公开(公告)号：US20210025070A1

公开(公告)日：2021-01-28

申请号：US17040642

申请日：2019-03-22

Applicant: BASF SE

Inventor： Katharina FRITZSCHE ,  Doris KREMZOW-GRAW ,  Marco ARNOLD ,  Alexander FLUEGEL

IPC: C25D3/32 ,  C25D3/46

Abstract: An aqueous composition comprising (a) metal ions comprising tin ions and silver ions and (b) at least one complexing agent of formula (C1) R1—X1—S—X21[D1-X22—]n—S—X3—R2, (C2) R1—X1—S—X31-D2-[X32—S—]nX3—R2, (C3) R3—X1—S—X41-[D3—X42—]nS—X3—R4 wherein X1, X3 are independently selected from a linear or branched C1-C12 alkanediyl, which may be unsubstituted or substituted by OH; X21, X22 are independently selected from X1, which may be further substituted by —X5—COOR12, —X5—SO2—O—R12, a C2 to C6 polyoxyalkylene group of formula —(O—CH2—CHR11)z—OH, or a combination thereof, and —X1—NH—CO—X6—CO—NH—X1—; X31, X32 are independently selected from a chemical bond and X1; X41, X42 are independently selected from X1; X5 is a linear or branched Ci to C10 alkyl; X6 is selected from X1 and a divalent 5 or 6 membered aromatic group; R1, R2 are independently selected from a monovalent 5 or 6 membered aromatic N-heterocyclic group comprising one N atom or two N atoms which are separated by at least one C atom, and its derivatives received by N-alkylation with a C1-C6-alkyl group, which may be substituted by —COOR12 or —SO2—O—R12, and which aromatic N-heterocyclic group may optionally further comprise, under the proviso that X21 is substituted by at least one OH, one S atom; R3, R4 are independently selected from a monovalent 5 or 6 membered aliphatic N-heterocyclic group comprising one N atom and one O atom; D1 is independently selected from S, O and NR10−; D2 is (a) a divalent 5 or 6 membered aliphatic heterocyclic ring system comprising 1 or 2 S atoms, or (b) a 5 or 6 membered aromatic heterocyclic ring system comprising at least two N atoms and optionally one or two S atoms; D3 is independently selected from S and NR10−; n is an integer of from 0 to 5; z is an integer from 1 to 50; R10 is selected from H and a linear or branched C1-C12 alkyl; R11 is selected from H and a linear or branched C1 to C6 alkyl; and R12 is selected from R10 and a cation.

公开(公告)号：US20170369455A1

公开(公告)日：2017-12-28

申请号：US15535945

申请日：2015-12-18

Applicant: BASF SE

Inventor： Rolf ALLES ,  Katharina FRITZSCHE ,  Wolfgang PETER ,  Adalbert BRAIG

IPC: C07D251/24 ,  C09D7/12 ,  C09D5/32 ,  C09K15/30 ,  C08K5/3492

CPC classification number: C07D251/24 ,  C08K5/3492 ,  C09D5/32 ,  C09D7/48 ,  C09K15/30

Abstract: A coating composition, which contains one or more compounds (A) according to formula (I) and a pigment (B) having a minimum integrated transmittance within the range of 380 to 600 nm, is provided: In formula (I), each R1, R2 and R3 is independently —OR4, R4 being independently hydrogen or a C1 to C24 hydrocarbyl group optionally containing heteroatoms, or C1 to C24 hydrocarbyl groups optionally containing heteroatoms; n is 2, 3, 4 or 5; o is 2, 3, 4 or 5; p is 2, 3, 4 or 5; with the proviso that at least one of R1 and at least one of R2 and at least one of R3 is —OR4. A coating is obtained by applying the coating composition to a substrate for protecting the substrate against UV/Vis-radiation or for stabilizing the substrate against the deleterious influence of UV/Vis-radiation.