
    Method for producing butyrolactones 失效
    丁内酯的制备方法

    公开(公告)号：US06346629B1

    公开(公告)日：2002-02-12

    申请号：US09700426

    申请日：2000-11-15

    申请人： Melanie Brunner ,  Ralf-Thomas Rahn ,  Udo Rheude ,  Jochem Henkelmann

    发明人： Melanie Brunner ,  Ralf-Thomas Rahn ,  Udo Rheude ,  Jochem Henkelmann

    IPC分类号： C07D30702

    CPC分类号： C07D315/00

    摘要： Process for producing butyrolactones of the general formula I where R1 and R2 are each hydrogen, alkyl, hydroxyalkyl, substituted or unsubstituted aryl or substituted or unsubstituted trialkylsilyl, by reacting alkynes of the general formula II where R1 and R2 are each as defined above, with carbon monoxide and water in the presence of a rhodium catalyst under pressures from 20 to 300 bar and hydrogenating the unhydrogenated 2(5H)-furanone intermediates comprises a) reacting the carbonylation reaction mixture with hydrogen at from 150 to 250° C. and from 100 to 300 bar, b) removing the precipitated catalyst and returning it into the carbonylation reaction, and c) subjecting the catalyst-free reaction mixture to a distillation to recover the butyrolactone.

    摘要翻译： 制备通式I的丁内酯的方法，其中R 1和R 2各自为氢，烷基，羟基烷基，取代或未取代的芳基或取代或未取代的三烷基甲硅烷基，其中通式II的炔烃其中R 1和R 2各自如上所定义，与一氧化碳 和铑催化剂存在下的水，在20-300巴的压力下氢化未氢化的2（5H） - 呋喃酮中间体包括：a）使羰基化反应混合物与氢在150-250℃和100-300巴条件下反应 ，b）除去沉淀的催化剂并将其返回到羰基化反应中，和c）使无催化剂反应混合物进行蒸馏以回收丁内酯。

    Preparation of sugar alcohols
    8.
    发明授权
    Preparation of sugar alcohols 失效
    制备糖醇

    公开(公告)号：US06177598B1

    公开(公告)日：2001-01-23

    申请号：US09283866

    申请日：1999-04-01

    申请人： Melanie Brunner ,  Boris Breitscheidel ,  Jochem Henkelmann ,  Arnd Böttcher

    发明人： Melanie Brunner ,  Boris Breitscheidel ,  Jochem Henkelmann ,  Arnd Böttcher

    IPC分类号： C07C29141

    CPC分类号： C07C29/132 ,  C07C31/26

    摘要： A process for the hydrogenation of a sugar or a mixture of two or more thereof comprises the following step: Bringing the sugar or the mixture of two or more thereof into contact with hydrogen in the presence of specific catalysts to give a sugar alcohol or a mixture of two or more thereof, wherein the catalyst comprises at least one metal of transition group VIII of the Periodic Table, either alone or together with at least one metal of transition group I or VII of the Periodic Table.

    摘要翻译： 糖或其两种或多种的混合物的氢化方法包括以下步骤：在特定催化剂存在下，使糖或其两种或多种的混合物与氢接触以得到糖醇或混合物 其中所述催化剂包含元素周期表中至少一种第Ⅷ族过渡金属，单独或与元素周期表中至少一种过渡族I或Ⅶ族金属一起。

    Method for preparing a catalyst and catalysts prepared accordingly
    9.
    发明授权
    Method for preparing a catalyst and catalysts prepared accordingly 失效
    制备相应的催化剂和催化剂的方法

    公开(公告)号：US06350714B1

    公开(公告)日：2002-02-26

    申请号：US09555603

    申请日：2000-05-31

    申请人： Arnd Böttcher ,  Jochem Henkelmann ,  Thomas Preiss ,  Melanie Brunner

    发明人： Arnd Böttcher ,  Jochem Henkelmann ,  Thomas Preiss ,  Melanie Brunner

    IPC分类号： B01J3100

    CPC分类号： B01J31/1616 ,  B01J31/2286 ,  B01J2231/346 ,  B01J2531/10 ,  B01J2531/16 ,  B01J2531/20 ,  C07C29/42 ,  C07C209/60 ,  C07C213/00 ,  C07C211/23 ,  C07C215/24 ,  C07C33/042 ,  C07C33/046

    摘要： The present invention relates to a process for preparing a catalyst by activating a catalytic composition which comprises a) at least one metal of group IB or IIB or a compound thereof, b) where appropriate a carrier which comprises treating the composition with an alkyne of the general formula I R1—C≡C—R2  (I) in which R1 is alkyl, cycloalkyl, aryl, hydroxyalkyl, haloalkyl, alkoxy or alkoxyalkyl, R2 is a hydrogen atom, alkyl, cycloalkyl or aryl, and a carbonyl compound of the general formula II in which R3 and R4 are, independently of one another, a hydrogen atom, alkyl, haloalkyl, cycloalkyl or aryl, to catalysts obtainable by this process, and to alkynylations and aminoalkylations employing these catalysts.

    摘要翻译： 本发明涉及通过活化催化组合物来制备催化剂的方法，所述催化组合物包含：a）至少一种IB或IIB族金属或其化合物，b）适当的载体包括用通式 其中R 1是烷基，环烷基，芳基，羟烷基，卤代烷基，烷氧基或烷氧基烷基，R 2是氢原子，烷基，环烷基或芳基，和通式IIin的羰基化合物，其中R 3和R 4彼此独立地是氢 原子，烷基，卤代烷基，环烷基或芳基，可通过该方法获得的催化剂，以及使用这些催化剂的炔基化和氨基烷基化。

    Method for producing alkyne diols
    10.
    发明授权
    Method for producing alkyne diols 失效
    炔二醇的制备方法

    公开(公告)号：US06297407B1

    公开(公告)日：2001-10-02

    申请号：US09744437

    申请日：2001-01-24

    申请人： Alois Kindler ,  Melanie Brunner ,  Christian Tragut ,  Jochem Henkelmann

    发明人： Alois Kindler ,  Melanie Brunner ,  Christian Tragut ,  Jochem Henkelmann

    IPC分类号： C07C3118

    CPC分类号： C07C29/42 ,  C07C33/042 ,  C07C33/044

    摘要： The invention relates to a method for producing alkyne diols by reacting ketones with acetylenic hydrocarbons in an organic solvent in the presence of a base which contains potassium alcoholates of primary and/or secondary alcohols. The alkyne diols are produced while forming adducts which precipitate out of the reaction mixture and which are comprised of alkyne monoalcohols and/or alkyne diols and a base. The stoichiometries of the reaction partners are selected such that gelatinous adducts are formed which comprise a spherical surface, whereby the reaction mixture remains agitable during the entire reaction.

    摘要翻译： 本发明涉及一种在含有伯醇和/或仲醇的醇钾的碱存在下，通过酮与炔烃在有机溶剂中反应制备炔烃的方法。 产生炔二醇，同时形成从反应混合物中沉淀的加合物，其由炔一醇和/或炔二醇和碱组成。 选择反应伴侣的化学计量，使得形成包含球形表面的凝胶状加合物，由此在整个反应期间反应混合物保持敏感。