公开(公告)号：US20160126022A1

公开(公告)日：2016-05-05

申请号：US14992761

申请日：2016-01-11

申请人： BASF SE

发明人： Ingmar Bruder ,  Robert Send ,  Simona Urnikaite ,  Tadas Malinauskas ,  Maryte Daskeviciene ,  Vytautas Getautis

IPC分类号： H01G9/20 ,  C07D417/12 ,  C09B26/02 ,  C07D277/36

CPC分类号： H01G9/2059 ,  C07D277/36 ,  C07D417/12 ,  C09B26/02 ,  H01G9/2031 ,  H01L51/0059 ,  Y02E10/542 ,  Y02E10/549

摘要： The present invention relates to compounds of general formula I wherein R100 and R200 are each independently hydrogen, C1-C10-alkyl which in case of C2-alkyl may be interrupted by one and in case of C3-C10-alkyl by one or two non-adjacent oxygen atoms, C5-C7-cycloalkyl, aryl, aryl-C1-C10-alkyl or aryloxy-C1-C10-alkyl, D is an m-valent (m=1, 2 or 3) donor moiety which comprises at least one carbon-carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, A is an acceptor moiety which comprises at least one carbon-carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, and the donor moiety D and the acceptor moiety A are π-conjugated to one another.Furthermore, the present invention relates to the use of compounds of formula I for producing dye-sensitized solar cells and to dye-sensitized solar cells comprising compounds of formula I.

摘要翻译： 本发明涉及通式Ⅰ的化合物，其中R100和R200各自独立地为氢，在C2-烷基的情况下，C1-C10-烷基可以被一个间隔并且在C3-C10-烷基的情况下被一个或两个非 - 相邻的氧原子，C 5 -C 7 - 环烷基，芳基，芳基-C 1 -C 10 - 烷基或芳氧基-C 1 -C 10烷基，D是至少包含至少一个m价（m = 1,2或3） 一个碳 - 碳或碳 - 杂原子双键和/或至少一个未融合或稠合的碳 - 或杂环，A是包含至少一个碳 - 碳或碳 - 杂原子双键的受体部分和/或至少一个 未稠合或稠合的碳环或杂环，并且供体部分D和受体部分A彼此共轭。 此外，本发明涉及式I化合物用于生产染料敏化太阳能电池的用途以及包含式I化合物的染料敏化太阳能电池的用途。

公开(公告)号：US09831042B2

公开(公告)日：2017-11-28

申请号：US14992761

申请日：2016-01-11

申请人： BASF SE

发明人： Ingmar Bruder ,  Robert Send ,  Simona Urnikaite ,  Tadas Malinauskas ,  Maryte Daskeviciene ,  Vytautas Getautis

IPC分类号： C07D277/36 ,  H01G9/20 ,  H01L51/00 ,  C09B26/02 ,  C07D417/12

CPC分类号： H01G9/2059 ,  C07D277/36 ,  C07D417/12 ,  C09B26/02 ,  H01G9/2031 ,  H01L51/0059 ,  Y02E10/542 ,  Y02E10/549

摘要： The present invention relates to compounds of general formula I wherein R100 and R200 are each independently hydrogen, C1-C10-alkyl which in case of C2-alkyl may be interrupted by one and in case of C3-C10-alkyl by one or two nonadjacent oxygen atoms, C5-C7-cycloalkyl, aryl, aryl-C1-C10-alkyl or aryloxy-C1-C10-alkyl, D is an m-valent (m=1, 2 or 3) donor moiety which comprises at least one carbon-carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, A is an acceptor moiety which comprises at least one carbon-carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, and the donor moiety D and the acceptor moiety A are π-conjugated to one another. Furthermore, the present invention relates to the use of compounds of formula I for producing dye-sensitized solar cells and to dye-sensitized solar cells comprising compounds of formula I.

公开(公告)号：US20140012002A1

公开(公告)日：2014-01-09

申请号：US13932403

申请日：2013-07-01

申请人： BASF SE

发明人： Ingmar BRUDER ,  Robert Send ,  Simona Urnikaite ,  Tadas Malinauskas ,  Maryte Daskeviciene ,  Vytautas Getautis

IPC分类号： H01G9/20

CPC分类号： H01G9/2059 ,  C07D277/36 ,  C07D417/12 ,  C09B26/02 ,  H01G9/2031 ,  H01L51/0059 ,  Y02E10/542 ,  Y02E10/549

摘要： The present invention relates to compounds of general formula I wherein R100 and R200 are each independently hydrogen, C1-C10-alkyl which in case of C2-alkyl may be interrupted by one and in case of C3-C10-alkyl by one or two nonadjacent oxygen atoms, C5-C7-cycloalkyl, aryl, aryl-C1-C10-alkyl or aryloxy-C1-C10-alkyl, D is an m-valent (m=1, 2 or 3) donor moiety which comprises at least one carbon-carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, A is an acceptor moiety which comprises at least one carbon-carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, and the donor moiety D and the acceptor moiety A are π-conjugated to one another.Furthermore, the present invention relates to the use of compounds of formula I for producing dye-sensitized solar cells and to dye-sensitized solar cells comprising compounds of formula I.

摘要翻译： 本发明涉及通式Ⅰ的化合物，其中R100和R200各自独立地为氢，在C2-烷基的情况下可以被一个间隔的C 1 -C 10 - 烷基和在C 3 -C 10 - 烷基的情况下被一个或两个不相邻的 氧原子，C 5 -C 7 - 环烷基，芳基，芳基-C 1 -C 10 - 烷基或芳氧基-C 1 -C 10 - 烷基，D是m价（m = 1,2或3）供体部分，其包含至少一个碳 碳或碳 - 杂原子双键和/或至少一个未融合或稠合的碳环或杂环，A是受体部分，其包含至少一个碳 - 碳或碳 - 杂原子双键和/或至少一个未被融合或 融合的碳环或杂环，并且供体部分D和受体部分A彼此结合。 此外，本发明涉及式I化合物用于生产染料敏化太阳能电池的用途以及包含式I化合物的染料敏化太阳能电池的用途。

公开(公告)号：US20140066656A1

公开(公告)日：2014-03-06

申请号：US14016514

申请日：2013-09-03

申请人： BASF SE

发明人： Ingmar BRUDER ,  Ruediger Sens ,  Robert Send ,  Henrike Wonneberger ,  Hermann Bergmann ,  Vytautas Getautis ,  Maryte Daskeviciene ,  Tadas Malinauskas ,  Daiva Tomkute-Luksiene

IPC分类号： H01L51/00

CPC分类号： H01L51/006 ,  H01L51/5056 ,  Y02E10/549

摘要： The present invention relates 9,9′-spirobifluorene compounds of general formula I wherein the variables R11, R12, R21, R22, R31, R32, R41 and R42 independently of each other have the meaning of aryl or hetaryl, with the proviso that not all of the radicals R11, R12, R21, R22, R31, R32, R41 and R42 are identical, to the use of compounds of general formula I in organic electronics applications, especially in organic field effect transistors, in organic photodetectors and organic solar cells, specifically in dye-sensitized solar cells and bulk heterojunction solar cells, and to an organic field effect transistor, a dye-sensitized solar cell and a bulk heterojunction solar cell comprising compounds of general formula I.

摘要翻译： 本发明涉及通式I的9,9'-螺二芴化合物，其中变量R11，R12，R21，R22，R31，R32，R41和R42彼此独立地具有芳基或杂芳基的含义，条件是不 所有基团R11，R12，R21，R22，R31，R32，R41和R42与有机电子应用中的通式I化合物的使用相同，特别是在有机光电探测器和有机太阳能电池中的有机场效应晶体管中 ，特别是在染料敏化太阳能电池和本体异质结太阳能电池中，以及有机场效应晶体管，染料敏化太阳能电池和包含通式I化合物的本体异质结太阳能电池。