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    Method of surface cross-linking highly neutralized superabsorbent polymer particles using bronsted acids
    1.
    发明申请
    Method of surface cross-linking highly neutralized superabsorbent polymer particles using bronsted acids 审中-公开
    使用青铜酸表面交联高度中和的超吸收性聚合物颗粒的方法

    公开(公告)号：US20070049689A1

    公开(公告)日：2007-03-01

    申请号：US11508373

    申请日：2006-08-23

    申请人： Axel Meyer ,  Andreas Flohr ,  Torsten Lindner

    发明人： Axel Meyer ,  Andreas Flohr ,  Torsten Lindner

    IPC分类号： C08G63/91

    CPC分类号： C08F8/00 ,  A61L15/60 ,  C08F8/14 ,  C08F2810/20 ,  C08J3/245 ,  C08J2300/14

    摘要： A method of surface cross-linking superabsorbent polymer particles having a relatively high degree of neutralization is provided. Brønsted acids are selectively applied onto the surface of the superabsorbent polymer particles to selectively facilitate a relatively high number of protonated carboxyl groups at the surface of the superabsorbent polymer particles while the relatively high degree of neutralization in the core of the superabsorbent polymer particles remains substantially unaffected.

    摘要翻译： 提供了具有较高中和度的表面交联超吸收性聚合物颗粒的方法。 布朗斯台德酸被选择性地施加到超吸收性聚合物颗粒的表面上，以选择性地促进超吸收性聚合物颗粒表面的相对高数量的质子化羧基，而超吸收性聚合物颗粒的芯中的相对较高程度的中和基本上不受影响 。

    Superabsorbent polymer particles comprising functionalizers and method of making them
    2.
    发明申请
    Superabsorbent polymer particles comprising functionalizers and method of making them 有权
    包含官能团的超吸收聚合物颗粒及其制备方法

    公开(公告)号：US20060030829A1

    公开(公告)日：2006-02-09

    申请号：US11198081

    申请日：2005-08-05

    申请人： Andreas Flohr ,  Torsten Lindner

    发明人： Andreas Flohr ,  Torsten Lindner

    IPC分类号： A61F13/15

    CPC分类号： C08F265/04 ,  C08L51/003 ,  Y10T428/249986 ,  C08L2666/02

    摘要： The present invention relates to superabsorbent polymer particles having functionalizers covalently bound to the surface of precursor superabsorbent polymer particles. The functionalizers of the present invention comprise a grafting unit with a radiation activatable group and a functional unit covalently bound to the grafting unit. The grafting unit is bound to an aliphatic C—H group comprised at the surface of the precursor superabsorbent polymer particle. The functional unit comprises chemical structures which are not present in the precursor superabsorbent polymer particle. These functional units add an additional function to the precursor suberabsorbent polymer particle or modifying an existing function of the precursor superabsorbent polymer particle. Moreover, the invention relates to a process for making these superabsorbent polymer particles.

    摘要翻译： 本发明涉及具有与前体超吸收性聚合物颗粒的表面共价结合的官能化物的超吸收性聚合物颗粒。 本发明的功能化剂包括具有可辐射活化基团和与接枝单元共价结合的官能单元的接枝单元。 接枝单元与包含在前体超吸收聚合物颗粒表面的脂族C-H基团结合。 功能单元包括不存在于前体超吸收聚合物颗粒中的化学结构。 这些功能单元向前体抗氧化剂聚合物颗粒添加附加功能或改变前体超吸收聚合物颗粒的现有功能。 此外，本发明涉及制备这些超吸收性聚合物颗粒的方法。

    Surface Cross-Linked Superabsorbent Polymer Particles and Methods of Making Them
    4.
    发明申请
    Surface Cross-Linked Superabsorbent Polymer Particles and Methods of Making Them 有权
    表面交联超吸收聚合物颗粒及其制备方法

    公开(公告)号：US20090299315A1

    公开(公告)日：2009-12-03

    申请号：US12537585

    申请日：2009-08-07

    申请人： Andreas Flohr ,  Torsten Lindner

    发明人： Andreas Flohr ,  Torsten Lindner

    IPC分类号： A61F13/53 ,  C08K7/00

    CPC分类号： A61F13/534 ,  A61F2013/530766 ,  A61L15/60 ,  C08J3/28 ,  C08J2333/02

    摘要： Superabsorbent polymer particles with improved surface cross-linking and their use in absorbent articles. The superabsorbent polymer particles comprise polymer chain segments, wherein at least a part of the polymer chain segments are covalently cross-linked to each other and wherein at least a part of the cross-links include the reaction product of cross-linking molecules having at least two C═C double bonds and further include the reaction product of radical former molecules. These cross-links are present at surfaces of the superabsorbent polymer particles.

    摘要翻译： 具有改进的表面交联的超吸收性聚合物颗粒及其在吸收制品中的应用。 超吸收聚合物颗粒包含聚合物链段，其中聚合物链段的至少一部分彼此共价交联，并且其中至少一部分交联包括至少具有至少一个交联分子的交联分子的反应产物 两个CC双键，并且还包括基团前分子的反应产物。 这些交联物存在于超吸收性聚合物颗粒的表面。

    Absorbent articles surface cross-linked superabsorbent polymer particles made by a method of using ultraviolet radiation and bronsted acids
    6.
    发明申请
    Absorbent articles surface cross-linked superabsorbent polymer particles made by a method of using ultraviolet radiation and bronsted acids 有权
    吸收制品表面交联的超吸收性聚合物颗粒通过使用紫外线和青铜酸的方法制成

    公开(公告)号：US20070048518A1

    公开(公告)日：2007-03-01

    申请号：US11508372

    申请日：2006-08-23

    申请人： Andreas Flohr ,  Torsten Lindner ,  Yoshiro Mitsukami

    发明人： Andreas Flohr ,  Torsten Lindner ,  Yoshiro Mitsukami

    IPC分类号： B32B5/16

    CPC分类号： A61L15/60 ,  C08J3/28 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2998

    摘要： A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The superabsorbent polymer particles for use in the method have a relatively high degree of neutralization. Brønsted acids are selectively applied onto the surface of the superabsorbent polymer particles to selectively facilitate a relatively high number of protonated carboxyl groups at the surface of the superabsorbent polymer particles while the relatively high degree of neutralization in the core of the superabsorbent polymer particles remains substantially unaffected.

    摘要翻译： 提供了使用紫外线照射来表面交联超吸收性聚合物颗粒的方法。 用于该方法的超吸收性聚合物颗粒具有相对较高的中和度。 布朗斯台德酸被选择性地施加到超吸收性聚合物颗粒的表面上，以选择性地促进超吸收性聚合物颗粒表面的相对高数量的质子化羧基，而超吸收性聚合物颗粒的芯中的相对较高程度的中和基本上不受影响 。

    Absorbent articles comprising surface cross-linked superabsorbent polymer particles made by a method using ultraviolet radiation
    7.
    发明申请
    Absorbent articles comprising surface cross-linked superabsorbent polymer particles made by a method using ultraviolet radiation 有权
    包含通过使用紫外线辐射的方法制成的表面交联的超吸收性聚合物颗粒的吸收制品

    公开(公告)号：US20070048517A1

    公开(公告)日：2007-03-01

    申请号：US11508371

    申请日：2006-08-23

    申请人： Andreas Flohr ,  Torsten Lindner ,  Esther Oliveros ,  Yoshiro Mitsukami

    发明人： Andreas Flohr ,  Torsten Lindner ,  Esther Oliveros ,  Yoshiro Mitsukami

    IPC分类号： B32B5/16

    CPC分类号： A61L15/60 ,  C08J3/28 ,  Y10T428/25 ,  Y10T428/2982 ,  Y10T428/2991

    摘要： A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The method is carried out in a so-called drum reactor, which comprises a hollow drum and an irradiation source. The drum has a longitudinal axis and a cross-section. Radical former molecules are applied on the surface of superabsorbent polymer particles. These superabsorbent polymer particles are fed into the drum and are irradiated while they move within the drum, which is rotated around its longitudinal axis. The irradiation source is provided such that the radiation emitted by the irradiation source is able to reach superabsorbent polymer particles within said drum. The irradiation source for use in the method is able to emit UV radiation of a wavelength between about 201 nm and about 400 nm.

    摘要翻译： 提供了使用紫外线照射来表面交联超吸收性聚合物颗粒的方法。 该方法在所谓的鼓式反应器中进行，该反应器包括中空鼓和照射源。 滚筒具有纵轴和横截面。 在超吸收性聚合物颗粒的表面上施加自由基前分子。 这些超吸收性聚合物颗粒被进料到滚筒中并且在它们围绕其纵向轴线旋转的滚筒内移动时被照射。 照射源设置成使得由照射源发射的辐射能够到达所述鼓内的超吸收性聚合物颗粒。 用于该方法的照射源能够发射约201nm至约400nm之间的波长的紫外线辐射。

    Surface cross-linked superabsorbent polymer particles and methods of making them
    9.
    发明授权
    Surface cross-linked superabsorbent polymer particles and methods of making them 有权
    表面交联超吸收聚合物颗粒及其制备方法

    公开(公告)号：US07588777B2

    公开(公告)日：2009-09-15

    申请号：US11183356

    申请日：2005-07-18

    申请人： Andreas Flohr ,  Torsten Lindner

    发明人： Andreas Flohr ,  Torsten Lindner

    IPC分类号： A61L15/16 ,  A61L15/60 ,  C08F8/14 ,  C08F8/28

    CPC分类号： A61F13/534 ,  A61F2013/530766 ,  A61L15/60 ,  C08J3/28 ,  C08J2333/02

    摘要： The present invention relates to superabsorbent polymer particles with improved surface cross-linking and their use in absorbent articles.The superabsorbent polymer particles of the present invention comprise polymer chain segments, wherein at least a part of the polymer chain segments are covalently cross-linked to each other and wherein at least a part of the cross-links comprise the reaction product of cross-linking molecules having at least two C═C double bonds and further comprise the reaction product of radical former molecules. These cross-links are present at surfaces of the superabsorbent polymer particles.Moreover, the invention relates a method for making these superabsorbent polymer particles.

    摘要翻译： 本发明涉及具有改进的表面交联的超吸收性聚合物颗粒及其在吸收制品中的用途。 本发明的超吸收聚合物颗粒包含聚合物链段，其中至少一部分聚合物链段彼此共价交联，并且其中至少一部分交联包含交联反应产物 具有至少两个CC双键的分子，并且还包含基团前体分子的反应产物。 这些交联物存在于超吸收性聚合物颗粒的表面。 此外，本发明涉及制备这些超吸收性聚合物颗粒的方法。

    METHOD OF SURFACE CROSS-LINKING SUPERABSORBENT POLYMER PARTICLES USING VACUUM ULTRAVIOLET RADIATION
    10.
    发明申请
    METHOD OF SURFACE CROSS-LINKING SUPERABSORBENT POLYMER PARTICLES USING VACUUM ULTRAVIOLET RADIATION 审中-公开
    使用真空紫外线辐射的表面交联超吸收聚合物颗粒的方法

    公开(公告)号：US20090197985A1

    公开(公告)日：2009-08-06

    申请号：US12064723

    申请日：2006-08-22

    申请人： Andreas Flohr ,  Torsten Lindner ,  Esther Oliveros ,  Yoshiro Mitsukami

    发明人： Andreas Flohr ,  Torsten Lindner ,  Esther Oliveros ,  Yoshiro Mitsukami

    IPC分类号： C08F2/48 ,  C08J3/28

    CPC分类号： B29C59/16 ,  B29C35/0266 ,  B29C35/0805 ,  B29C2035/0827 ,  C08J3/245 ,  C08J3/28 ,  C08J2300/14

    摘要： The present invention relates to a method of surface cross-linking superabsorbent polymer particles using UV irradiation. The method is carried out in a so-called drum reactor, which comprises a hollow drum and an irradiation source. The drum has a longitudinal axis and a cross-section. Superabsorbent polymer particles are fed into the drum and are irradiated while they move within the drum, which is rotated around its longitudinal axis. The irradiation source is provided such that the radiation emitted by the irradiation source is able to reach superabsorbent polymer particles within said drum. The irradiation source for use in the method of the present invention is able to emit UV radiation of a wavelength between 100 nm and 200 nm.

    摘要翻译： 本发明涉及使用紫外线照射来表面交联超吸收聚合物颗粒的方法。 该方法在所谓的鼓式反应器中进行，该反应器包括中空鼓和照射源。 滚筒具有纵轴和横截面。 超吸收性聚合物颗粒进料到滚筒中并在滚筒内移动时被照射，滚筒围绕其纵向轴线旋转。 照射源设置成使得由照射源发射的辐射能够到达所述鼓内的超吸收性聚合物颗粒。 用于本发明方法的照射源能够发射波长在100nm与200nm之间的紫外线。