Efficient sunscreen compositions with diethylamino hydroxybenzoyl hexyl benzoate and butyl methoxydibenzoylmethane free of octocrylene

    公开(公告)号:US12246082B2

    公开(公告)日:2025-03-11

    申请号:US17439631

    申请日:2020-03-13

    Applicant: BASF SE

    Abstract: The present invention relates to sunscreen or daily care composition comprising (i) hexyl 2-[4-(diethylamino)-2-hydroxybenzoyl]benzoate (INCI diethylamino hydroxybenzoyl hexyl benzoate); and (ii) 1-(4-(1,1-dimethylethyl)phenyl)-3-(4-methoxyphenyl)propane-1,3-dione (INCI butyl methoxydibenzoylmethane); and (iii) 2,4-bis-{[4-(2-ethy-hexyoxy)-2-hydroxy]-pheny}-6-(4-methoxypheny)-1,3,5 triazine (INCI bis-ethylhexyloxyphenol methoxyphenyl triazine); and (iv) 4,4′,4″-(1,3,5-triazine-2,4,6-triyltriimino)tris-benzoic acid-tris(2-ethylhexyl)ester (INCI ethylhexyl triazone) and/or 4, 4′-[[6-[[4-[[(1,1-dimethylethyl)amino]carbonyl]phenyl]amino]-1,3,5-triazin-2,4-diyl]diimino]bis-benzoic acid-bis(2-ethylhexyl)ester (INCI diethyl-hexyl-butamidotriazone); and (v) at least one organic particulate UV filter, wherein the composition is free of ethylhexyl-2-cyano-3, 3-diphenyl-acrylate (INCI octocrylene), 2-ethylhexyl-(2E)-3-(4-methoxyphenyl) acrylate (INCI ethylhexyl methoxy cinnamate) and pp benzylidene malonates, and wherein the composition comprises diethylamino hydroxybenzoyl hexylbenzoate and butyl methoxydibenzoylmethane in a ratio of larger or equal to 0.8. Furthermore, the present invention relates to the use of said composition for the administration to sensitive skin. In addition, the present invention relates to the use of said composition to reduce sand adhesion after application of the composition on the skin.

    STABILIZATION OF COSMETIC COMPOSITIONS
    4.
    发明申请
    STABILIZATION OF COSMETIC COMPOSITIONS 审中-公开
    化妆品组合物的稳定性

    公开(公告)号:US20150250695A1

    公开(公告)日:2015-09-10

    申请号:US14722037

    申请日:2015-05-26

    Applicant: BASF SE

    Abstract: Disclosed is the use of UV absorbers selected from (a1) diphenylacrylates; (a2) hydroxyphenyl triazines of formula (1), in which R1, R2 and R3 independently of one another, are C1-C18alkyl; (a3) benzotriazole derivatives of formula (2), wherein R4 is a random statistical mixture of at least three isomeric branched secondary alkyl groups each having 8 to 30 carbon atoms and having the formula (2a); E1 is a straight-chain C1-C14alkyl; E2 is a straight-chain C4-C15alkyl; wherein the total number of carbon atoms in E1 plus E2 is from 7 to 29; and R5 is C1-C5alkyl; and (a4) dialkyl naphthalate; for stabilizing cosmetic compositions comprising (b) symmetrical triazine derivatives of formula (3), wherein A is a radical of formula (3a); or (3b) R6 and R10 independently from each other are hydrogen; C1-C18alkyl; or C6-C12aryl; R7, R8 and R9 independently from each other are hydrogen; or a radical of formula (3c), wherein, in formula (3a), at least one of the radicals R7, R8 and R9 are a radical of formula (3c); R11, R12, R13 and R14 independently from each other are hydrogen; hydroxy; halogen; C1-C18alkyl; C1-C18alkoxy; C6-C12aryl; biphenylyl; C6-C12aryloxy; C1-C18alkylthio; carboxy; —COOM; C1-C18-alkylcarboxyl; aminocarbonyl; mono- or di-C1-C18alkylamino; C1-C10acylamino; or —COOH; M is an alkali metal ion; x is 1 or 2; and y is a number from 2 to 10; and a UV-absorber selected from (c1) cinnamic acid derivatives; and (C2) dibenzoylmethane derivatives.

    Abstract translation: 公开了使用选自(a1)二苯基丙烯酸酯的UV吸收剂; (a2)式(1)的羟基苯基三嗪,其中R 1,R 2和R 3彼此独立地是C 1 -C 18烷基; (a3)式(2)的苯并三唑衍生物,其中R4是至少三个具有8至30个碳原子并具有式(2a)的异构支链仲烷基的随机统计混合物; E1是直链C1-C14烷基; E2是直链C4-C15烷基; 其中E1加E2的总碳原子数为7〜29; R5是C1-C5烷基; 和(a4)萘二甲酸二烷基酯; 用于稳定化妆品组合物,其包含(b)式(3)的对称三嗪衍生物,其中A是式(3a)的基团; 或(3b)R 6和R 10彼此独立地为氢; C1-C18烷基; 或C6-C12芳基; R 7,R 8和R 9彼此独立地为氢; 或式(3c)的基团,其中在式(3a)中,基团R7,R8和R9中的至少一个是式(3c)的基团; R 11,R 12,R 13和R 14彼此独立地为氢; 羟基; 卤素; C1-C18烷基; C1-C18烷氧基; C6-C12芳基; 联苯基 C 6 -C 12芳氧基; C1-C18烷硫基; 羧基; -COOM; C 1 -C 18烷基羧基; 氨基羰基; 单或二C1-C18烷基氨基; C1-C10酰氨基; 或-COOH; M是碱金属离子; x为1或2; y为2〜10的数; 和选自(c1)肉桂酸衍生物的紫外线吸收剂; 和(C2)二苯甲酰甲烷衍生物。

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