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1.发明授权Method of surface cross-linking superabsorbent polymer particles using ultraviolet radiation and bronsted acids 有权使用紫外线和青铜酸表面交联超吸收聚合物颗粒的方法公开(公告)号：US07838569B2
公开(公告)日：2010-11-23
申请号：US12064706
申请日：2006-08-22
IPC分类号： C08F2/48
CPC分类号： A61L15/60 , A61L2400/18 , C08J3/245 , C08J3/28 , C08J2300/14
摘要： The present invention relates to a method of surface cross-linking superabsorbent polymer particles using UV irradiation. The superabsorbent polymer particles for use in the method of the present invention have a relatively high degree of neutralization. Bronsted acids are selectively applied onto the surface of the superabsorbent polymer particles to selectively facilitate a relatively high number of protonated carboxyl groups at the surface of the superabsorbent polymer particles while the relatively high degree of neutralization in the core of the superabsorbent polymer particles remains substantially unaffected.
摘要翻译： 本发明涉及使用紫外线照射来表面交联超吸收聚合物颗粒的方法。 用于本发明方法的超吸收性聚合物颗粒具有较高的中和度。 布朗斯台德酸选择性地施加到超吸收性聚合物颗粒的表面上，以选择性地促进在超吸收性聚合物颗粒的表面上相对高数量的质子化羧基，而超吸收性聚合物颗粒的芯的相对高度的中和基本上不受影响 。
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2.发明申请METHOD OF SURFACE CROSS-LINKING SUPERABSORBENT POLYMER PARTICLES USING ULTRAVIOLET RADIATION AND BRONSTED ACIDS 有权使用超紫外线辐射和溴化物的表面交联超吸收聚合物颗粒的方法公开(公告)号：US20090131633A1
公开(公告)日：2009-05-21
申请号：US12064706
申请日：2006-08-22
IPC分类号： C08J3/24
CPC分类号： A61L15/60 , A61L2400/18 , C08J3/245 , C08J3/28 , C08J2300/14
摘要： The present invention relates to a method of surface cross-linking superabsorbent polymer particles using UV irradiation. The superabsorbent polymer particles for use in the method of the present invention have a relatively high degree of neutralization. Bronsted acids are selectively applied onto the surface of the superabsorbent polymer particles to selectively facilitate a relatively high number of protonated carboxyl groups at the surface of the superabsorbent polymer particles while the relatively high degree of neutralization in the core of the superabsorbent polymer particles remains substantially unaffected.
摘要翻译： 本发明涉及使用紫外线照射来表面交联超吸收聚合物颗粒的方法。 用于本发明方法的超吸收性聚合物颗粒具有较高的中和度。 布朗斯台德酸选择性地施加到超吸收性聚合物颗粒的表面上，以选择性地促进在超吸收性聚合物颗粒的表面上相对高数量的质子化羧基，而超吸收性聚合物颗粒的芯的相对高度的中和基本上不受影响 。
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3.发明申请Method of surface cross-linking highly neutralized superabsorbent polymer particles using bronsted acids 审中-公开使用青铜酸表面交联高度中和的超吸收性聚合物颗粒的方法公开(公告)号：US20070049689A1
公开(公告)日：2007-03-01
申请号：US11508373
申请日：2006-08-23
申请人： Axel Meyer , Andreas Flohr , Torsten Lindner
发明人： Axel Meyer , Andreas Flohr , Torsten Lindner
IPC分类号： C08G63/91
CPC分类号： C08F8/00 , A61L15/60 , C08F8/14 , C08F2810/20 , C08J3/245 , C08J2300/14
摘要： A method of surface cross-linking superabsorbent polymer particles having a relatively high degree of neutralization is provided. Brønsted acids are selectively applied onto the surface of the superabsorbent polymer particles to selectively facilitate a relatively high number of protonated carboxyl groups at the surface of the superabsorbent polymer particles while the relatively high degree of neutralization in the core of the superabsorbent polymer particles remains substantially unaffected.
摘要翻译： 提供了具有较高中和度的表面交联超吸收性聚合物颗粒的方法。 布朗斯台德酸被选择性地施加到超吸收性聚合物颗粒的表面上，以选择性地促进超吸收性聚合物颗粒表面的相对高数量的质子化羧基，而超吸收性聚合物颗粒的芯中的相对较高程度的中和基本上不受影响 。
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4.发明申请Absorbent articles comprising surface cross-linked superabsorbent polymer particles made by a method using vacuum ultraviolet radiation 失效包含通过使用真空紫外线辐射的方法制成的表面交联的超吸收性聚合物颗粒的吸收制品公开(公告)号：US20070048516A1
公开(公告)日：2007-03-01
申请号：US11508370
申请日：2006-08-23
IPC分类号： B32B5/16
CPC分类号： B29C71/04 , A61L15/60 , B29C2035/0827 , B29C2791/006 , B29K2105/251 , C08J3/24 , C08J3/28 , Y10S526/931 , Y10T428/25 , Y10T428/2982 , Y10T428/2991
摘要： A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The method is carried out in a so-called drum reactor, which comprises a hollow drum and an irradiation source. The drum has a longitudinal axis and a cross-section. Superabsorbent polymer particles are fed into the drum and are irradiated while they move within the drum, which is rotated around its longitudinal axis. The irradiation source is provided such that the radiation emitted by the irradiation source is able to reach superabsorbent polymer particles within said drum. The irradiation source for use in the method is able to emit UV radiation of a wavelength between about 100 nm and about 200 nm.
摘要翻译： 提供了使用紫外线照射来表面交联超吸收性聚合物颗粒的方法。 该方法在所谓的鼓式反应器中进行，该反应器包括中空鼓和照射源。 滚筒具有纵轴和横截面。 超吸收性聚合物颗粒进料到滚筒中并在滚筒内移动时被照射，滚筒围绕其纵向轴线旋转。 照射源设置成使得由照射源发射的辐射能够到达所述鼓内的超吸收性聚合物颗粒。 用于该方法的照射源能够发射约100nm至约200nm之间的波长的紫外线辐射。
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公开(公告)号：US20060020053A1
公开(公告)日：2006-01-26
申请号：US11183356
申请日：2005-07-18
申请人： Andreas Flohr , Torsten Lindner
发明人： Andreas Flohr , Torsten Lindner
IPC分类号： C08J3/28
CPC分类号： A61F13/534 , A61F2013/530766 , A61L15/60 , C08J3/28 , C08J2333/02
摘要： The present invention relates to superabsorbent polymer particles with improved surface cross-linking and their use in absorbent articles. The superabsorbent polymer particles of the present invention comprise polymer chain segments, wherein at least a part of the polymer chain segments are covalently cross-linked to each other and wherein at least a part of the cross-links comprise the reaction product of cross-linking molecules having at least two C═C double bonds and further comprise the reaction product of radical former molecules. These cross-links are present at surfaces of the superabsorbent polymer particles. Moreover, the invention relates a method for making these superabsorbent polymer particles.
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6.发明申请Superabsorbent polymer particles comprising functionalizers and method of making them 有权包含官能团的超吸收聚合物颗粒及其制备方法公开(公告)号：US20060030829A1
公开(公告)日：2006-02-09
申请号：US11198081
申请日：2005-08-05
申请人： Andreas Flohr , Torsten Lindner
发明人： Andreas Flohr , Torsten Lindner
IPC分类号： A61F13/15
CPC分类号： C08F265/04 , C08L51/003 , Y10T428/249986 , C08L2666/02
摘要： The present invention relates to superabsorbent polymer particles having functionalizers covalently bound to the surface of precursor superabsorbent polymer particles. The functionalizers of the present invention comprise a grafting unit with a radiation activatable group and a functional unit covalently bound to the grafting unit. The grafting unit is bound to an aliphatic C—H group comprised at the surface of the precursor superabsorbent polymer particle. The functional unit comprises chemical structures which are not present in the precursor superabsorbent polymer particle. These functional units add an additional function to the precursor suberabsorbent polymer particle or modifying an existing function of the precursor superabsorbent polymer particle. Moreover, the invention relates to a process for making these superabsorbent polymer particles.
摘要翻译： 本发明涉及具有与前体超吸收性聚合物颗粒的表面共价结合的官能化物的超吸收性聚合物颗粒。 本发明的功能化剂包括具有可辐射活化基团和与接枝单元共价结合的官能单元的接枝单元。 接枝单元与包含在前体超吸收聚合物颗粒表面的脂族C-H基团结合。 功能单元包括不存在于前体超吸收聚合物颗粒中的化学结构。 这些功能单元向前体抗氧化剂聚合物颗粒添加附加功能或改变前体超吸收聚合物颗粒的现有功能。 此外，本发明涉及制备这些超吸收性聚合物颗粒的方法。
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7.发明授权Superabsorbent polymers comprising direct covalent bonds between polymer chain segments and method of making them 有权包含聚合物链段之间的直接共价键的超吸收性聚合物及其制备方法公开(公告)号：US08080705B2
公开(公告)日：2011-12-20
申请号：US11182421
申请日：2005-07-15
申请人： Andreas Flohr , Torsten Lindner
发明人： Andreas Flohr , Torsten Lindner
IPC分类号： A61F13/53
CPC分类号： C08L53/00 , C08F265/02 , C08F291/00 , C08J3/12 , C08J3/28 , C08J2300/14 , C08J2333/02 , C08L51/003 , C08F238/00 , C08L2666/02
摘要： The present invention relates to superabsorbent polymer particles with improved surface cross-linking and their use in absorbent articles.Superabsorbent polymers of the invention comprise polymer chain segments, wherein at least a part of these polymer chain segments are cross-linked to each other through direct covalent bonds.Moreover, the invention relates to a process for making these superabsorbent polymer particles.
摘要翻译： 本发明涉及具有改进的表面交联的超吸收性聚合物颗粒及其在吸收制品中的用途。 本发明的超吸收性聚合物包含聚合物链段，其中这些聚合物链段的至少一部分通过直接共价键彼此交联。 此外，本发明涉及制备这些超吸收性聚合物颗粒的方法。
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8.发明申请Surface Cross-Linked Superabsorbent Polymer Particles and Methods of Making Them 有权表面交联超吸收聚合物颗粒及其制备方法公开(公告)号：US20090299315A1
公开(公告)日：2009-12-03
申请号：US12537585
申请日：2009-08-07
申请人： Andreas Flohr , Torsten Lindner
发明人： Andreas Flohr , Torsten Lindner
CPC分类号： A61F13/534 , A61F2013/530766 , A61L15/60 , C08J3/28 , C08J2333/02
摘要： Superabsorbent polymer particles with improved surface cross-linking and their use in absorbent articles. The superabsorbent polymer particles comprise polymer chain segments, wherein at least a part of the polymer chain segments are covalently cross-linked to each other and wherein at least a part of the cross-links include the reaction product of cross-linking molecules having at least two C═C double bonds and further include the reaction product of radical former molecules. These cross-links are present at surfaces of the superabsorbent polymer particles.
摘要翻译： 具有改进的表面交联的超吸收性聚合物颗粒及其在吸收制品中的应用。 超吸收聚合物颗粒包含聚合物链段，其中聚合物链段的至少一部分彼此共价交联，并且其中至少一部分交联包括至少具有至少一个交联分子的交联分子的反应产物 两个CC双键，并且还包括基团前分子的反应产物。 这些交联物存在于超吸收性聚合物颗粒的表面。
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公开(公告)号：US20090298963A1
公开(公告)日：2009-12-03
申请号：US11721285
申请日：2005-12-09
申请人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Andreas Flohr , Torsten Lindner
发明人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Andreas Flohr , Torsten Lindner
CPC分类号： C08L33/02 , C08F8/44 , C08J3/28 , C08J2300/14 , C08J2333/02 , C08F20/06 , C08L2666/04
摘要： This invention is to provide a method for producing a modified water absorbent resin excelling in water absorbing properties. This invention relates to a method for producing a modified water absorbent resin, which comprises a) mixing a water absorbent resin and a water-soluble radical polymerization initiator or a heat-degradable radical polymerization initiator without addition of an ethylenically unsaturated monomer and b) irradiating the resultant mixture with active energy rays. The method is particularly capable of exalting the absorbency against pressure and the saline flow conductivity.
摘要翻译： 本发明提供一种制造吸水性优异的改性吸水性树脂的方法。 本发明涉及一种改性吸水性树脂的制造方法，该方法包括：a）在不加入烯属不饱和单体的情况下，将吸水性树脂与水溶性自由基聚合引发剂或热降解自由基聚合引发剂混合，b）照射 所得的具有活性能量射线的混合物。 该方法特别能够提高抗压力和盐水流动导电性的吸收性。
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10.发明申请Absorbent articles surface cross-linked superabsorbent polymer particles made by a method of using ultraviolet radiation and bronsted acids 有权吸收制品表面交联的超吸收性聚合物颗粒通过使用紫外线和青铜酸的方法制成公开(公告)号：US20070048518A1
公开(公告)日：2007-03-01
申请号：US11508372
申请日：2006-08-23
IPC分类号： B32B5/16
CPC分类号： A61L15/60 , C08J3/28 , Y10T428/25 , Y10T428/254 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998
摘要： A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The superabsorbent polymer particles for use in the method have a relatively high degree of neutralization. Brønsted acids are selectively applied onto the surface of the superabsorbent polymer particles to selectively facilitate a relatively high number of protonated carboxyl groups at the surface of the superabsorbent polymer particles while the relatively high degree of neutralization in the core of the superabsorbent polymer particles remains substantially unaffected.
摘要翻译： 提供了使用紫外线照射来表面交联超吸收性聚合物颗粒的方法。 用于该方法的超吸收性聚合物颗粒具有相对较高的中和度。 布朗斯台德酸被选择性地施加到超吸收性聚合物颗粒的表面上，以选择性地促进超吸收性聚合物颗粒表面的相对高数量的质子化羧基，而超吸收性聚合物颗粒的芯中的相对较高程度的中和基本上不受影响 。
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