公开(公告)号：US20180141888A1

公开(公告)日：2018-05-24

申请号：US15575169

申请日：2016-05-19

Applicant: BASF SE

Inventor： Stefan RÜDENAUER ,  Miriam BRU ROIG ,  Andreas ERNST ,  Thomas FENLON

IPC: C07C45/30 ,  C07C49/385

CPC classification number: C07C45/30 ,  C07C49/385 ,  C07C2601/18

Abstract: The present invention relates to a process for preparing a macrocyclic diketone compound of the formula (I), which comprises the oxidation of a bicycloolefine compound of the formula (II) with an oxidizing agent, formulae (I) (II) where in formulae (I) and (II) A is (CH2)n with n being an integer from 2 to 12, where two hydrogen atoms may be replaced by C1-C4-alkyl, in particular methyl, or two hydrogen atoms, which are bound to adjacent carbon atoms may be replaced by a fused 5- or 6-membered saturated carbocycle; B is (CH2)m with m being 1 or 2, where 1 or 2 hydrogen atoms may be replaced by C1-C4-alkyl, in particular methyl.

公开(公告)号：US20180208550A1

公开(公告)日：2018-07-26

申请号：US15746151

申请日：2016-07-20

Applicant: BASF SE

Inventor： Klaus BREUER ,  Robert BAUMANN ,  Alexander PANCHENKO ,  Michael LORENZ ,  Frank HETTCHE ,  Norbert GUTFRUCHT ,  Thomas FENLON

IPC: C07C263/10

CPC classification number: C07C263/10 ,  C07B2200/09 ,  C07C2601/14 ,  C07C265/14

Abstract: The present invention relates to a process for preparing a cyclic isocyanate (B) from a composition (Z) which comprises at least one component (A) which has at least one cycloalkane ring having at least 4 ring carbons, where the cycloalkane ring has two NH2 groups in β or γ positions relative to one another as substituents and in more than 50 mol % of the total amount of component (A) the two NH2 groups in β or in γ positions relative to one another assume a trans configuration relative to one another. This composition (Z) is, in the process of the invention, reacted with phosgene to give a composition (ZP) which comprises at least one cyclic isocyanate (B) having isocyanate groups.In addition, the invention relates to the use of the isocyanate mixture (M) as monomer in processes for preparing polymers, in particular for preparing polyurethanes and polyureas.

公开(公告)号：US20170283352A1

公开(公告)日：2017-10-05

申请号：US15509238

申请日：2015-09-08

Applicant: BASF SE

Inventor： Thomas FENLON ,  Sumana CHATURVEDULA ,  Dominic RIEDEL ,  Stefan RÜDENAUER ,  Ralf PELZER ,  Pepa DIMITROVA ,  Florina Corina PATCAS ,  Manuel DANZ

IPC: C07C45/54 ,  C07C45/80

CPC classification number: C07C45/54 ,  C07C41/05 ,  C07C41/18 ,  C07C45/80 ,  C07C51/367 ,  C07C2601/14 ,  C07C43/196 ,  C07C43/23 ,  C07C59/64 ,  C07C47/58

Abstract: A method of preparing a compound of formula (IV) where R1 is alkyl of 1 to 4 carbon atoms, comprises reacting cyclohexene with hydrogen peroxide and an alcohol R1OH in the presence of a catalyst comprising a zeolite of framework structure MWW, wherein the framework of the zeolite comprises silicon, titanium, boron, oxygen and hydrogen.

公开(公告)号：US20180244613A1

公开(公告)日：2018-08-30

申请号：US15753244

申请日：2016-08-17

Applicant: BASF SE

Inventor： Stefan RÜDENAUER ,  Thomas FENLON ,  Shriang HINDALEKAR ,  Nisha PANSARE ,  Abhijeet Deb ROY ,  Vijay Narayanan SWAMINATHAN

IPC: C07C403/16 ,  C07C45/39 ,  C07C49/203

CPC classification number: C07C403/16 ,  C07C45/39 ,  C07C49/203 ,  C07C2601/16

Abstract: The present invention relates to a process for preparing 1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one, which comprises a) providing 6,10-dimethylundeca-1,5,9-trien-4-ol, b) oxidizing 6,10-dimethylundeca-1,5,9-trien-4-ol provided in step a) with an oxidizing agent in the presence of at least one organic nitroxyl radical, at least one nitrate compound and an inorganic solid to yield 6,10-dimethylundeca-1,5,9-trien-4-one, c) reacting the 6,10-dimethylundeca-1,5,9-trien-4-one obtained in step b) with an acid to yield 1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one.

公开(公告)号：US20180208533A1

公开(公告)日：2018-07-26

申请号：US15744474

申请日：2016-07-15

Applicant: BASF SE

Inventor： Stefan RÜDENAUER ,  Andreas LANVER ,  Ralf PELZER ,  Klaus EBEL ,  Thomas FENLON ,  Andrei-Nicolae PARVULESCU ,  Sumana CHATURVEDULA

IPC: C07C41/18

CPC classification number: C07C41/18 ,  C07C43/215

Abstract: A process for preparing an arylpropene from a diarylpropane by gas phase thermolysis in the presence of solid porous catalyst comprising silica having large pore volume and low acidity.

公开(公告)号：US20180237369A1

公开(公告)日：2018-08-23

申请号：US15753236

申请日：2016-08-17

Applicant: BASF SE

Inventor： Thomas FENLON ,  Stefan RÜDENAUER ,  Ralf PELZER ,  Shrirang HINDALEKAR ,  Vijay Narayanan SWAMINATHAN ,  Nitin GUPTE ,  Sadanand ARDEKAR

IPC: C07C41/01 ,  C07C43/115

CPC classification number: C07C41/01 ,  C07C41/16 ,  C07C43/115 ,  C07C2531/02 ,  C07C2601/14

Abstract: The present invention relates to a process for preparing,4-bis(ethoxymethyl)cyclohexane, which comprises reacting1,4-bis(hydroxymethyl)cyclohexane with ethyl chloride in the presence of an inorganic base, a solvent and a phase transfer catalyst to yield a reaction mixture containing 1,4-bis(ethoxymethyl)cyclohexane, where the inorganic base is selected from alkali metal hydroxides and earth alkaline metal hydroxides and where the solvent is selected from water or a mixture of water with at least one organic solvent.

公开(公告)号：US20170275225A1

公开(公告)日：2017-09-28

申请号：US15509228

申请日：2015-09-08

Applicant: BASF SE

Inventor： Dominic Riedel ,  Joaquim Henrique TELES ,  Andrei-Nicolae PARVULESCU ,  Stefan RÜDENAUER ,  Thomas FENLON

IPC: C07C45/00 ,  C07C29/03 ,  B01J29/70 ,  C07C45/27 ,  C01B39/48 ,  C07C41/05 ,  C07D301/12

CPC classification number: C07C45/00 ,  B01J29/7038 ,  C01B39/48 ,  C07C29/03 ,  C07C41/05 ,  C07C45/27 ,  C07C2601/14 ,  C07C2601/16 ,  C07D301/12 ,  C07C43/196

Abstract: A method of preparing 2-alkoxycyclohexanol, a mixture comprising 2-alkoxycyclohexanol obtained via said method, and the use of said mixture for preparing 4-hydroxy-3-alkoxy-benzaldehyde.