Sodium hydroxide production with carboxylic acid and sulfur dioxide intermediates

    公开(公告)号:US12030846B2

    公开(公告)日:2024-07-09

    申请号:US18198664

    申请日:2023-05-17

    发明人: Ethan Novek

    摘要: The present application pertains to processes producing oxides using a weak acid intermediate. In one embodiment a material comprising calcium carbonate is reacted with a solution comprising aqueous carboxylic acid to form a gas comprising carbon dioxide and a solution comprising aqueous calcium carboxylate. The solution comprising aqueous calcium carboxylate is reacted with sodium sulfate to form a solution comprising aqueous sodium carboxylate and a solid comprising calcium sulfate. The solution comprising aqueous sodium carboxylate is reacted with sulfur dioxide to form sodium sulfite and an aqueous carboxylic acid. The sodium sulfite is separated from said aqueous carboxylic acid and reacted to form a solid comprising calcium sulfite which is decomposed to form calcium oxide and sulfur dioxide.

    MOLECULAR ISOTOPIC ENGINEERING
    5.
    发明申请

    公开(公告)号:US20170369495A1

    公开(公告)日:2017-12-28

    申请号:US15540075

    申请日:2015-12-30

    申请人: John P. JASPER

    发明人: John P. JASPER

    摘要: The present invention relates to molecular isotopic engineering. The present invention relates to a method or process for preparing a target compound of a statistically defined isotopic composition comprising the step of reacting one or more reactant compounds, wherein each reactant compound is of a statistically defined isotopic composition. The reactant compound is reacted in a chemical process or a biological process thereby generating an isotopic mass balance, or further, an isotopic fractionation to produce the target compound. The present invention also relates to a statistically defined isotopic composition of a target compound. The statistically defined isotopic composition comprises an internal marker, and can be used as, for example, a security feature, an identity indicator, or a purity indicator of the target compound.

    METHOD FOR PROCESSING MAGNESIUM CHLORIDE SOLUTIONS
    8.
    发明申请
    METHOD FOR PROCESSING MAGNESIUM CHLORIDE SOLUTIONS 审中-公开
    氯化镁溶液的处理方法

    公开(公告)号:US20160369302A1

    公开(公告)日:2016-12-22

    申请号:US14902374

    申请日:2014-07-02

    申请人: PURAC BIOCHEM BV

    IPC分类号: C12P3/00 C01B7/03 C01F5/10

    摘要: A method for processing MgCl2 solutions including the steps of: providing an aqueous solution including 5-25 wt. % of MgCl2 and optionally organic contaminants to a step, wherein water and present, organic components are evaporated; withdrawing aqueous solution with a MgCl2 concentration of 25-35 wt. % from an evaporation step and providing it to a preconcentrator where it is contacted with a HCl containing gas stream at least 300° C.; providing aqueous solution with a MgCl2 concentration of 35-45 wt. % resulting from the preconcentrator to a thermohydrolysis reactor, being at at least 300° C.; withdrawing MgO from the thermohydrolysis reactor in solid form, and withdrawing a HCl containing gas stream from the thermohydrolysis reactor, said HCl-containing gas stream at least 300° C.; providing the HCl-containing gas stream with at least 300° C. to the preconcentrator; withdrawing a HCl-containing gas stream with a temperature of at most 150° C. from the preconcentrator.

    摘要翻译: 一种处理MgCl 2溶液的方法,包括以下步骤:提供包含5-25wt。 %的MgCl 2和任选的有机污染物到一个步骤,其中水和存在的有机组分被蒸发; 以25〜35wt。%的MgCl 2浓度萃取水溶液。 %,并将其提供给预浓缩器,其中其与含HCl的气流接触至少300℃; 提供MgCl 2浓度为35-45wt。%的水溶液。 由预浓缩器导致热水解反应器的至少300℃的%。 从固体形式的热水解反应器中取出MgO,并从热水解反应器中取出含HCl的气体流,所述含HCl的气流至少为300℃。 将至少300℃的含HCl气流提供给预浓缩器; 从预浓缩器中取出具有至多150℃温度的含HCl气流。

    Electrochemical Co-Production of Chemicals from Carbon Dioxide Using Sulfur-Based Reactant Feeds to Anode
    9.
    发明申请
    Electrochemical Co-Production of Chemicals from Carbon Dioxide Using Sulfur-Based Reactant Feeds to Anode 审中-公开
    使用硫基反应物进料到阳极的二氧化碳化学品的电化学共同生产

    公开(公告)号:US20160355931A1

    公开(公告)日:2016-12-08

    申请号:US15089126

    申请日:2016-04-01

    摘要: The present disclosure includes a system and method for producing a first product from a first region of an electrochemical cell having a cathode and a second product from a second region of the electrochemical cell having an anode. The method may include a step of contacting the first region with a catholyte comprising carbon dioxide, producing a first product which may include carbon monoxide or an alkli metal formate. The method may include another step of contacting the second region with an anolyte comprising a sulfur-based reactant and producing a second product including oxygen and sulfur dioxide. Further, the method may include a step for introducing the separated oxygen from second region of the electrochemical cell with a hydrogen sulfide stream in a catalyst reactor bed, converting the hydrogen sulfide to sulfur dioxide. The sulfur dioxide may then be liquefied as a product, or a portion of the sulfur dioxide may be recycled to the second region of the electrochemical cell where it may be converted to sulfuric acid. The sulfuric acid may then be reacted with another reactant, such as ammonia, to produce an ammonium sulfate product.

    摘要翻译: 本公开包括用于从具有阴极的电化学电池的第一区域产生第一产物的系统和方法,以及来自具有阳极的电化学电池的第二区域的第二产物。 该方法可以包括使第一区域与包含二氧化碳的阴极电解液接触的步骤,产生可包括一氧化碳或烷基金属甲酸盐的第一产物。 该方法可以包括使第二区域与包含硫基反应物的阳极电解液接触并产生包括氧和二氧化硫的第二产物的另一步骤。 此外,该方法可以包括将来自电化学电池的第二区域的分离的氧从催化剂反应器床中的硫化氢流引入到二氧化硫中的步骤。 然后二氧化硫可以作为产品液化,或者二氧化硫的一部分可以再循环到电化学电池的第二区域,在那里它可以被转化成硫酸。 然后可以将硫酸与另一种反应物如氨反应产生硫酸铵产物。