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公开(公告)号:US20250100965A1
公开(公告)日:2025-03-27
申请号:US18852720
申请日:2023-03-30
Applicant: BASF SE
Inventor: Stefan BLEI , Faissal-Ali EL-TOUFAILI , Alexander HETZ-HUNSINGER , Marc FELDEN , Jochen GAUER , Michel GASSMANN , Christian DIENES , Zeljko KOTANJAC , Vikram Raghavendhar RAVIKUMAR , Esther Matyka LARYEA
IPC: C07D201/12 , C07D201/16
Abstract: The present invention relates to a process for separating at least one ε-caprolactam oligomeric compound CPO from a stream SR comprising said at least one CPO and ε-caprolactam monomeric compound CPM.
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公开(公告)号:US20220212936A1
公开(公告)日:2022-07-07
申请号:US17605737
申请日:2020-04-14
Applicant: BASF SE
Inventor: Torsten MATTKE , Gerhard OLBERT , Jochen GAUER , Kai THIELE , Koenraad VANDEWALLE , Jens FERBITZ , Peter VAN DEN ABEEL
Abstract: The present invention relates to a process for preparing phosgene by reacting chlorine with carbon monoxide over an activated carbon catalyst, wherein the content of chlorine oxides in the chlorine feed stream is low, to an apparatus for preparation of phosgene and to the use of the phosgene prepared by the process of the invention.
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公开(公告)号:US20230192500A1
公开(公告)日:2023-06-22
申请号:US17925331
申请日:2021-05-10
Applicant: BASF SE
Inventor: Gerhard OLBERT , Benjamin KRON , Jochen GAUER , Jens FERBITZ , Torsten MATTKE , Kai THIELE , Peter VAN DEN ABEEL , Koenraad VANDEWALLE , Kirill BRAMNIK , Jim BRANDTS
CPC classification number: C01B32/80 , B01J21/18 , B01J35/04 , B01J35/1023 , B01J35/1028 , B01J35/1042 , B01J35/1047 , B01J35/1061
Abstract: The invention relates to a process for the production of phosgene comprising a gas phase reaction of carbon monoxide and chlorine in the presence of a carbon catalyst in a multi-tubular reactor, wherein the carbon catalyst comprises an amount of mesopores having a pore diameter in the range of from 2 to 50 nm of at least 0.45 ml/g of the total pore volume and the use of a carbon catalyst comprising an amount of mesopores having a pore diameter in the range of from 2 to 50 nm of at least 0.45 ml/g of the total pore volume, for the production of phosgene and a reaction mixture for preparing phosgene, the mixture comprising a catalyst for preparing phosgene comprising a porous material comprising carbon, micropores and mesopores, wherein said micropores have a pore diameter of less than 2 nm and wherein said mesopores have a pore diameter in the range of from 2 to 50 nm, wherein the volume of the mesopores of the porous material is of at least 0.45 ml/g, and a gas stream G comprising carbon monoxide (CO) and chlorine (Cl2).
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公开(公告)号:US20180305210A1
公开(公告)日:2018-10-25
申请号:US15779347
申请日:2016-11-18
Applicant: BASF SE
Inventor: Gerhard OLBERT , Jochen GAUER , Holger FRIEDRICH , Andreas SPIEGEL , Andreas WÖLFERT , Wolfgang GMEINER , Michael LORENZ
CPC classification number: C01B21/28 , B01J10/007 , B01J19/2485 , C01B21/26 , C01B21/38
Abstract: The present invention relates to a reactor R with apparatus D, the latter comprising a gas- and/or liquid-permeable tray B, in the edge region of which there is disposed a lateral boundary W which fully encloses the tray B and forms a volume V comprising catalytic and/or noncatalytic shaped bodies (F), wherein there is at least one braid made of precious metal and/or base metal on the upstream side opposite the tray B, and the catalytic and/or noncatalytic shaped bodies (F) are selected from (i) shaped bodies (F1) in the form of straight prisms, the footprint of which is selected from triangle, rectangle, hexagon or fragments of these polygons, and (ii) a combination of the shaped bodies (F1) with shaped bodies (F2) that are smaller than the shaped bodies (F1), wherein groups of m to n shaped bodies (F1), m and n being an integer from 3 to 30 with n>m, are framed in a metal cassette open in the upstream direction and closed in the downstream direction by a gas-permeable tray, in a virtually seamless manner with side face to side face and with their longitudinal axis aligned in vertical direction, virtually completely covering the cross section of the tray, to form modules (M), and the modules (M), optionally with cooperation of a joint filler material, with vertical alignment of the longitudinal axis of the shaped bodies (F1), are joined to one another virtually seamlessly in a mosaic-like manner such
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