公开(公告)号：US20160050923A1

公开(公告)日：2016-02-25

申请号：US14784126

申请日：2014-04-15

Applicant: BASF SE

Inventor： Nina Gertrud BANDUR ,  Martin John MCLAUGHLIN ,  Matthias POHLMAN

IPC: A01N43/40 ,  C07D401/06 ,  A01N43/54 ,  A01N43/56 ,  A01N43/78 ,  C07D413/06 ,  A01N43/80 ,  C07D405/06 ,  C07D213/75 ,  C07D417/06

CPC classification number: A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/78 ,  A01N43/80 ,  C07D213/75 ,  C07D401/06 ,  C07D405/06 ,  C07D413/04 ,  C07D413/06 ,  C07D417/06

Abstract: The invention relates to N-substituted acyl-imino-pyridine compounds of formula (I), to the enantiomers, diastereomers and salts thereof and to compositions comprising such compounds. The invention also relates to methods and uses of these N-substituted acyl-imino-pyridine compounds, and of compositions comprising thereof, for combating and controlling animal pests. Furthermore the invention relates also to pesticidal methods of applying such N-substituted acyl-imino-pyridine compounds.The N-substituted acyl-imino-pyridine compounds of the present invention are defined by the following formula I: wherein p, X, Y, W1, W2, W3, W4, Het, R1, R2, R3a, R3b, R4a, R4b and R5 are defined as in the description.

Abstract translation: 本发明涉及式（I）的N-取代酰基 - 亚氨基 - 吡啶化合物，其涉及其对映体，非对映异构体和盐以及包含这些化合物的组合物。 本发明还涉及这些N-取代的酰基 - 亚氨基 - 吡啶化合物及其组合物的方法和用途，用于对抗和控制动物害虫。 此外，本发明还涉及施用这种N-取代的酰基 - 亚氨基 - 吡啶化合物的杀虫方法。 本发明的N-取代酰基亚氨基 - 吡啶化合物由下式I定义：其中p，X，Y，W1，W2，W3，W4，Het，R1，R2，R3a，R3b，R4a，R4b 和R5如说明书中所定义。

公开(公告)号：US20160235069A1

公开(公告)日：2016-08-18

申请号：US15023176

申请日：2014-09-19

Applicant: BASF SE

Inventor： Nina Gertrud BANDUR ,  Martin John MCLAUGHLIN ,  Matthias POHLMAN ,  Jochen DIETZ ,  Wolfgang VON DEYN

IPC: A01N55/00 ,  A01N43/40 ,  A01N43/78 ,  A01N43/56 ,  C07F7/18 ,  C07D417/06 ,  C07D401/06 ,  C07D405/06

CPC classification number: A01N55/00 ,  A01N43/40 ,  A01N43/56 ,  A01N43/78 ,  A01N43/80 ,  C07D401/06 ,  C07D401/14 ,  C07D405/06 ,  C07D405/14 ,  C07D409/14 ,  C07D413/06 ,  C07D417/06 ,  C07D471/04 ,  C07F7/18

Abstract: The present invention relates to N-acrylimino compound of formula (I): wherein X is O or S, in particular O; Het is a 5- or 6-membered carbon-bound or nitrogen-bound heterocyclic ring, W1-W2-W3-W4 represents a carbon chain group connected to N and C═N, and thus forming a saturated, unsaturated, or partially unsaturated 5 or 6 membered nitrogen containing heterocycle, wherein W1, W2, W3 and W4 each individually represent CRvRw, R1, R2 may be hydrogen, halogen, etc. R3 is selected from the group consisting of hydrogen, halogen, CN, C1-C6-alkyl, etc. R4 is selected from the group consisting of hydrogen, halogen, CN, C1-C10-alkyl, etc. R5 is selected from the group consisting of hydrogen CN, C1-C10-alkyl, C2-C10-alkenyl C3-C8-cycloalkyl, S(O)nNR9aR9b, O—NR9aR9b, NR9aR9b, NR9a NR9aR9b, NR9aC(═O)R7a, NR9aC(═S)R7a, NR9aC(═O)NR9aR9b, NR9aC(═S)NR9aR9b, C(═O)OR8, C(═O)NR9aR9b, C(═S)NR9aR9b, C(═O)R7a, C(═S)R7a, a moitey Q-phenyl, where the phenyl ring is optionally substituted with 1, 2, 3, 4 or 5 identical or different substituents R10, and a moiety Q-Het# where Het# represents a 3- to 10-membered saturated, partly saturated or unsaturated aromatic heterocyclic ring. The invention also relates to the use of the N-acrylimino heterocyclic compounds, their stereoisomers, their tautomers and their salts, for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.

Abstract translation: 本发明涉及式（I）的N-丙烯酰亚氨基化合物：其中X是O或S，特别是O; Het是5或6元碳键或氮键合的杂环，W1-W2-W3-W4表示与N和C = N连接的碳链基团，因此形成饱和的，不饱和的或部分不饱和的 5或6元含氮杂环，其中W1，W2，W3和W4各自独立地表示CRvRw，R1，R2可以是氢，卤素等。R3选自氢，卤素，CN，C1-C6- 烷基等.R 4选自氢，卤素，CN，C 1 -C 10 - 烷基等。R 5选自氢CN，C 1 -C 10 - 烷基，C 2 -C 10 - 烯基C3- C 9 - 环烷基，S（O）n NR 9 a R 9 b，O-NR 9 a R 9 b，NR 9 a R 9 b，NR 9 a NR 9 a R 9 b，NR 9 a C（= O）R 7a，NR 9 a C（≡S）R 7a，NR 9 a C（≡O）NR 9 a R 9 b，NR 9 a C（≡S）NR 9 a R 9 b，C O）OR 8，C（= O）NR 9 a R 9 b，C（= S）NR 9 a R 9 b，C（= O）R 7a，C（= O）R 7a，其中苯环任选被1,2， 3,4或5个相同或不同的取代基R10，和其中Het＃表示a的部分Q-Het＃ 3-至10-元饱和，部分饱和或不饱和的芳族杂环。 本发明还涉及N-丙烯酰胺杂环化合物，其立体异构体，其互变异构体及其盐的用途，用于对抗无脊椎动物害虫。 此外，本发明还涉及防治无脊椎害虫的方法，其包括施用这样的化合物。

公开(公告)号：US20190382362A1

公开(公告)日：2019-12-19

申请号：US16480407

申请日：2018-01-16

Applicant: BASF SE

Inventor： Martin John MCLAUGHLIN ,  Karsten KOERBER ,  Birgit GOCKEL ,  Devendra VYAS ,  Arun NARINE

IPC: C07D307/79

Abstract: The present invention relates to a process for preparing benzylic amides of formula I wherein the variables have the meaning as defined in the description, by reductive amidation of a nitrile of formula II wherein the variables have the meanings given for formula I, with an activated carbonyl compound of formula III, and which nitrile is obtained by reaction of a compound of formula IV with a halogen compound of formula V, wherein X is a halogen atom, preferably bromo, which halogen compound V in turn is obtained by Sandmeyer reaction of an aniline derivative of formula VI novel compounds of formula I, and processes for preparing compounds of formula XII wherein the variables have the meaning as defined in the description by condensing compounds of formula I with compounds of formula X and subjecting the resulting α,β-unsaturated ketone of formula XI to a reaction with hydroxylamine to yield compounds of formula XII.

公开(公告)号：US20190142004A1

公开(公告)日：2019-05-16

申请号：US16245471

申请日：2019-01-11

Applicant: BASF SE

Inventor： Martin John MCLAUGHLIN ,  Nina Gertrud BANDUR ,  Matthias POHLMAN ,  Jochen DIETZ ,  Wolfgang VON DEYN

IPC: A01N43/40 ,  C07D417/14 ,  C07D401/14 ,  A01N53/00 ,  A01N43/78 ,  C07D405/14 ,  C07D417/06 ,  C07D405/06 ,  C07D401/06 ,  A01N43/54

Abstract: The present invention relates to N-acylimino compound of formula (I): wherein X is O or S, in particular O; m is an integer selected from 0, 1, 2, 3, 4, 5 or 6; Het is a 5 or 6 membered carbon-bound or nitrogen-bound heterocyclic ring, W1-W2-W3-W4 represents a carbon chain group connected to N and C═N, and thus forming a saturated, unsaturated, or partially unsaturated 5 or 6 membered nitrogen containing heterocycle, wherein W1, W2, W3 and W4 each individually represent CRvRw, R1, R2 may be hydrogen, halogen, etc. R3 may be hydrogen, halogen, CN, C1-C6-alkyl, etc. R4a, R4b if present, may be hydrogen, halogen, C1-C6-alkyl, etc. R5 may be hydrogen, halogen, C1-C6-alkyl, C1-C6-alkenyl, C1-C6-alkinyl, C3-C8-cycloalkyl, S(O)nNR9aR9b, NR9aR9b, C(═O)OR8, C(═O)NR9aR9b, C(═S)NR9aR9b, C(═O)R7a, C(═S)R7a, NR9a—C(═O)R7a, NR9a—C(═S)R7a, NR9a—S(O)nR8a, a moitey Q-phenyl, where the phenyl ring is optionally substituted with one or more, e.g. 1, 2, 3, 4 or 5 identical or different substituents R10, or a moiety Q-Het#, or R3 and R5 together may also form with the carbon atom they are bound to, a 3, 4, 5 or 6 membered saturated partially unsaturated carbocycle or heterocycle. The invention also relates to the use of the N-acylimino heterocyclic compounds, their stereoisomers, their tautomers and their salts, for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.

公开(公告)号：US20200165255A1

公开(公告)日：2020-05-28

申请号：US16612111

申请日：2018-05-07

Applicant: BASF SE

Inventor： Martin John MCLAUGHLIN ,  Arun NARINE ,  Wolfgang VON DEYN ,  Birgit GOCKEL

IPC: C07D487/04 ,  A01N43/90

Abstract: The present invention relates to compounds of formula I, wherein the variables are defined as given in the description and claims. The invention further relates to uses, processes and composition for compounds I.

公开(公告)号：US20190308920A1

公开(公告)日：2019-10-10

申请号：US16315417

申请日：2017-06-23

Applicant: BASF SE

Inventor： Martin John MCLAUGHLIN ,  Karsten KOERBER ,  Birgit GOCKEL ,  Pascal BINDSCHAEDLER ,  Sebastian SOERGEL ,  Devendra VYAS ,  Johannes ROECKL

IPC: C07C33/48 ,  C07C49/813 ,  C07C25/24 ,  C07C63/74 ,  C07C17/263 ,  C07C45/51

Abstract: Compounds of formula I a process for preparation of compounds of formula I; precursor compounds of formula II a process for preparation of precursor compounds of formula II; compounds of formula III a process for the preparation of compounds of formula IV from compounds of formula III and the use of compounds of formula I for the preparation of compounds of formula IV.

公开(公告)号：US20160326153A1

公开(公告)日：2016-11-10

申请号：US15105239

申请日：2014-12-17

Applicant: BASF SE

Inventor： Karsten KÖRBER ,  Martin John MCLAUGHLIN ,  Birgit GOCKEL ,  Wolfgang VON DEYN ,  Jochen DIETZ ,  Matthias POHLMAN

IPC: C07D417/06 ,  A01N43/40 ,  A01N43/78 ,  C07D213/76

CPC classification number: C07D417/06 ,  A01N43/40 ,  A01N43/78 ,  C07D213/76 ,  C07D401/06 ,  C07D405/06 ,  C07D413/06

Abstract: The present invention relates to N-substituted imino compound of formula (I): wherein Y is a radical Y1, Y2, Y3, Y4 or Y5, where Y1 is O—C(═X)—R3; Y2 is S—C(═X)—R3; Y3 is N(R5)—C(═X)—R3; Y4 is N(R5)—S(═O)—R4; Y5 is N(R5)—S(═O)2—R4; and where X is O or S; Het is a 5 or 6 membered carbon-bound or nitrogen-bound heterocyclic ring, W1—W2—W3—W4 represents a carbon chain group connected to N and C═N, and thus forming a saturated, unsaturated, or partially unsaturated 5 or 6 membered nitrogen containing heterocycle, wherein W1, W2, W3 and W4 each individually represent CRvRw; R1, R2 may be hydrogen, halogen, C1-C6-alkyl etc.; and where R3, R4 and R5 are as defined herein. The invention also relates to the use of the N-acylimino heterocyclic compounds, their stereoisomers, their tautomers and their salts, for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.

Abstract translation: 本发明还涉及N-酰基亚氨基杂环化合物，其立体异构体，其互变异构体及其盐的用途，用于防治无脊椎动物害虫。 此外，本发明还涉及防治无脊椎害虫的方法，其包括施用这样的化合物。

公开(公告)号：US20160297793A1

公开(公告)日：2016-10-13

申请号：US15038272

申请日：2014-11-21

Applicant: BASF SE

Inventor： Nina Gertrud BANDUR ,  Jochen DIETZ ,  Matthias POHLMAN ,  Martin John MCLAUGHLIN ,  Birgit GOCKEL ,  Karsten Körber ,  Wolfgang VON DEYN

IPC: C07D401/06 ,  C07D405/06 ,  C07D417/06 ,  A01N43/78 ,  A01N47/10 ,  A01N43/60 ,  C07D401/14 ,  C07D405/14 ,  C07D413/14 ,  A01N43/80 ,  A01N43/54 ,  C07D409/14 ,  A01N43/40 ,  A01N43/84

CPC classification number: C07D401/06 ,  A01N43/40 ,  A01N43/54 ,  A01N43/60 ,  A01N43/78 ,  A01N43/80 ,  A01N43/84 ,  A01N47/10 ,  C07D401/14 ,  C07D405/06 ,  C07D405/14 ,  C07D409/14 ,  C07D413/14 ,  C07D417/06 ,  C07D417/14 ,  C07D419/14

Abstract: The present invention relates to N-acylimino compound of formula (I): wherein X is O or S, in particular O; Y is a single bond, O, S or NR5; Het is a 5 or 6 membered carbon-bound or nitrogen-bound heterocyclic ring, W1—W2—W3—W4 represents a carbon chain group connected to N and C═N, and thus forming a saturated, unsaturated, or partially unsaturated 5 or 6 membered nitrogen containing heterocycle, wherein W1, W2, W3 and W4 each individually represent CRvRw; R1, R2 may be hydrogen, halogen, etc.; R3 may be hydrogen, CN, C1-C6-alkyl, etc.; R4 may be of hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C8-cycloalkyl, Q-phenyl, Q′-O-phenyl, Q′-S-phenyl, where the phenyl ring is optionally substituted with one or more, e.g. 1, 2, 3, 4 or 5 identical or different substituents R10, and the moieties Q-Het#, Q′-O-Het# and Q′-S-Het# where Het# represents a heterocyclic radical and where Q and Q′ are C1-C6-alkandiyl, C2-C6-alkendiyl, or C2-C6-alkyndiyl, and where Q may also be a single bond; R3 and R4 together may also may also a bivalent radical, selected from the group consisting of C2-C5-alkandiyl, C2-C5-alkendiyl, Q″-C1-C4-alkandiyl and Q″-C2-C4-alkendiyl, where Q″ is O or S. The invention also relates to the use of the N-acylimino heterocyclic compounds, their stereoisomers, their tautomers and their salts, for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.

Abstract translation: 本发明还涉及N-酰基亚氨基杂环化合物，其立体异构体，其互变异构体及其盐的用途，用于防治无脊椎动物害虫。 此外，本发明还涉及防治无脊椎害虫的方法，其包括施用这样的化合物。

公开(公告)号：US20160227777A1

公开(公告)日：2016-08-11

申请号：US15023128

申请日：2014-09-18

Applicant: BASF SE

Inventor： Martin John MCLAUGHLIN ,  Nina Gertrud BANDUR ,  Matthias POHLMAN ,  Jochen DIETZ ,  Wolfgang VON DEYN

IPC: A01N43/40 ,  A01N53/00 ,  C07D417/06 ,  C07D417/14 ,  C07D405/06 ,  A01N43/54 ,  C07D405/14 ,  C07D401/14 ,  C07D401/06 ,  A01N43/78

CPC classification number: A01N43/40 ,  A01N43/54 ,  A01N43/78 ,  A01N53/00 ,  C07D401/06 ,  C07D401/14 ,  C07D405/06 ,  C07D405/14 ,  C07D417/06 ,  C07D417/14

Abstract: The present invention relates to N-acylimino compound of formula (I): wherein X is O or S, in particular O; m is an integer selected from 0, 1, 2, 3, 4, 5 or 6; Het is a 5 or 6 membered carbon-bound or nitrogen-bound heterocyclic ring, W1-W2-W3-W4 represents a carbon chain group connected to N and C═N, and thus forming a saturated, unsaturated, or partially unsaturated 5 or 6 membered nitrogen containing heterocycle, wherein W1, W2, W3 and W4 each individually represent CRvRw, R1, R2 may be hydrogen, halogen, etc. R3 may be hydrogen, halogen, CN, C1-C6-alkyl, etc. R4a, R4b if present, may be hydrogen, halogen, C1-C6-alkyl, etc. R5 may be hydrogen, halogen, C1-C6-alkyl, C1-C6-alkenyl, C1-C6-alkinyl, C3-C8-cycloalkyl, S(O)nNR9aR9b, NR9aR9b, C(═O)OR8, C(═O)NR9aR9b, C(═S)NR9aR9b, C(═O)R7a, C(═S)R7a, NR9a—C(═O)R7a, NR9a—C(═S)R7a, NR9a—S(O)nR8a, a moiety Q-phenyl, where the phenyl ring is optionally substituted with one or more, e.g. 1, 2, 3, 4 or 5 identical or different substituents R10, or a moiety Q-Het#, or R3 and R5 together may also form with the carbon atom they are bound to, a 3, 4, 5 or 6 membered saturated partially unsaturated carbocycle or heterocycle. The invention also relates to the use of the N-acylimino heterocyclic compounds, their stereoisomers, their tautomers and their salts, for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.

Abstract translation: 本发明涉及式（I）的N-酰基亚胺基化合物：其中X是O或S，特别是O; m为选自0,1,2,3,4,5或6的整数; Het是5或6元碳键或氮键的杂环，W1-W2-W3-W4表示与N和C = N连接的碳链基团，从而形成饱和的，不饱和的或部分不饱和的5或 6元含氮杂环，其中W1，W2，W3和W4各自独立地表示CRvRw，R1，R2可以是氢，卤素等。R3可以是氢，卤素，CN，C1-C6-烷基等。R4a，R4b R 5可以是氢，卤素，C 1 -C 6 - 烷基，C 1 -C 6 - 烯基，C 1 -C 6 - 炔基，C 3 -C 8 - 环烷基，S（ O（n）NR 9a R 9 b，C（= O）OR 8，C（= O）NR 9 a R 9 b，C（= S）NR 9 a R 9 b，C（= O） NR9a-C（= S）R7a，NR9a-S（O）nR8a，部分Q-苯基，其中苯环任选被一个或多个例如 1,2,3或4或5个相同或不同的取代基R10或部分Q-Het＃，或R3和R5一起也可以与它们所键合的碳原子一起形成，3,4,5或6元饱和 部分不饱和碳环或杂环。 本发明还涉及N-酰基亚氨基杂环化合物，其立体异构体，其互变异构体及其盐的用途，用于防治无脊椎动物害虫。 此外，本发明还涉及防治无脊椎害虫的方法，其包括施用这样的化合物。