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    Lipophilic polyalkylenepolyamines by homogeneously catalyzed alcohol amination
    2.
    发明授权
    Lipophilic polyalkylenepolyamines by homogeneously catalyzed alcohol amination 有权
    亲油性聚亚烷基多胺通过均相催化醇胺化

    公开(公告)号：US09550725B2

    公开(公告)日：2017-01-24

    申请号：US14359134

    申请日：2012-11-19

    Applicant: BASF SE

    Inventor： Julia Strautmann ,  Thomas Schaub ,  Stephan Hueffer ,  Steffen Maas ,  Claudia Wood

    IPC: C07C209/14 ,  C08G73/02 ,  C09J179/02

    CPC classification number: C07C209/14 ,  C08G73/0213 ,  C09J179/02

    Abstract: Process for the preparation of lipophilic polyalkylenepolyamines by homogeneously catalyzed alcohol amination, where aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst, at least one of the reactants comprising an alkyl or alkylene group having five or more carbon atoms, and after the reaction a phase separation into at least one apolar phase and at least one polar phase being present, the lipophilic polyalkylenepolyamines being present in enriched form in the apolar phase. Polyalkylenepolyamines obtainable by such processes, and polyalkylenepolyamines comprising hydroxyl groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers in paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.

    Abstract translation: 通过均相催化的醇胺化制备亲脂性聚亚烷基多胺的方法，其中脂肪族氨基醇彼此反应或脂族二胺或多胺与脂肪族二元醇或多元醇反应，在均相催化剂存在下，除去水，至少一种 的反应物，其包含具有五个或更多个碳原子的烷基或亚烷基，并且在反应之后，相分离成至少一个非极性相和至少一个极性相存在，亲油性聚亚烷基多胺以非极性相存在于富集形式 。 可通过这些方法得到的聚亚烷基多胺，以及包含羟基，仲胺或叔胺的聚亚烷基多胺。 使用这种聚亚烷基多胺作为印刷油墨的粘合促进剂，复合膜中的粘合促进剂，粘合剂的粘合促进剂，树脂的交联剂/固化剂，油漆中的底漆，乳液涂料的湿粘合促进剂，络合剂和絮凝剂，渗透助剂 木材保存，腐蚀抑制剂，蛋白质和酶的固定剂。

    INCREASING THE MOLAR MASS OF POLYALKYLENEPOLYAMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION
    3.
    发明申请
    INCREASING THE MOLAR MASS OF POLYALKYLENEPOLYAMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION 审中-公开
    通过均相催化的醇醇胺化增加聚烯丙基胺的摩尔质量

    公开(公告)号：US20140309460A1

    公开(公告)日：2014-10-16

    申请号：US14357822

    申请日：2012-11-19

    Applicant: BASF SE

    Inventor： Julia Strautmann ,  Thomas Schaub ,  Stephan Hueffer ,  Rocco Paciello

    IPC: C07C209/16 ,  C07C211/02

    CPC classification number: C07C209/16 ,  C07C211/02 ,  C08G73/0213

    Abstract: Process for increasing the molar mass of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, which comprises carrying out a reaction of the polyalkylenepolyamines in a reactor with elimination of water in the presence of a homogeneous catalyst and removing the water of reaction from the reaction system. Polyalkylenepolyamines obtainable by such processes, and polyalkylenepolyamines comprising hydroxyl groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.

    Abstract translation: 通过均相催化醇胺化来提高聚亚烷基多胺的摩尔质量的方法，其包括在均相催化剂存在下进行反应中的聚亚烷基多胺与反应器中的水反应，并从反应体系中除去反应水。 可通过这些方法得到的聚亚烷基多胺，以及包含羟基，仲胺或叔胺的聚亚烷基多胺。 使用这种聚亚烷基多胺作为印刷油墨的粘合促进剂，复合膜中的粘合促进剂，粘合剂的内聚力促进剂，树脂的交联剂/固化剂，油漆的底漆，乳液漆的湿粘合促进剂，络合剂和絮凝剂，渗透助剂 木材保存，腐蚀抑制剂，蛋白质和酶的固定剂。

    LIPOPHILIC POLYALKYLENEPOLYAMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION
    4.
    发明申请
    LIPOPHILIC POLYALKYLENEPOLYAMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION 有权
    通过均相催化的醇醇胺化得到的聚丙烯酰胺（LIPOPHILIC POLYALKYLENEPOLYAMINES）

    公开(公告)号：US20140305339A1

    公开(公告)日：2014-10-16

    申请号：US14359134

    申请日：2012-11-19

    Applicant: BASF SE

    Inventor： Julia Strautmann ,  Thomas Schaub ,  Stephan Hueffer ,  Steffen Maas ,  Claudia Wood

    IPC: C07C209/14 ,  C09J179/02

    CPC classification number: C07C209/14 ,  C08G73/0213 ,  C09J179/02

    Abstract: Process for the preparation of lipophilic polyalkylenepolyamines by homogeneously catalyzed alcohol amination, where aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst, at least one of the reactants comprising an alkyl or alkylene group having five or more carbon atoms, and after the reaction a phase separation into at least one apolar phase and at least one polar phase being present, the lipophilic polyalkylenepolyamines being present in enriched form in the apolar phase. Polyalkylenepolyamines obtainable by such processes, and polyalkylenepolyamines comprising hydroxyl groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers in paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.

    Abstract translation: 通过均相催化的醇胺化制备亲脂性聚亚烷基多胺的方法，其中脂肪族氨基醇彼此反应或脂族二胺或多胺与脂肪族二元醇或多元醇反应，在均相催化剂存在下，除去水，至少一种 的反应物，其包含具有五个或更多个碳原子的烷基或亚烷基，并且在反应之后，相分离成至少一个非极性相和至少一个极性相存在，亲油性聚亚烷基多胺以非极性相存在于富集形式 。 可通过这些方法得到的聚亚烷基多胺，以及包含羟基，仲胺或叔胺的聚亚烷基多胺。 使用这种聚亚烷基多胺作为印刷油墨的粘合促进剂，复合膜中的粘合促进剂，粘合剂的粘合促进剂，树脂的交联剂/固化剂，油漆中的底漆，乳液涂料的湿粘合促进剂，络合剂和絮凝剂，渗透助剂 木材保存，腐蚀抑制剂，蛋白质和酶的固定剂。

    Storage-stable enzyme preparations, their production and use
    5.
    发明授权
    Storage-stable enzyme preparations, their production and use 有权

    公开(公告)号：US11512268B2

    公开(公告)日：2022-11-29

    申请号：US16768109

    申请日：2018-11-19

    Applicant: BASF SE

    Inventor： Stephan Hueffer ,  Alejandra Garcia Marcos ,  Oliver Spangenberg ,  Matthias Kellermeier ,  Susanne Wolwertz

    IPC: C11D3/386 ,  C11D3/20 ,  C11D11/00 ,  C07C219/06 ,  C12N9/14 ,  C12N9/96 ,  C11D3/30 ,  C11D3/37

    Abstract: Described herein is a liquid enzyme preparation containing
    component (a): at least one salt according to general formula (I) (R2)3N+—(CH2)nC(R3)(R4)—(O—X)m—O—C(O)—R1A−  (I) wherein n is selected from 1 to 12, m is selected from zero to 50, R1 is selected from the group consisting of methyl, ethyl, —CH(OH)—CH(OH)—COOH, CH(OH)—CH3, (E)-CH═CHCOOH, (Z)—CH═CHCOOH, —C6H5, para-HO—C6H4—, o,p-dihydroxyphenyl, and 3,4,5-triydroxyphenyl, R2 are same or different and selected from C1-C10-alkyl, phenyl, R3 and R4 are same or different and selected from hydrogen and C1-C4-alkyl, X is C2-C4-alkylen, and A− is an inorganic or organic counteranion, component (b): at least one enzyme selected from hydrolases (EC 3), and optionally component (c): at least one compound selected from enzyme stabilizers different from component (a), preservatives, and surfactants.

    STORAGE-STABLE ENZYME PREPARATIONS, THEIR PRODUCTION AND USE
    6.
    发明申请
    STORAGE-STABLE ENZYME PREPARATIONS, THEIR PRODUCTION AND USE 审中-公开

    公开(公告)号：US20200291334A1

    公开(公告)日：2020-09-17

    申请号：US16768109

    申请日：2018-11-19

    Applicant: BASF SE

    Inventor： Stephan Hueffer ,  Alejandra Garcia Marcos ,  Oliver Spangenberg ,  Matthias Kellermeier ,  Susanne Wolwertz

    IPC: C11D3/386 ,  C12N9/96 ,  C12N9/14 ,  C07C219/06 ,  C11D3/20 ,  C11D11/00

    Abstract: Described herein is a liquid enzyme preparation containingcomponent (a): at least one salt according to general formula (I) (R2)3N+—(CH2)nC(R3)(R4)—(O—X)m—O—C(O)—R1 A−  (I) wherein n is selected from 1 to 12, m is selected from zero to 50, R1 is selected from the group consisting of methyl, ethyl, —CH(OH)—CH(OH)—COOH, CH(OH)—CH3, (E)-CH═CHCOOH, (Z)—CH═CHCOOH, —C6H5, para-HO—C6H4—, o,p-dihydroxyphenyl, and 3,4,5-triydroxyphenyl, R2 are same or different and selected from C1-C10-alkyl, phenyl, R3 and R4 are same or different and selected from hydrogen and C1-C4-alkyl, X is C2-C4-alkylen, and A− is an inorganic or organic counteranion, component (b): at least one enzyme selected from hydrolases (EC 3), and optionally component (c): at least one compound selected from enzyme stabilizers different from component (a), preservatives, and surfactants.

    FORMULATIONS, THEIR USE AS OR FOR PRODUCING DISHWASHING COMPOSITIONS AND THEIR PREPARATION
    10.
    发明申请
    FORMULATIONS, THEIR USE AS OR FOR PRODUCING DISHWASHING COMPOSITIONS AND THEIR PREPARATION 有权
    制剂，他们作为或用于生产洗涤组合物及其制备

    公开(公告)号：US20130288941A1

    公开(公告)日：2013-10-31

    申请号：US13869111

    申请日：2013-04-24

    Applicant: BASF SE

    Inventor： Stephan Hueffer ,  Alejandra Garcia Marcos ,  Markus Hartmann ,  Heike Weber ,  Mario Emmeluth

    IPC: C11D3/37 ,  C11D3/33

    CPC classification number: C11D3/3723 ,  C11D3/33 ,  C11D11/0082 ,  C11D11/02

    Abstract: The present invention relates to formulations comprising (A) at least one aminocarboxylate, selected from methylglycine diacetate (MGDA), iminodisuccinic acid (IDA) and glutaminic acid diacetate (GLDA), and salts and derivatives thereof, and (B) at least one alkyleneimine polymer which is covalently modified with at least one carboxylic acid or at least one derivative of a carboxylic acid or at least one derivative of carbonic acid, where up to at most 75 mol % of the nitrogen atoms of the primary and secondary amino groups of the alkyleneimine polymer have been reacted with carboxylic acid or derivative of carboxylic acid or carbonic acid.

    Abstract translation: 本发明涉及包含（A）至少一种选自甲基甘氨酸二乙酸酯（MG​​DA），亚氨基二琥珀酸（IDA）和谷氨酸二乙酸酯（GLDA））的氨基羧酸盐及其盐和衍生物的制剂，和（B）至少一种亚烷基亚胺 与至少一种羧酸或至少一种羧酸衍生物或至少一种碳酸衍生物共价修饰的聚合物，其中至多75mol％的伯和仲氨基的氮原子 亚烷基亚胺聚合物已经与羧酸或羧酸或碳酸的衍生物反应。

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