公开(公告)号：US3876446A

公开(公告)日：1975-04-08

申请号：US32521473

申请日：1973-01-19

Applicant: BASF AG

Inventor： BLECKMANN GERHARD ,  SANNER AXEL ,  SCHLEMMER LOTHAR ,  WIGGER AUGUST

IPC: C08J9/00 ,  B29C67/20 ,  C08F2/46 ,  C08F283/01 ,  C08F291/18 ,  C08J9/28 ,  B44D1/50 ,  C08F3/00

CPC classification number: C08J9/283 ,  B29C67/202 ,  C08F2/46 ,  C08F283/01 ,  C08F291/18 ,  C08J2201/0504

Abstract: Poromeric web materials are continuously manufactured by applying to a thin layer of ice crystals a textile fibrous structure and an aqueous solution or dispersion of A. polyethylenically unsaturated monomers having at least two polymerizable double bonds or mixtures of at least 0.1 percent w/w of such polyethylenically unsaturated monomers and monoethylenically unsaturated copolymerizable monomers and optionally high molecular weight polymers, or B. monoethylenically unsaturated monomers and high polymers having molecular weights of more than 10,000, Cooling the whole to such an extent that at least 50 percent of the water Crystallizes, irradiating the solidified structure with electromagnetic radiation having a wavelength of less than 0.70 .mu.m to cause polymerization of the monomers, causing the structure to thaw, removing the material from the support and optionally washing the removed material, separating it from the water and finally drying it.

公开(公告)号：US3640753A

公开(公告)日：1972-02-08

申请号：US3640753D

申请日：1969-10-31

Applicant: BASF AG

Inventor： KRAUCH CARL HEINRICH ,  SANNER AXEL

IPC: C08F2/00 ,  C08F2/02 ,  C08F2/36 ,  C08F4/40 ,  C08J9/28 ,  D06M14/00 ,  B44D1/44 ,  D06N3/04

CPC classification number: C08J9/28 ,  C08J2357/00 ,  D06M14/00

Abstract: The process of making poromeric materials which comprises impregnating webs of fibrous material with aqueous liquids containing olefinically unsaturated monomers which can be polymerized using redox catalysts, and, if desired, high polymeric plastics in dissolved, emulsified or dispersed form, freezing the webs of fibrous materials impregnated with the aqueous liquids, polymerizing the monomers using redox catalysts and thawing out and separating out the water and any residual monomer from the resulting poromeric materials. These poromeric materials are suitable as floor coverings, insulating materials, leather substitutes and coating materials.

Abstract translation: 制造多孔体材料的方法包括用含有可以使用氧化还原催化剂聚合的烯属不饱和单体的水性液体浸渍纤维材料纤维，以及如果需要，溶解，乳化或分散形式的高分子塑料，冻结纤维材料网 用含水液体浸渍，使用氧化还原催化剂聚合单体，并将所得到的多孔体材料中的水和任何残留的单体解离出来并分离出来。 这些孔体材料适用于地板覆盖物，绝缘材料，皮革代用品和涂料。