公开(公告)号：US20220411281A1

公开(公告)日：2022-12-29

申请号：US17754952

申请日：2020-10-15

Applicant: BASF SE

Inventor： Young Jin KIM ,  James A. SIOSS ,  Jacob HAAG ,  Plousia VASSILARAS ,  Jordan K. LAMPERT ,  Brandon Ray LONG

IPC: C01G53/00 ,  H01M10/0525

Abstract: Electrode active material comprising (A) a core material according to general formula Li1+x1TM1−x1O2 wherein TM is a combination of Ni and at least one of Mn, Co and Al, and, optionally, at least one more metal selected from Mg, Ti, Zr, Nb, Ta, and W, and x1 is in the range of from −0.05 to 0.2, and (B) particles of cobalt compound(s) and of aluminum compound(s) and of titanium compound(s) or zirconium compound(s) wherein the molar ratio of lithium to cobalt in said particles is in the range of from zero to below 1 and wherein said particles are attached to the surface of the core material.

公开(公告)号：US20220263069A1

公开(公告)日：2022-08-18

申请号：US17754954

申请日：2020-10-15

Applicant: BASF SE

Inventor： Young Jin KIM ,  James A. SIOSS ,  Jacob HAAG ,  Plousia VASSILARAS ,  Jordan K. LAMPERT ,  Brandon Ray LONG

IPC: H01M4/36 ,  H01M4/505 ,  H01M4/525 ,  H01M4/04 ,  C01G53/00

Abstract: Electrode active material comprising (A) a core material according to general formula Li1+x1TM1−x1O2 wherein TM is a combination of Ni and at least one of Mn, Co and Al, and, optionally, at least one more metal selected from Mg, Ti, Zr, Nb, Ta, and W, and x1 is in the range of from −0.05 to 0.2, and (B) particles of cobalt compound(s) and of titanium compound(s) and of zirconium compound(s) and of aluminum compound(s) in which the average oxidation state of cobalt is higher than +II and lower than +III and wherein the molar ratio of lithium to cobalt in said particles is in the range of from zero to 1 and wherein said particles are attached to the surface of the core material.

公开(公告)号：US20220278324A1

公开(公告)日：2022-09-01

申请号：US17635347

申请日：2020-08-20

Applicant: BASF SE

Inventor： Young Jin KIM ,  James A. SIOSS ,  Tobias Maximilian TEUFL ,  Jordan K. LAMPERT

IPC: H01M4/525 ,  C01G53/00 ,  H01M4/505 ,  H01M4/62 ,  H01M10/0525

Abstract: Particulate material of the composition Li1+xTM1−xO2 wherein x is in the range of from 0.1 to 0.25 and TM is a combination of elements according to general formula (I) (NiaCobMnc)1−dM1d(I) wherein a is in the range of from 0.30 to 0.38, b being in the range of from zero to 0.05, c being in the range of from 0.60 to 0.70, and d being in the range of from zero to 0.05, M1 is selected from Al, Ti, Zr, Mo, Mg, B, and combinations of at least two of the foregoing, a+b+c=1, wherein said particulate material has an average particle diameter D50 in the range of from 2 to 20 μm and wherein said particulate material has a pressed density in the range of from 2.75 to 3.1 g/cm3.

公开(公告)号：US20180358615A1

公开(公告)日：2018-12-13

申请号：US15751308

申请日：2016-08-10

Applicant: BASF SE

Inventor： Simon SCHROEDLE ,  Thomas Michael RYLL ,  Aleksei VOLKOV ,  Ji-Yong SHIN ,  Jordan K. LAMPERT

IPC: H01M4/525 ,  H01M10/0525 ,  H01M4/505 ,  C01G53/00 ,  C01G53/04

Abstract: The present invention is directed towards a process for making a particulate material according to the general formula (I): NiaCObMncMd(O)x(OH)y, wherein M is selected from Al and Ti, x is in the range of from 0.01 to 0.9, y is in the range of from 1.1 to 1.99, a is in the range of from 0.3 to 0.85, b is in the range of from 0.05 to 0.4, c is in the range of from 0.1 to 0.5, d is in the range of from 0.001 to 0.03, with a+b+c+d=1 said process comprising the following steps: (a) providing an aqueous slurry of particles of aluminum hydroxide or titanium dioxide, (b) adding an aqueous solution of water-soluble salts of nickel, cobalt and manganese and a solution of alkali metal hydroxide to the slurry according to step (a), thereby co-precipitating a layer of a mixed hydroxide of nickel and cobalt and manganese hydroxide on the particles according to step (a), (c) removing particles of (NiaCObMncAld)(OH)2+d or (NiaCObMncTid)(OH)2+2d so obtained and drying them in the presence of oxygen.