公开(公告)号：US3616320A

公开(公告)日：1971-10-26

申请号：US3616320D

申请日：1969-03-17

Applicant: BASF AG

Inventor： BECK FRITZ ,  LEITNER HANS

IPC: C25B3/10 ,  C07B29/06 ,  B01K3/00

CPC classification number: C25B3/105

Abstract: Production of adiponitrile by direct electrochemical hydrodimerization of acrylonitrile in a medium which contains acrylonitrile, and electrolyte salt, water and, if desired, a solvent at a temperature of from 10* to 60* C. and a pH value of from 1 to 10 using liquid-impermeable electrodes. The medium is passed through the pairs of electrodes which are 0.05 to 2 mm. apart. Adiponitrile is an important intermediate for synthetic fiber manufacture.

Abstract translation: 通过使用含有丙烯腈，电解质盐，水和如果需要的溶剂，在10至60℃的温度下，在1至10的pH下，通过丙烯腈的直接电化学加氢聚合制备己二腈的方法 在该过程中，电解是在具有液体阴极的电池中进行的，该液体阴极与不被液体阴极润湿或固体阳极浸入其中的深度不超过20mm的固体阳极接触。 己二腈是合成纤维制造的重要中间体。

公开(公告)号：US3511765A

公开(公告)日：1970-05-12

申请号：US3511765D

申请日：1966-07-08

Applicant: BASF AG

Inventor： BECK FRITZ ,  LEITNER HANS ,  GUTHKE HARALD ,  WINTERSBERGER KARL

IPC: C25B3/00 ,  C25B3/04 ,  C25B3/10 ,  C25B9/06 ,  C25B9/12 ,  C25B11/02 ,  C25B15/00 ,  C25B15/06 ,  B01K3/00

CPC classification number: C25B9/12 ,  C25B3/00 ,  C25B3/04 ,  C25B3/105 ,  C25B9/06 ,  C25B11/02 ,  C25B15/00 ,  C25B15/06

公开(公告)号：US3477923A

公开(公告)日：1969-11-11

申请号：US3477923D

申请日：1966-07-08

Applicant: BASF AG

Inventor： BECK FRITZ ,  LEITNER HANS ,  WINTERSBERGER KARL ,  GUTHKE HARALD

IPC: B01J19/08 ,  C25B3/10 ,  B01K1/00 ,  B01K3/10

CPC classification number: C07C255/00 ,  C25B3/105

公开(公告)号：US3642592A

公开(公告)日：1972-02-15

申请号：US3642592D

申请日：1969-03-17

Applicant: BASF AG

Inventor： BECK FRITZ ,  GUTHKE HARALD ,  LEITNER HANS

IPC: C25B3/10 ,  C07B29/06

CPC classification number: C25B3/105

Abstract: Process for the production of adiponitrile by direct electrochemical hydrodimerization of acrylonitrile using a medium containing acrylonitrile, an electrolyte salt, water and, if desired, a solvent at a temperature of from 10* to 60* C. at a pH of from 1 to 10. In the process, electrolysis is carried out in a cell having a liquid cathode which is contacted by a solid anode which is not wetted by the liquid cathode or into which the solid anode is immersed to a depth of up to 20 mm. Adiponitrile is an important intermediate for synthetic fiber manufacture.

公开(公告)号：US3557186A

公开(公告)日：1971-01-19

申请号：US3557186D

申请日：1968-06-17

Applicant: BASF AG

Inventor： LEITNER HANS ,  WINTERSBERGER KARL

IPC: C07B31/00 ,  C07C121/26

CPC classification number: C07B31/00

Abstract: A PROCESS FOR THE REDUCTIVE DIMERIZATION OF A,B-UNSATURATED NITRILES, AMIDES OR ESTERS SUSCEPTIBLE TO MICHAEL REACTION BY TREATMENT WITH ALKALI METAL OR ALKALINE EARTH METAL AMALGAMS IN THE PRESENCE OF COMPOUNDS WHICH ARE PROTON DONORS BUT DO NOT REACT APPRECIABLY UNDER THE REACTION CONDITIONS, PARTICULARLY WATER, AND IN THE PRESENCE OF HEXAMETHYLETHYLENETETRAMINE.