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    REMOVAL OF HYDROGEN SULPHIDE AND CARBON DIOXIDE FROM A STREAM OF FLUID
    1.
    发明申请
    REMOVAL OF HYDROGEN SULPHIDE AND CARBON DIOXIDE FROM A STREAM OF FLUID 审中-公开

    公开(公告)号：US20190134557A1

    公开(公告)日：2019-05-09

    申请号：US16238069

    申请日：2019-01-02

    Applicant: BASF SE

    Inventor： Thomas INGRAM ,  Ralf NOTZ ,  Gerald VORBERG ,  Georg SIEDER

    IPC: B01D53/14 ,  C07C217/08

    Abstract: A process for removing hydrogen sulfide and carbon dioxide from a fluid stream comprises a) an absorption step in which the fluid stream is contacted with an absorbent comprising an aqueous solution (i) of an amine of the general formula (I) in which R1, R2 and R3 are each independently selected from C1-4-alkyl and C1-4-hydroxyalkyl; each R4 is independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl; each R5 is independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl; X is OH or NH(CR1R2R3); m is 2, 3, 4 or 5; n is 2, 3, 4 or 5; and o is 0 or 1; and optionally (ii) at least one tertiary amine, where the molar ratio of (i) to (ii) is greater than 0.05; wherein at least 90% of the hydrogen sulfide is removed from the fluid stream and selectivity for hydrogen sulfide over carbon dioxide is not greater than 8, wherein a CO2- and H2S-laden absorbent is obtained; b) a regeneration step in which at least a substream of the CO2- and H2S-laden absorbent is regenerated and a regenerated absorbent is obtained; and c) a recycling step in which at least a substream of the regenerated absorbent is recycled into the absorption step a). The process allows a high level of hydrogen sulfide removal with a simultaneously high coabsorption of carbon dioxide.

    REMOVAL OF HYDROGEN SULPHIDE AND CARBON DIOXIDE FROM A STREAM OF FLUID
    2.
    发明申请
    REMOVAL OF HYDROGEN SULPHIDE AND CARBON DIOXIDE FROM A STREAM OF FLUID 审中-公开

    公开(公告)号：US20170282115A1

    公开(公告)日：2017-10-05

    申请号：US15506635

    申请日：2015-08-20

    Applicant: BASF SE

    Inventor： Thomas INGRAM ,  Ralf NOTZ ,  Gerald VORBERG ,  Georg SIEDER

    IPC: B01D53/14 ,  C07C217/08

    CPC classification number: B01D53/1462 ,  B01D53/1493 ,  B01D2252/2026 ,  B01D2252/20405 ,  B01D2252/2041 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20484 ,  B01D2252/502 ,  B01D2252/504 ,  C07C217/08

    Abstract: A process for removing hydrogen sulfide and carbon dioxide from a fluid stream comprises a) an absorption step in which the fluid stream is contacted with an absorbent comprising an aqueous solution (i) of an amine of the general formula (I) in which R1, R2 and R3 are each independently selected from C1-4-alkyl and C1-4-hydroxyalkyl; each R4 is independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl; each R5 is independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl; X is OH or NH(CR1R2R3); m is 2, 3, 4 or 5; n is 2, 3, 4 or 5; and o is 0 or 1; and optionally (ii) at least one tertiary amine, where the molar ratio of (i) to (ii) is greater than 0.05; wherein at least 90% of the hydrogen sulfide is removed from the fluid stream and selectivity for hydrogen sulfide over carbon dioxide is not greater than 8, wherein a CO2- and H2S-laden absorbent is obtained; b) a regeneration step in which at least a substream of the CO2- and H2S-laden absorbent is regenerated and a regenerated absorbent is obtained; and c) a recycling step in which at least a substream of the regenerated absorbent is recycled into the absorption step a). The process allows a high level of hydrogen sulfide removal with a simultaneously high coabsorption of carbon dioxide.

    CYCLIC AMINE FOR SELECTIVELY REMOVING HYDROGEN SULPHIDE
    3.
    发明申请
    CYCLIC AMINE FOR SELECTIVELY REMOVING HYDROGEN SULPHIDE 审中-公开

    公开(公告)号：US20200030739A1

    公开(公告)日：2020-01-30

    申请号：US16594526

    申请日：2019-10-07

    Applicant: BASF SE

    Inventor： Thomas INGRAM ,  Georg SIEDER ,  Torsten KATZ ,  Gerald VORBERG ,  Ralf NOTZ

    IPC: B01D53/14 ,  C10L3/10

    Abstract: The use of an amine of the formula (I) in which the R1 to R5 radicals are each as defined in the description, and an absorbent and a process for removing acidic gases from a fluid stream, especially for selectively removing hydrogen sulfide over carbon dioxide. The invention also relates to particular amines suitable for selective removal of hydrogen sulfide. Absorbents based on amines of the formula (I) have high selectivity, high loading capacity and good regeneration capacity.

    PREMIX FOR PRODUCING AN ABSORPTION AGENT FOR REMOVING ACID GASES FROM A FLUID FLOW
    4.
    发明申请
    PREMIX FOR PRODUCING AN ABSORPTION AGENT FOR REMOVING ACID GASES FROM A FLUID FLOW 审中-公开

    公开(公告)号：US20190126193A1

    公开(公告)日：2019-05-02

    申请号：US16093731

    申请日：2017-04-06

    Applicant: BASF SE

    Inventor： Thomas INGRAM ,  Gerald VORBERG ,  Georg SIEDER

    IPC: B01D53/14 ,  C10L3/10

    Abstract: A premixture for producing an absorbent for removing acid gases from a fluid stream containing a) at least a tertiary amine and/or a sterically hindered secondary amine; b) a dicarboxylic acid in an amount, calculated as neutralization equivalent based on the protonatable nitrogen atoms in a), of at least 30%, wherein the dicarboxylic acid has a solubility in water at a temperature of 20° C. of not more than 15 g of dicarboxylic acid per 100 g of water; and c) 20 to 80 wt % of water. Also described is a process for producing an absorbent from the premixture. The premixture is a transportable and readily handleable solution of a dicarboxylic acid having poor solubility in water for producing an absorbent for removing acid gases from a fluid stream.

    PROCESS FOR REMOVAL OF ACID GASES FROM A FLUID STREAM WITH A LIQUID ABSORBENT COMPRISING A PIPERAZINE RING
    6.
    发明申请
    PROCESS FOR REMOVAL OF ACID GASES FROM A FLUID STREAM WITH A LIQUID ABSORBENT COMPRISING A PIPERAZINE RING 有权

    公开(公告)号：US20220152551A1

    公开(公告)日：2022-05-19

    申请号：US17431872

    申请日：2020-02-14

    Applicant: BASF SE

    Inventor： Martin ERNST ,  Thomas INGRAM ,  Gerald VORBERG ,  Georg SIEDER

    IPC: B01D53/14 ,  C10L3/10 ,  C07D295/13

    Abstract: A process for removal of acid gases from fluid stream, wherein the fluid stream is brought into contact with an absorbent to obtain a treated fluid stream and a laden absorbent, the absorbent comprising a diluent and a compound of the general formula (I) wherein R1 is selected from C1-C8-alkyl and C2-C8-hydroxyalkyl; R2 is selected from hydrogen and C1-C8-alkyl; R3 is selected from hydrogen and C1-C8-alkyl; R4 is selected from hydrogen and C1-C8-alkyl; R5 is C1-C8-alkyl; with the proviso that at least one of the following conditions (i) and (ii) is met: (i) R5 is C3-C8-alkyl bound to the nitrogen atom via a secondary or tertiary carbon atom; (ii) when R4 is hydrogen, R3 is C1-C8-alkyl; or when R4 is C1-C8-alkyl, at least one of R2 and R3 is C1-C8-alkyl; and n is an integer from 0 to 6. Further provided is an absorbent for the absorption of acid gases from a fluid stream, comprising a diluent and a compound of the general formula (I) as defined above, as well as the use of a compound of the general formula (I) as defined above for removal of acid gases from a fluid stream. The absorbents are useful for the selective removal of hydrogen sulfide from fluid streams and have high acid gas loading capacity, high stability, and low volatility.

    ABSORBENT AND PROCESS FOR SELECTIVELY REMOVING HYDROGEN SULFIDE
    7.
    发明申请
    ABSORBENT AND PROCESS FOR SELECTIVELY REMOVING HYDROGEN SULFIDE 审中-公开

    公开(公告)号：US20200269187A1

    公开(公告)日：2020-08-27

    申请号：US16643665

    申请日：2018-08-30

    Applicant: BASF SE ,  ExxonMobil Research and Engineering Company

    Inventor： Martin ERNST ,  Gerald VORBERG ,  Thomas INGRAM ,  Georg SIEDER ,  Carla PEREIRA

    IPC: B01D53/14

    Abstract: An absorbent for the selective removal of hydrogen sulfide over carbon dioxide from a fluid stream, wherein the absorbent contains an aqueous solution, comprising an amine of formula (I) and/or an amine of formula (II) wherein U—V—W is CH—O—CHR5, N—CO—CHR5 or N—CO—NR5; U′—V′—W is C—O—CR5; R1 is independently C1-C5-alkyl; R2 is selected from hydrogen and C1-C5-alkyl; R3 is independently selected from hydrogen and C1-C5-alkyl; R4 is independently selected from hydrogen and C1-C5-alkyl; R5 is selected from hydrogen, C1-C5-alkyl, (C1-C5-alkoxy)-C1-C5-alkyl, and hydroxy-C1-C5-alkyl; and x is an integer from 1 to 10. The absorbent has a reduced tendency for phase separation at temperatures falling within the usual range of regeneration temperatures for the aqueous amine mixtures and a low volatility in aqueous solvents.

    ABSORBENT FOR SELECTIVE REMOVAL OF HYDROGEN SULFIDE FROM A FLUID STREAM
    8.
    发明申请
    ABSORBENT FOR SELECTIVE REMOVAL OF HYDROGEN SULFIDE FROM A FLUID STREAM 审中-公开

    公开(公告)号：US20190388829A1

    公开(公告)日：2019-12-26

    申请号：US16556903

    申请日：2019-08-30

    Applicant: BASF SE

    Inventor： Gerald VORBERG ,  Ralf NOTZ ,  Thomas INGRAM ,  Georg SIEDER ,  Torsten KATZ

    IPC: B01D53/14 ,  C10L3/10

    Abstract: An absorbent for selective removal of hydrogen sulfide over carbon dioxide from a fluid stream comprises an aqueous solution of a) a tertiary amine, b) a sterically hindered secondary amine of the general formula (I) in which R1 and R2 are each independently selected from C1-4-alkyl and C1-4-hydroxyalkyl; R3, R4, R5 and R6 are each independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl, with the proviso that at least one R4 and/or R5 radical on the carbon atom bonded directly to the nitrogen atom is C1-4-alkyl or C1-4-hydroxyalkyl when R3 is hydrogen; x and y are integers from 2 to 4 and z is an integer from 1 to 4; where the molar ratio of b) to a) is in the range from 0.05 to 1.0, and c) an acid in an amount, calculated as neutralization equivalent relative to the protonatable nitrogen atoms in a) and b), of 0.05 to 15.0%. One preferred amine of the formula I is 2-(2-tert-butylaminoethoxy)ethanol. The absorbent allows a defined H2S selectivity to be set at pressures of the kind typical in natural gas processing.

    ABSORBENT AND PROCESS FOR SELECTIVELY REMOVING HYDROGEN SULFIDE
    10.
    发明申请
    ABSORBENT AND PROCESS FOR SELECTIVELY REMOVING HYDROGEN SULFIDE 审中-公开

    公开(公告)号：US20200164303A1

    公开(公告)日：2020-05-28

    申请号：US16612921

    申请日：2018-05-14

    Applicant: BASF SE ,  ExxonMobil Research and Engineering Company

    Inventor： Martin ERNST ,  Gerald VORBERG ,  Georg SIEDER ,  Thomas INGRAM ,  Virginia REINER ,  Carla PEREIRA ,  Michael SISKIN

    IPC: B01D53/14 ,  C10L3/10 ,  C07C217/08 ,  C07C213/02

    Abstract: An absorbent for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide, wherein the absorbent contains an aqueous solution, comprising: a) an amine or a mixture of amines of the general formula (I) wherein R1 is C1-C5-alkyl; R2 is C1-C5-alkyl; R3 is selected from hydrogen and C1-C5-alkyl; x is an integer from 2 to 10; and b) an ether or a mixture of ethers of the general formula (II): R4—[O—CH2—CH2]y—OH; wherein R4 is C1-C5-alkyl; and y is an integer from 2 to 10; wherein R1 and R4 are identical; wherein the mass ratio of b) to a) is from 0.08 to 0.5. The absorbent is suitable for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide. The absorbent has a reduced tendency for phase separation at temperatures falling within the usual range of regeneration temperatures for the aqueous amine mixtures and is easily obtainable.

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