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公开(公告)号：US20240300820A1
公开(公告)日：2024-09-12
申请号：US18593677
申请日：2024-03-01
IPC分类号： C01B39/48 , B01J29/70 , B01J29/86 , B01J35/63 , B01J37/00 , B01J37/03 , B01J37/04 , C01B37/00 , C01B39/02 , C07D471/04
CPC分类号： C01B39/48 , B01J29/70 , B01J29/86 , B01J35/633 , B01J37/0018 , B01J37/031 , B01J37/04 , C01B37/007 , C01B39/026 , C07D471/04 , C01P2002/72 , C01P2004/03 , C01P2004/12 , C01P2004/20 , C01P2006/12 , C01P2006/14
摘要： Molecular sieves, designated as EMM-74, characterized by a unique powder XRD pattern, methods of making the same, and uses thereof.
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公开(公告)号：US20240174525A1
公开(公告)日：2024-05-30
申请号：US18552665
申请日：2022-03-24
申请人： CHEVRON U.S.A. INC.
发明人： Adeola OJO
CPC分类号： C01B39/48 , B01J29/7046 , B01J29/7492 , C07C5/2775 , C01B39/46 , C01P2002/72
摘要： The present application pertains to family of new crystalline molecular sieves designated SSZ-94. Molecular sieve SSZ-94 is structurally similar to sieves falling within the MTT structure type such as SSZ-32x, SSZ-32, ZSM-23, EU-13, ISI-4, and KZ-1 family of molecular sieves. SSZ-94 is characterized as having magnesium.
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公开(公告)号：US20240174524A1
公开(公告)日：2024-05-30
申请号：US18059705
申请日：2022-11-29
发明人： Lianhui Ding
IPC分类号： C01B39/48 , B01J29/70 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/06 , B01J37/08
CPC分类号： C01B39/48 , B01J29/7007 , B01J35/0013 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1061 , B01J37/0018 , B01J37/0236 , B01J37/036 , B01J37/04 , B01J37/06 , B01J37/08 , C01P2004/03 , C01P2004/64 , C01P2006/12 , C01P2006/14 , C01P2006/16
摘要： Methods for synthesizing a nano-sized zeolite beta are described. The method may include mixing alumina and tetraethylammonium hydroxide to form an aluminum solution; mixing silica, additional TEAOH, and water to form a silica slurry; and adding the aluminum solution into the silica slurry and mixing to form an aluminosilicate gel. The method may further include transferring the aluminosilicate gel to an autoclave operated at 120° C. to 160° C. for 2 to 4 days at a rotational speed of 60 to 100 rotations per minute to form a zeolite precursor colloid; washing the zeolite precursor colloid with water to form a washed colloid; drying the washed colloid at 80° C. to 150° C. for 6 to 24 hours to form a zeolite precursor; and calcining the zeolite precursor at 400° C. to 650° C. for 2 to 8 hours to form the nano-sized zeolite beta.
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公开(公告)号：US20240116038A1
公开(公告)日：2024-04-11
申请号：US18262884
申请日：2022-01-30
申请人： BASF Corporation
发明人： Xiaoduo Qi , Lihua Shi , Vivek Vattipalli , Mingming Wei , Haitao Liu , Jin Li
IPC分类号： B01J29/76 , B01D53/94 , B01J37/00 , B01J37/03 , B01J37/04 , B01J37/08 , B01J37/30 , C01B39/02 , C01B39/48 , F01N3/20 , F01N3/28
CPC分类号： B01J29/763 , B01D53/9418 , B01J37/0018 , B01J37/031 , B01J37/04 , B01J37/08 , B01J37/30 , C01B39/026 , C01B39/48 , F01N3/2066 , F01N3/2803 , B01D2255/20761 , B01D2255/50 , B01D2255/9207 , B01D2257/404 , B01D2258/01 , B01J2229/186 , C01P2002/72 , C01P2002/74 , C01P2002/78 , C01P2004/03 , C01P2006/12 , F01N2370/04
摘要： The present invention relates to a CHA-like zeolitic material having an X-ray diffraction pattern including the following peaks in Table 1 in its as-synthesized form, and to a process for preparing the zeolitic material, and use of the zeolitic material for the selective catalytic reduction of NOx.
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公开(公告)号：US11952283B2
公开(公告)日：2024-04-09
申请号：US17626077
申请日：2020-07-09
申请人： CHINA PETROLEUM & CHEMICAL CORPORATION , SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
发明人： Weimin Yang , Wenhua Fu , Zhiqing Yuan , Zhendong Wang , Jiawei Teng , Weichuan Tao , Shengli Zhao
CPC分类号： C01B39/48 , B01J20/18 , C01P2002/72
摘要： A silicon-and germanium-based molecular sieve has a framework chemical composition as represented by the formula “SiO2.1/nGeO2”. The silicon/germanium molar ratio is 0.1n30. The molecular sieve has a unique X-ray diffraction pattern. It can be used in adsorptive separation, ion exchange, and catalytic conversion of organic compounds.
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公开(公告)号：US11939225B2
公开(公告)日：2024-03-26
申请号：US17285546
申请日：2019-11-01
发明人： Joseph M. Falkowski , Hilda Bouza Vroman , Allen W. Burton , Eugene Terefenko , Kanmi Mao , Karl G. Strohmaier
IPC分类号： B01J20/18 , B01D53/047 , C01B39/48
CPC分类号： C01B39/48 , B01D53/047 , B01J20/186 , B01D2253/116 , B01D2253/306 , B01D2253/311 , B01D2256/245 , B01D2257/504 , C01P2002/72 , C01P2002/74 , C01P2006/12 , C01P2006/14 , C01P2006/16
摘要： A composition can include a Rho zeolite with a RHO topology having a Si to B ratio or a Si to Al ratio greater than or equal to 8. Making such a composition can include heating an aqueous reaction mixture having a molar ratio of atomic Si to atomic B of about 4 to about 50 or a molar ratio of atomic Si to atomic Al of about 4 to about 50 in the presence of a C4-C6 diquat of N,2-dimethylbenzimidazole structure directing agent to a temperature of at least 75° C. to produce a Rho zeolite.
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公开(公告)号：US20240059574A1
公开(公告)日：2024-02-22
申请号：US18260640
申请日：2022-01-07
申请人： CHINA PETROLEUM & CHEMICAL CORPORATION , SINOPEC DALIAN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS CO., LTD.
发明人： Yujing CHEN , Hongfei FAN , Zhengmin YU , Xiaoyan SUN
IPC分类号： C01B39/48
CPC分类号： C01B39/48 , C01P2006/12 , C01P2006/14 , C01P2002/72 , C01P2004/03
摘要： A ZSM-23 zeolite and a process for preparing the same and use thereof are provided. The total acid amount of the ZSM-23 zeolite is 0.05-0.25 mmol/g, preferably 0.06-0.22 mmol/g, more preferably 0.06-0.20 mmol/g. The strong acid content of the ZSM-23 zeolite is 5-33%, preferably 7-33%, more preferably 9-33%, or further preferably 7-31%, further more preferably 10-28% of the total acid amount. The strong acid refers to an acid having a desorption temperature of 350° C. or higher in an NH3 temperature programmed desorption (NH3-TPD). The ZSM-23 zeolite has a low strong acid content.
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公开(公告)号：US11904282B2
公开(公告)日：2024-02-20
申请号：US17149823
申请日：2021-01-15
发明人： Jungkyu Choi , Kwan Young Lee , Minseong Lee
IPC分类号： B01D67/00 , B01D53/22 , C02F1/44 , C01B39/02 , C01B39/48 , B01J20/18 , B01J20/28 , B01J20/30 , C10L3/10 , B01D69/10 , B01D71/02 , C02F101/34
CPC分类号： B01D67/0083 , B01D53/228 , B01D67/0051 , B01D67/0095 , B01D69/107 , B01D69/108 , B01D71/0281 , B01J20/183 , B01J20/28033 , B01J20/3057 , B01J20/3078 , C01B39/026 , C01B39/48 , C02F1/44 , C10L3/104 , C10L3/105 , C02F2101/34 , C10L2290/548
摘要： The present invention relates to a method of controlling a defect structure in a chabazite (CHA) zeolite membrane, the CHA zeolite membrane having a controlled defect structure by the method and a method of separating CO2, H2, or He and water from a mixture of water and an organic solvent using the CHA zeolite membrane, and more particularly, to a method of controlling a defect structure in a CHA zeolite membrane that improves the separation performance by reducing the amount and size of defects formed in the CHA membrane structure when removing organic-structure-directing agents in the membrane through calcination at a low temperature using ozone.
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公开(公告)号：US20230416102A1
公开(公告)日：2023-12-28
申请号：US18253748
申请日：2021-11-08
发明人： Feijian CHEN , Zihao Rei GAO , Jian LI
CPC分类号： C01B39/48 , B01J29/89 , B01J37/03 , B01J37/0018 , B01J37/06 , B01J37/0236 , C01P2004/03 , C01P2002/72 , B01J2229/183
摘要： Provided are a ZEO-1 silicate molecular sieve having a new structure, a synthesis method therefor and the use thereof. An X-ray powder diffraction feature, a pore channel system and a topology feature of the ZEO-1 molecular sieve are characterized. Further, titanium atoms are successfully introduced in the framework of the ZEO-1 molecular sieve. The ZEO-1 molecular sieve of the present invention has a good thermal stability and can be used as an adsorbent or a catalyst.
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公开(公告)号：US11851339B2
公开(公告)日：2023-12-26
申请号：US17652777
申请日：2022-02-28
发明人： Kaneshalingam Arulraj , Guy R. Chandler , Jillian Collier , Raquel Garcia , Alexander Green , Nicholas Mcnamara , Paul Phillips , Maria Pia Ruggeri , Alessandro Turrina
IPC分类号： C01B39/48 , B01J29/70 , B01J29/72 , B01J29/78 , F01N3/20 , B01J29/06 , B01J29/04 , B01J37/26 , B01J37/22 , B01J39/14 , B01J49/08 , B01J47/012 , F01N3/023 , F01N3/08
CPC分类号： C01B39/48 , B01J29/7065 , B01J29/723 , B01J29/783 , F01N3/2066 , B01J29/048 , B01J29/06 , B01J37/22 , B01J37/26 , B01J39/14 , B01J47/012 , B01J49/08 , F01N3/0231 , F01N3/0814 , F01N3/0821 , F01N3/0871 , F01N3/0885 , F01N3/206 , F01N3/2006 , F01N2240/18 , F01N2560/026 , F01N2570/14 , F01N2570/145 , F01N2610/02 , F01N2900/1612 , F01N2900/1621 , F01N2900/1624
摘要： The present invention is directed to a method of preparing a synthetic crystalline material, designated as JMZ-12, with a framework built up by the disorder AEI and CHA structures, substantially free of framework phosphorous and prepared preferably in the absence of halides such as fluoride ions. Such method comprises the step of heating a reaction mixture under crystallization conditions for a sufficient period to form a disordered zeolite having both CHA and AEI topologies, wherein the reaction mixture comprises at least one source of aluminum, at least one source of silicon, a source of alkaline or alkaline-earth cations, and a structure directing agent containing at least one source of quaternary ammonium cations and at least one source of alkyl-substituted piperidinium cations in a molar ratio of 0.20 to about 1.4. The resulting zeolites are useful as catalysts, particularly when used in combination with exchanged transition metal(s) and, optionally, rare earth metal(s).
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