Separation of 3,3-dimethylacrolein and -methyl-3-buten-1-ol by azeotropic distillation with water and glycerol
    1.
    发明授权
    Separation of 3,3-dimethylacrolein and -methyl-3-buten-1-ol by azeotropic distillation with water and glycerol 失效
    通过与水和甘油共沸蒸馏分离3,3-二甲基丙烯醛和 - 甲基-3-丁烯-1-醇

    公开(公告)号:US3894916A

    公开(公告)日:1975-07-15

    申请号:US39282173

    申请日:1973-08-29

    Applicant: BASF AG

    CPC classification number: C07C45/84 C07C47/21

    Abstract: A process for separating, by distillation, a mixture consisting essentially of 3,3-dimethylacrolein and 3-methyl-3-buten-1-ol, wherein the mixture to be separated is distilled in the presence of water and glycerol, the 3,3-dimethyl-acrolein first being distilled off azeotropically with water and the 3-methyl-3-buten1-ol then being separated, as an azeotropic mixture with water, from the higher-boiling glycerol. It is also possible to isolate the 3,3-dimethylacrolein by distillation if the 3-methyl-3-buten1-ol is partially replaced by 3-methyl-2-buten-1-ol. The 3,3dimethylacrolein, which can be isolated in pure form by the process of the invention, is a valuable intermediate for the synthesis of natural substances such as citral, vitamin A and chrysanthemic acid.

    Abstract translation: 通过蒸馏分离基本上由3,3-二甲基丙烯醛和3-甲基-3-丁烯-1-醇组成的混合物的方法,其中待分离的混合物在水和甘油的存在下蒸馏, 首先与水共沸蒸馏出3-三甲基 - 丙烯醛,然后将3-甲基-3-丁烯-1-醇与较高沸点甘油作为与水的共沸混合物分离。 如果3-甲基-3-丁烯-1-醇部分被3-甲基-2-丁烯-1-醇代替,也可以通过蒸馏分离3,3-二甲基丙烯醛。 可以通过本发明的方法以纯形式分离的3,3-二甲基丙烯醛是合成天然物质如柠檬醛,维生素A和菊酸的有价值的中间体。

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