公开(公告)号：US09428518B2

公开(公告)日：2016-08-30

申请号：US14772488

申请日：2014-03-12

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Henrike Wonneberger ,  Neil Gregory Pschirer ,  Flavio Luiz Benedito ,  Ingmar Bruder ,  Robert Send ,  Yulian Zagranyarski ,  Chen Li ,  Klaus Muellen ,  Long Chen ,  Artem Nikolaevich Skabeev

IPC: C07D471/08 ,  C07D493/08 ,  H01L51/42 ,  C07D491/06 ,  H01L51/00 ,  C07D221/04 ,  C07D471/06 ,  C07D493/06 ,  C07D495/06 ,  C09B5/62 ,  H01G9/20

CPC classification number: C07D491/06 ,  C07D221/04 ,  C07D471/06 ,  C07D493/06 ,  C07D495/06 ,  C09B5/62 ,  C09B57/08 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0053 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/4226 ,  Y02E10/542 ,  Y02E10/549 ,  Y02P70/521

Abstract: A sensitizer in a dye-sensitized solar cell, including a compound of formula (I′) where: R1 and R2 are hydrogen, a halogen, an alkyl group, a cycloalkyl group, an aryl group, a hetaryl group, an alkoxy group, an aryloxy group, an arylthio group, a hetaryloxy group, a hetarylthio group, a diarylamino group, or a dialkylamino group; m, n are each independently an integer from 0-4; X is sulfur, oxygen, or NR3, where R3 is hydrogen, an alkyl group, a cycloalkyl group, an aryl group, or a hetaryl group; Y1 is oxygen or N—Z-A, where A is —COOM, —SO3M, or —PO3M, where M is hydrogen, an alkali metal cation, or [NR′]4+, where each R′ is independently hydrogen or an alkyl group, and where Z is C1-C6-alkylene or 1,4-phenylene, where the phenylene radical is optionally substituted by one or more alkyl, nitro, cyano, and halogen substituents.

Abstract translation: 染料敏化太阳能电池中的敏化剂，包括式（I'）化合物，其中：R1和R2是氢，卤素，烷基，环烷基，芳基，杂芳基，烷氧基， 芳氧基，芳硫基，杂芳氧基，杂芳硫基，二芳基氨基或二烷基氨基; m，n各自独立地为0-4的整数; X是硫，氧或NR 3，其中R 3是氢，烷基，环烷基，芳基或杂芳基; Y1是氧或N-ZA，其中A是-COOM，-SO3M或-PO3M，其中M是氢，碱金属阳离子或[NR'] 4+，其中每个R'独立地是氢或烷基 并且其中Z是C 1 -C 6亚烷基或1,4-亚苯基，其中亚苯基任选被一个或多个烷基，硝基，氰基和卤素取代基取代。

公开(公告)号：US09054325B2

公开(公告)日：2015-06-09

申请号：US13762764

申请日：2013-02-08

Applicant: BASF SE

Inventor： Flavio Luiz Benedito ,  Ingmar Bruder ,  Peter Erk ,  Neil Gregory Pschirer ,  Robert Send ,  Klaus Muellen ,  Henrike Wonneberger ,  Chen Li

IPC: F21V9/00 ,  G02B5/02 ,  G02C7/10 ,  G02F1/361 ,  G03B11/00 ,  H01L51/44 ,  H01G9/20 ,  H01L51/00 ,  C09B67/00 ,  H01C13/00 ,  H01L51/42

CPC classification number: H01L51/44 ,  C09B5/62 ,  C09B57/001 ,  C09B57/08 ,  H01G9/2059 ,  H01L51/0053 ,  H01L51/0061 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/4226 ,  Y02E10/542 ,  Y02E10/549

Abstract: Thin layers or films of metal oxides are used as a semiconductor material of solar cells and they are coated with a sensitizer to achieve the high absorption of sunlight. Various dyes have been used as sensitizers in solar cells. Rylene monoimide derivatives are developed as photosensitizers for dye-sensitized solar cells and as photodetectors. The Rylene monoimide derivatives have very good quantum efficiencies, particularly in the NIR region of the absorption spectrum.

Abstract translation: 金属氧化物的薄层或薄膜用作太阳能电池的半导体材料，并且用敏化剂涂覆以实现太阳光的高吸收。 各种染料已被用作太阳能电池中的敏化剂。 Rylene单酰亚胺衍生物作为染料敏化太阳能电池的光敏剂和光电探测器开发。 Rylene单酰亚胺衍生物具有非常好的量子效率，特别是在吸收光谱的NIR区域。

公开(公告)号：US20140039193A1

公开(公告)日：2014-02-06

申请号：US13958934

申请日：2013-08-05

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerd. der Wisse. e.V.

Inventor： Henrike Wonneberger ,  Ingmar Bruder ,  Robert Send ,  Glauco Battagliarin ,  Chen Li ,  Klaus Muellen

IPC: H01G9/20

CPC classification number: H01G9/2059 ,  C07D221/18 ,  C07F5/04 ,  C09B5/62 ,  H01G9/2031 ,  H01L51/0053 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/008 ,  Y02B10/10 ,  Y02E10/542 ,  Y02E10/549

Abstract: Boron-comprising perylene monoimides and a process for producing the boron-comprising perylene monoimides are provided. The boron-comprising perylene monoimides are useful as building blocks for producing perylene monoimide derivatives and monoimide derivatives. The boron-comprising perylene monoimides are also useful for preparing dye-sensitized solar cells.

Abstract translation: 提供了含硼的苝单酰亚胺和制备含硼的苝单酰亚胺的方法。 含硼的苝单酰亚胺可用作生产苝单酰亚胺衍生物和单酰亚胺衍生物的结构单元。 含硼的苝单酰亚胺也可用于制备染料敏化太阳能电池。

公开(公告)号：US10353049B2

公开(公告)日：2019-07-16

申请号：US14897981

申请日：2014-06-05

Applicant: BASF SE

Inventor： Henrike Wonneberger ,  Ingmar Bruder ,  Erwin Thiel ,  Robert Send ,  Stephan Irle

IPC: G01C3/08 ,  G01S5/16 ,  G01C3/32 ,  G01S17/46 ,  G01S7/481 ,  G01S17/66

Abstract: A detector device (111) for determining an orientation of at least one object (112) is disclosed. The detector device comprises: at least two beacon devices (204), the beacon devices (204) being adapted to be at least one of attached to the object (112), held by the object (112) and integrated into the object (112), the beacon devices (204) each being adapted to direct light beams (138) towards a detector (110), the beacon devices (204) having predetermined coordinates in a coordinate system of the object (112); at least one detector (110) adapted to detect the light beams (138) traveling from the beacon devices (204) towards the detector (110); at least one evaluation device (142), the evaluation device (142) being adapted to determine longitudinal coordinates of each of the beacon devices (204) in a coordinate system of the detector (110), the evaluation device (142) being further adapted to determine an orientation of the object (112) in the coordinate system of the detector (110) by using the longitudinal coordinates of the beacon devices (204).

公开(公告)号：US09624375B2

公开(公告)日：2017-04-18

申请号：US14746113

申请日：2015-06-22

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerd. der Wisse e.V.

Inventor： Henrike Wonneberger ,  Ingmar Bruder ,  Robert Send ,  Glauco Battagliarin ,  Chen Li ,  Klaus Muellen

IPC: C07D221/18 ,  C07D311/78 ,  H01L31/00 ,  C09B5/62 ,  H01G9/20 ,  H01L51/00 ,  C07F5/04

CPC classification number: H01G9/2059 ,  C07D221/18 ,  C07F5/04 ,  C09B5/62 ,  H01G9/2031 ,  H01L51/0053 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/008 ,  Y02B10/10 ,  Y02E10/542 ,  Y02E10/549

Abstract: Boron-comprising perylene monoimides and a process for producing the boron-comprising perylene monoimides are provided. The boron-comprising perylene monoimides are useful as building blocks for producing perylene monoimide derivatives and monoimide derivatives. The boron-comprising perylene monoimides are also useful for preparing dye-sensitized solar cells.

公开(公告)号：US20140291480A1

公开(公告)日：2014-10-02

申请号：US14132570

申请日：2013-12-18

Applicant: BASF SE

Inventor： Ingmar BRUDER ,  Simone Christina Spiller ,  Erwin Thiel ,  Stephan Irle ,  Robert Send ,  Henrike Wonneberger

IPC: G01B11/14

CPC classification number: G01S17/89 ,  G01C3/06 ,  G01S3/781 ,  G01S3/786 ,  G01S7/4816 ,  G01S17/46 ,  G01S17/66

Abstract: A detector (110) for determining a position of at least one object (112) is proposed. The detector (110) comprises: at least one transversal optical sensor (130), the transversal optical sensor (130) being adapted to determine a transversal position of at least one light beam (138) traveling from the object (112) to the detector (110), the transversal position being a position in at least one dimension perpendicular to an optical axis (116) of the detector (110), the transversal optical sensor (130) being adapted to generate at least one transversal sensor signal; at least one longitudinal optical sensor (132), wherein the longitudinal optical sensor (132) has at least one sensor region (136), wherein the longitudinal optical sensor (132) is designed to generate at least one longitudinal sensor signal in a manner dependent on an illumination of the sensor region (136) by the light beam (138), wherein the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam (138) in the sensor region (136); at least one evaluation device (142), wherein the evaluation device (142) is designed to generate at least one item of information on a transversal position of the object (112) by evaluating the transversal sensor signal and to generate at least one item of information on a longitudinal position of the object (112) by evaluating the longitudinal sensor signal.

Abstract translation: 提出了一种用于确定至少一个物体（112）的位置的检测器（110）。 检测器（110）包括：至少一个横向光学传感器（130），横向光学传感器（130）适于确定从物体（112）行进到检测器的至少一个光束（138）的横向位置 （110），所述横向位置是垂直于所述检测器（110）的光轴（116）的至少一个维度的位置，所述横向光学传感器（130）适于产生至少一个横向传感器信号; 至少一个纵向光学传感器（132），其中所述纵向光学传感器（132）具有至少一个传感器区域（136），其中所述纵向光学传感器（132）被设计成以依赖的方式产生至少一个纵向传感器信号 在由光束（138）照射传感器区域（136）的情况下，给予相同的照明总功率的纵向传感器信号取决于光束（138）中的光束横截面 传感器区域（136）; 至少一个评估装置（142），其中所述评估装置（142）被设计成通过评估横向传感器信号来产生对象（112）的横向位置上的至少一个信息项，并且生成至少一个项目 通过评估纵向传感器信号对物体（112）的纵向位置的信息。

公开(公告)号：US20140066656A1

公开(公告)日：2014-03-06

申请号：US14016514

申请日：2013-09-03

Applicant: BASF SE

Inventor： Ingmar BRUDER ,  Ruediger Sens ,  Robert Send ,  Henrike Wonneberger ,  Hermann Bergmann ,  Vytautas Getautis ,  Maryte Daskeviciene ,  Tadas Malinauskas ,  Daiva Tomkute-Luksiene

IPC: H01L51/00

CPC classification number: H01L51/006 ,  H01L51/5056 ,  Y02E10/549

Abstract: The present invention relates 9,9′-spirobifluorene compounds of general formula I wherein the variables R11, R12, R21, R22, R31, R32, R41 and R42 independently of each other have the meaning of aryl or hetaryl, with the proviso that not all of the radicals R11, R12, R21, R22, R31, R32, R41 and R42 are identical, to the use of compounds of general formula I in organic electronics applications, especially in organic field effect transistors, in organic photodetectors and organic solar cells, specifically in dye-sensitized solar cells and bulk heterojunction solar cells, and to an organic field effect transistor, a dye-sensitized solar cell and a bulk heterojunction solar cell comprising compounds of general formula I.

Abstract translation: 本发明涉及通式I的9,9'-螺二芴化合物，其中变量R11，R12，R21，R22，R31，R32，R41和R42彼此独立地具有芳基或杂芳基的含义，条件是不 所有基团R11，R12，R21，R22，R31，R32，R41和R42与有机电子应用中的通式I化合物的使用相同，特别是在有机光电探测器和有机太阳能电池中的有机场效应晶体管中 ，特别是在染料敏化太阳能电池和本体异质结太阳能电池中，以及有机场效应晶体管，染料敏化太阳能电池和包含通式I化合物的本体异质结太阳能电池。

公开(公告)号：US09557856B2

公开(公告)日：2017-01-31

申请号：US14460540

申请日：2014-08-15

Applicant: BASF SE

Inventor： Robert Send ,  Ingmar Bruder ,  Stephan Irle ,  Erwin Thiel ,  Henrike Wonneberger

IPC: G06F3/042 ,  G01J4/04 ,  G01S7/499 ,  G01J1/42 ,  G01S17/02 ,  G01S17/42 ,  G01S17/66 ,  G01S17/93 ,  G01S7/481 ,  G01S11/12 ,  G06T7/00 ,  G01S17/46 ,  G01S5/16 ,  G06K9/74 ,  G01B11/25 ,  G01N30/74

CPC classification number: G01J1/0437 ,  G01B11/25 ,  G01J1/42 ,  G01J4/04 ,  G01N30/74 ,  G01S5/163 ,  G01S7/4816 ,  G01S7/499 ,  G01S11/12 ,  G01S17/026 ,  G01S17/42 ,  G01S17/46 ,  G01S17/66 ,  G01S17/936 ,  G06F3/0425 ,  G06K9/741 ,  G06T7/73 ,  G06T2207/10016 ,  G06T2207/10152

Abstract: An optical detector (110) is disclosed, the optical detector (110) comprising: at least one spatial light modulator (114) being adapted to modify at least one property of a light beam (136) in a spatially resolved fashion, having a matrix (132) of pixels (134), each pixel (134) being controllable to individually modify the at least one optical property of a portion of the light beam (136) passing the pixel (134); at least one optical sensor (116) adapted to detect the light beam (136) after passing the matrix (132) of pixels (134) of the spatial light modulator (114) and to generate at least one sensor signal; at least one modulator device (118) adapted for periodically controlling at least two of the pixels (134) with different modulation frequencies; and at least one evaluation device (120) adapted for performing a frequency analysis in order to determine signal components of the sensor signal for the modulation frequencies.

Abstract translation: 公开了一种光检测器（110），所述光检测器（110）包括：至少一个空间光调制器（114），其适于以空间分辨的方式修改光束（136）的至少一个属性，具有矩阵 （132）的每个像素（134），每个像素（134）可被控制以分别修改通过像素（134）的光束（136）的一部分的至少一个光学特性; 至少一个光学传感器（116）适于在通过空间光调制器（114）的像素（134）的矩阵（132）之后检测光束（136）并且产生至少一个传感器信号; 至少一个调制器装置（118）适于周期性地控制具有不同调制频率的至少两个像素（134）; 以及适于执行频率分析以便确定调制频率的传感器信号的信号分量的至少一个评估装置（120）。

公开(公告)号：US09389315B2

公开(公告)日：2016-07-12

申请号：US14132570

申请日：2013-12-18

Applicant: BASF SE

Inventor： Ingmar Bruder ,  Simone Christina Spiller ,  Erwin Thiel ,  Stephan Irle ,  Robert Send ,  Henrike Wonneberger

IPC: G06M7/00 ,  G01J1/20 ,  G01V8/00 ,  G01S17/66 ,  G01C3/06 ,  G01S17/89 ,  G01S3/781 ,  G01S3/786 ,  G01S7/481

CPC classification number: G01S17/89 ,  G01C3/06 ,  G01S3/781 ,  G01S3/786 ,  G01S7/4816 ,  G01S17/46 ,  G01S17/66

Abstract: A detector (110) for determining a position of at least one object (112) is proposed. The detector (110) comprises: at least one transversal optical sensor (130), the transversal optical sensor (130) being adapted to determine a transversal position of at least one light beam (138) traveling from the object (112) to the detector (110), the transversal position being a position in at least one dimension perpendicular to an optical axis (116) of the detector (110), the transversal optical sensor (130) being adapted to generate at least one transversal sensor signal; at least one longitudinal optical sensor (132), wherein the longitudinal optical sensor (132) has at least one sensor region (136), wherein the longitudinal optical sensor (132) is designed to generate at least one longitudinal sensor signal in a manner dependent on an illumination of the sensor region (136) by the light beam (138), wherein the longitudinal sensor signal, given the same total power of the illumination, is dependent on a beam cross-section of the light beam (138) in the sensor region (136); at least one evaluation device (142), wherein the evaluation device (142) is designed to generate at least one item of information on a transversal position of the object (112) by evaluating the transversal sensor signal and to generate at least one item of information on a longitudinal position of the object (112) by evaluating the longitudinal sensor signal.

Abstract translation: 提出了一种用于确定至少一个物体（112）的位置的检测器（110）。 检测器（110）包括：至少一个横向光学传感器（130），横向光学传感器（130）适于确定从物体（112）行进到检测器的至少一个光束（138）的横向位置 （110），所述横向位置是垂直于所述检测器（110）的光轴（116）的至少一个维度的位置，所述横向光学传感器（130）适于产生至少一个横向传感器信号; 至少一个纵向光学传感器（132），其中所述纵向光学传感器（132）具有至少一个传感器区域（136），其中所述纵向光学传感器（132）被设计成以依赖的方式产生至少一个纵向传感器信号 在由光束（138）照射传感器区域（136）的情况下，给予相同的照明总功率的纵向传感器信号取决于光束（138）中的光束横截面 传感器区域（136）; 至少一个评估装置（142），其中所述评估装置（142）被设计成通过评估横向传感器信号来产生对象（112）的横向位置上的至少一个信息项，并且生成至少一个项目 通过评估纵向传感器信号对物体（112）的纵向位置的信息。

公开(公告)号：US20150286340A1

公开(公告)日：2015-10-08

申请号：US14460540

申请日：2014-08-15

Applicant: BASF SE

Inventor： Robert SEND ,  Ingmar Bruder ,  Stephan Irle ,  Erwin Thiel ,  Henrike Wonneberger

IPC: G06F3/042 ,  G01J4/04 ,  G01S7/499 ,  G01J1/42 ,  G01S17/02 ,  G01S17/42

CPC classification number: G01J1/0437 ,  G01B11/25 ,  G01J1/42 ,  G01J4/04 ,  G01N30/74 ,  G01S5/163 ,  G01S7/4816 ,  G01S7/499 ,  G01S11/12 ,  G01S17/026 ,  G01S17/42 ,  G01S17/46 ,  G01S17/66 ,  G01S17/936 ,  G06F3/0425 ,  G06K9/741 ,  G06T7/73 ,  G06T2207/10016 ,  G06T2207/10152

Abstract: An optical detector (110) is disclosed, the optical detector (110) comprising: at least one spatial light modulator (114) being adapted to modify at least one property of a light beam (136) in a spatially resolved fashion, having a matrix (132) of pixels (134), each pixel (134) being controllable to individually modify the at least one optical property of a portion of the light beam (136) passing the pixel (134); at least one optical sensor (116) adapted to detect the light beam (136) after passing the matrix (132) of pixels (134) of the spatial light modulator (114) and to generate at least one sensor signal; at least one modulator device (118) adapted for periodically controlling at least two of the pixels (134) with different modulation frequencies; and at least one evaluation device (120) adapted for performing a frequency analysis in order to determine signal components of the sensor signal for the modulation frequencies.

Abstract translation: 公开了一种光检测器（110），所述光检测器（110）包括：至少一个空间光调制器（114），其适于以空间分辨的方式修改光束（136）的至少一个属性，具有矩阵 （132）的每个像素（134），每个像素（134）可被控制以分别修改通过像素（134）的光束（136）的一部分的至少一个光学特性; 至少一个光学传感器（116）适于在通过空间光调制器（114）的像素（134）的矩阵（132）之后检测光束（136）并且产生至少一个传感器信号; 至少一个调制器装置（118）适于周期性地控制具有不同调制频率的至少两个像素（134）; 以及适于执行频率分析以便确定调制频率的传感器信号的信号分量的至少一个评估装置（120）。